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Photoreforming is a clean photocatalytic technology for simultaneous plastic waste degradation and hydrogen fuel production, but there are still limited active and stable catalysts for this process. This work introduces the brookite…

材料科学 · 物理学 2024-08-21 Thanh Tam Nguyen , Kaveh Edalati

The clean production of hydrogen as a zero-emission fuel can be done using photocatalysis, with TiO2 being one of the most promising photocatalysts. However, the activity of TiO2 anatase and rutile phases is still limited. In this study, an…

材料科学 · 物理学 2025-08-19 Jacqueline Hidalgo-Jimenez , Taner Akbay , Tatsumi Ishihara , Kaveh Edalati

Bismuth (III) oxide (Bi2O3) has been highly studied as a photocatalyst for green hydrogen production due to its low band gap, yet its efficiency requires enhancement. This study synthesizes a defective and strained black Bi2O3 by severe…

材料科学 · 物理学 2024-12-03 Thanh Tam Nguyen , Kaveh Edalati

CO$_2$ photoreduction on photocatalysts is a nature-friendly solution to decrease the CO$_2$ amount, but the method still has low efficiency because of difficult separation and easy recombination of charge carriers in available catalysts.…

High-entropy oxides (HEOs), as a new family of materials with five or more principal cations, have shown promising properties for various applications. In this work and inspired by inherent defective and strained structure of HEOs,…

Generally adopted design strategies for enhancing the photocatalytic activity are aimed at tuning properties such as the visible light response, the exposed crystal facets, and the nanocrystal shape. Here, we present a different approach…

Photoreforming is a sustainable photocatalytic process that degrades plastic waste while simultaneously producing hydrogen (H2) from water. However, this process has received limited attention due to the scarcity of effective catalysts…

材料科学 · 物理学 2024-12-03 Thanh Tam Nguyen , Kaveh Edalati

Titanium dioxide is a photocatalytic substance of great practical importance. However, with its bandgap in the ultraviolet (UV) regime, native forms (undoped) of TiO2 generally exhibits poor photocatalytic activities under visible light.…

化学物理 · 物理学 2013-12-04 Mingzheng Wang , Ka-Kit Yee , Biao Nie , Hua Cheng , Jian Lu , Linbao Luo , Zhengtao Xu , Yang Yang Li

Titanium dioxide (TiO2) is a known photocatalyst with a capability of decomposing organic substance. However, the photocatalysis of the pure TiO2 is not effective for the indoor environment due to a lack of the ultraviolet irradiation…

应用物理 · 物理学 2019-05-17 Zhuoying Jiang , Xiong Yu

Excessive CO2 emission from fossil fuel usage has resulted in global warming and environmental crises. To solve this problem, the photocatalytic conversion of CO2 to CO or useful components is a new strategy that has received significant…

材料科学 · 物理学 2023-01-27 Saeid Akrami , Tatsumi Ishihara , Masayoshi Fuji , Kaveh Edalati

Adsorption of CO$_2$ on a semiconductor surface is a prerequisite for its photocatalytic reduction. Owing to superior photocorrosion resistance, nontoxicity and suitable band edge positions, TiO$_2$ is considered to be the most efficient…

材料科学 · 物理学 2018-12-05 Shashi B. Mishra , Aditya Choudhary , Somnath C. Roy , B. R. K. Nanda

TiO2 nanotube arrays grown by anodization were coated with thin layers of polydopamine as visible light sensitizer. The PDA-coated TiO2 scaffolds were used as photocatalyst for selective oxidation of benzyl alcohol under monochromatic…

材料科学 · 物理学 2016-10-18 Jyotsna Tripathy , Gabriel Loget , Marco Altomare , Patrik Schmuki

Black TiO2 with/without noble metal has been proposed for visible photocatalyst, still leaving poor catalyst efficiency. Alternatively, phase-mixed TiO2 such as anatase and rutile has been commonly used for visible catalysts with the…

Photocatalytic hydrogen (H2) production and carbon dioxide (CO2) conversion to methane (CH4) are considered promising solutions for reducing CO2 emissions. However, the development of highly active photocatalysts is essential to efficiently…

材料科学 · 物理学 2025-10-23 Jacqueline Hidalgo-Jimenez , Taner Akbay , Tatsumi Ishihara , Kaveh Edalati

"Black" TiO2 has gained increasing interest because of its outstanding properties and promising applications in a wide range of fields. Among the outstanding features of the material is that certain synthesis processes lead to the formation…

Visible-light photocatalyst titanium dioxide (TiO2) was successfully prepared via a novel and facile single-mode microwave assisted synthesis process. In this one-step synthesis, Ti as target material selectively oxides in magnetic field…

应用物理 · 物理学 2022-02-04 Kunihiko Katoa , Sebastien Vaucher , Patrik Hoffmann , Yunzi Xin , Takashi Shirai

Catalysis is indispensable to chemical processes and relevant to many aspects of modern life. Owing to the intriguing electronic structures and good ionic properties, multivalent transition metal oxides have attracted attention as key…

Converting CO$_2$ to useful compounds through the solar photocatalytic reduction has been one of the most promising strategies for artificial carbon recycling. The highly relevant photocatalytic substrate for CO$_2$ conversion has been the…

化学物理 · 物理学 2015-05-28 Shijing Tan , Yan Zhao , Jin Zhao , Zhuo Wang , Chuanxu Ma , Aidi Zhao , Bing Wang , Yi Luo , Jinlong Yang , Jianguo Hou

Oxygen vacancies in transition metal oxides facilitate catalysis critical for energy storage and generation. However, it has proven elusive to promote vacancies at the lower temperatures required for operation in devices such as metal-air…

材料科学 · 物理学 2016-06-08 Jonathan R. Petrie , Hyoungjeen Jeen , Sara C. Barron , Tricia L. Meyer , Ho Nyung Lee

Photocatalytic nitrogen fixation provides a promising route to produce reactive nitrogen compounds at benign conditions. Titania has been reported as an active photocatalyst for reduction of dinitrogen to ammonia; however there is little…

化学物理 · 物理学 2018-02-01 Benjamin M. Comer , Andrew J. Medford
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