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The accurate prediction of solid-solid structural phase transitions at finite temperature is a challenging task, since the dynamics is so slow that direct simulations of the phase transitions by first-principles (FP) methods are typically…

材料科学 · 物理学 2021-05-25 Peitao Liu , Carla Verdi , Ferenc Karsai , Georg Kresse

The traditional picture of solid-solid phase transformations assumes an ordered parent phase transforms into an ordered daughter phase via a single unique pathway. Zirconium and its prototypical phase transition from hexagonal close-packed…

In order to probe the mechanism of solid-solid phase transformations, we have applied ultrafast shock wave compression (120 picosecond duration) and ultrashort (130 femtosecond) x-ray diffraction at the Linac Coherent Light Source (LCLS) to…

The structural phase behaviors of pure zirconium metal under compressions up to $160$ GPa at room temperature are investigated from the perspective of ensemble theory where the partition function is solved by our recently proposed method…

材料科学 · 物理学 2022-10-21 Bo-Yuan Ning

Characteristic shock effects in silica serve as a key indicator of historical impacts at geological sites. Despite this geological significance, atomistic details of structural transformations under high pressure and shock compression…

材料科学 · 物理学 2025-04-16 Linus C. Erhard , Christoph Otzen , Jochen Rohrer , Clemens Prescher , Karsten Albe

Under high pressure conditions, Zr undergoes a phase transformation from its ambient equilibrium hexagonal close packed $\alpha$ phase to hexagonal $\omega$ phase. Upon returning to ambient conditions, the material displays hysteretic…

We present results from ramp compression experiments on high-purity Zr that show the $\alpha \rightarrow \omega$, $\omega \rightarrow \beta$, as well as reverse $\beta \rightarrow \omega$ phase transitions. Simulations with a multi-phase…

材料科学 · 物理学 2022-05-25 C. W. Greeff , J. Brown , N. Velisavljevic , P. A. Rigg

We investigated the effects of uniaxial stress on the pressure-induced alpha-to-omega transition in pure titanium (Ti) by means of angle dispersive x-ray diffraction in a diamond-anvil cell. Experiments under four different pressure…

材料科学 · 物理学 2009-11-10 Daniel Errandonea , Y. Meng , M. Somayazulu , D. Hausermann

Zirconium (Zr) is an important engineering material with numerous practical applications. It undergoes martensitic $\alpha$ to $\omega$ phase transformation (PT) at pressures that vary from 0.67 GPa to 17 GPa under different loading…

材料科学 · 物理学 2025-05-15 Raghunandan Pratoori , Hamed Babaei , Valery I. Levitas

We introduce a simple model of deterministic particles in weakly disordered media which exhibits a transition from normal to anomalous diffusion. The model consists of a set of non-interacting overdamped particles moving on a disordered…

无序系统与神经网络 · 物理学 2017-04-26 M. Hidalgo-Soria , R. Salgado-García

Results of X-ray diffraction experiments on solid oxygen at low temperature and at pressures up to 10 GPa are presented.A careful sample preparation and annealing around 240 K allowed to obtain very good diffraction patterns in the…

材料科学 · 物理学 2009-11-07 Federico A. Gorelli , Mario Santoro , Lorenzo Ulivi , Michael Hanfland

A detailed understanding of the material response to rapid compression is challenging and demanding. For instance, the element gold under dynamic compression exhibits complex phase transformations where there exist some large discrepancies…

材料科学 · 物理学 2021-07-20 Bo Chen , Qiyu Zeng , Han Wang , Shen Zhang , Dongdong Kang , Denghui Lu , Jiayu Dai

We study the thermally activated, slow conversion of the hysteretically retained $\omega$ phase into stable $\alpha$ phase in recovered samples of shocked zirconium. The $\omega$-phase decays in time following an algebraic law, unlike the…

材料科学 · 物理学 2015-10-05 Cristiano Nisoli , Honxiang Zong , Stephen R. Niezgoda , Donald W. Brown , Turab Lookman

We use computer simulations to study the microscopic dynamics of an athermal assembly of soft particles near the fluid-to-solid, jamming transition. Borrowing tools developed to study dynamic heterogeneity near glass transitions, we…

材料科学 · 物理学 2010-06-24 Claus Heussinger , Ludovic Berthier , Jean-Louis Barrat

We have performed a detailed x-ray diffraction structural study of Zr under pressure and unambiguously identify the existence of a first-order isostructural bcc-to-bcc phase transition near 58 GPa. First-principles quantum molecular…

A growing number of shock compression experiments, especially those involving laser compression, are taking advantage of in situ x-ray diffraction as a tool to interrogate structure and microstructure evolution. Although these experiments…

High-pressure and variable temperature single crystal synchrotron X-ray measurements combined with first-principles based molecular dynamics simulations study diffuse scattering in the relaxor ferroelectric system PSN…

材料科学 · 物理学 2015-05-13 P. Ganesh , E. Cockayne , M. Ahart , R. E. Cohen , B. Burton , R. J. Hemley , Yang Ren , Wenge Yang , Z-G Ye

We consider an inhomogeneous quantum phase transition across a multicritical point of the XY quantum spin chain. This is an example of a Lifshitz transition with a dynamical exponent z = 2. Just like in the case z = 1 considered in New J.…

统计力学 · 物理学 2010-10-28 Jacek Dziarmaga , Marek M. Rams

We report on a novel approach to dynamic compression of materials that bridges the gap between previous static- and dynamic- compression techniques, allowing to explore a wide range of pathways in the pressure-temperature space. By…

We examine time-resolved X-ray diffraction from molecules in the gas phase which undergo nonadiabatic avoided-crossing dynamics involving strongly coupled electrons and nuclei. Several contributions to the signal are identified,…

化学物理 · 物理学 2017-05-30 Markus Kowalewski , Kochise Bennett , Shaul Mukamel
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