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The hydrogen-bonding interpolymer complexation between poly(acrylic acid) (PAA) and the poly(N,N-dimethylacrylamide) (PDMAM) side chains of the negatively charged graft copolymer poly(acrylic acid-co-2-acrylamido-2-methyl-1-propane sulfonic…

软凝聚态物质 · 物理学 2009-11-11 Maria Sotiropoulou , Julian Oberdisse , Georgios Staikos

Thermal behaviors of hydroxypropyl cellulose dilute aqueous solutions with impurities of Group~I alkali metal ions (Li, Na, K, Rb and Cs chlorides) has been studied by means of static and dynamic light scattering measurements. From the…

软凝聚态物质 · 物理学 2025-04-08 Valery I. Kovalchuk

A grand challenge in designing polymeric materials is to tune their properties by macromolecular engineering. In this context, one of the drawbacks that often limits broader applications under high temperature conditions is their poor…

软凝聚态物质 · 物理学 2020-07-01 Daniel Bruns , Tiago Espinosa de Oliveira , Joerg Rottler , Debashish Mukherji

Metal-insulator-metal (MIM) nanogaps in canonical nanoparticle-on-mirror geometry (NPoM) provide deep-subwavelength confinement of light with mode volumes smaller than $V/V_0$ $<$ $10^{-6}$. However, access to these hotspots is limited by…

光学 · 物理学 2021-07-26 Rohit Chikkaraddy , Jeremy J Baumberg

The influence of shape fluctuations on deformable thermosensitive microgels in aqueous solution is investigated by dynamic light scattering (DLS) and depolarized dynamic light scattering (DDLS). The systems under study consist of a solid…

软凝聚态物质 · 物理学 2009-02-20 S. Bolisetty , M. Hoffmann , S. Lekkala , Th. Hellweg , M. Ballauff , L. Harnau

We introduced silica nanoparticles into poly ($N$,$N$-dimethylacrylamide) gel, (PDAM-NC gel), and poly (acrylamide) gel (PAM-NC gel), and carried out SAXS measurements under uniaxial elongation. It is well known that PDAM chains are…

软凝聚态物质 · 物理学 2016-01-05 Kengo Nishi , Mitsuhiro Shibayama

Applying ac voltages, we trapped gold nanoparticles between microfabricated electrodes under well-defined conditions. We demonstrate that the nanoparticles can be controllably fused together to form homogeneous gold nanowires with…

介观与纳米尺度物理 · 物理学 2007-05-23 L. Bernard , M. Calame , S. J. van der Molen , J. Liao , C. Schoenenberger

We systematically investigated and quantified how gold (Au) metal nanoparticles (NPs) optical spectra change upon introduction into biological tissue phantoms environment, in which the AuNPs can agglomerate. Quantitative knowledge of how…

应用物理 · 物理学 2021-03-17 J. C. R. Araujo , A. F. G. Monte , R. L. Serrano , W. Iwamoto , A. Antunes , O. Brener , M. Foschini

High-entropy alloy nanoparticles synthesized via laser ablation in liquid are promising for catalysis due to their ability to form simple solid solutions despite chemical complexity. In this study, noble metal HEA NPs (CuPdAgPtAu) are…

We present a model for structure formation, melting, and optical properties of gold/DNA nanocomposites. These composites consist of a collection of gold nanoparticles (of radius 50 nm or less) which are bound together by links made up of…

凝聚态物理 · 物理学 2009-11-10 Sung Yong Park , D. Stroud

We have used a gold nanohole array to trap single polystyrene nanoparticles, with a mean diameter of 30 nm, into separated hot spots located at connecting nanoslot regions. A high trap stiffness of approximately 0.85 fN/(nmmW) at a low…

光学 · 物理学 2019-08-16 Xue Han , Viet Giang Truong , Sile Nic Chormaic

The performance of gold nanoparticles (NPs) in applications depends critically on the structure of the NP-solvent interface, at which the electrostatic surface polarization is one of the key characteristics that affects hydration, ionic…

化学物理 · 物理学 2021-09-20 Zhujie Li , Victor G. Ruiz , Matej Kanduč , Joachim Dzubiella

We explore the influence of the nanoporous structure on the thermal relaxation of electrons and holes excited by ultrashort laser pulses ($\sim 7$ fs) in thin gold films. Plasmon decay into hot electron-hole pairs results in the generation…

A continuum, post-deposition mesoscopic model of a Moir\'e-regulated self-assembly of metal nanoclusters on a twisted bilayer graphene is presented. Quasi-two-dimensional nanocluster-like steady states at a low adsorbate coverage are…

介观与纳米尺度物理 · 物理学 2021-10-04 Mikhail Khenner , Lars Hebenstiel

We present results on electromigrated Au nanojunctions broken near the conductance quantum $77.5 \mu$S. At room temperature we find that wires, initially narrowed by an actively-controlled electromigration technique down to a few…

材料科学 · 物理学 2007-05-23 K. O'Neill , E. A. Osorio , H. S. J. van der Zant

By means of multicanonical computer simulations, we investigate thermodynamic properties of the aggregation of interacting semiflexible polymers. We analyze a mesoscopic bead-stick model, where nonbonded monomers interact via Lennard-Jones…

软凝聚态物质 · 物理学 2015-05-28 Christoph Junghans , Michael Bachmann , Wolfhard Janke

Nanoporous gold (np-Au) has found use in applications ranging from catalysis to biosensing where pore morphology plays a critical role in performance. While morphology evolution of bulk np-Au has been widely studied, knowledge about its…

材料科学 · 物理学 2024-02-20 Sadi Shahriar , Kavya Somayajula , Conner Winkeljohn , Jeremy Mason , Erkin Seker

Nanoparticle self-assembly is an efficient bottom-up strategy for the creation of nanostructures. In the standard approach, ligands are grafted on the surfaces of nanoparticles to keep them separated and control interparticle interactions.…

A polymer shell offers a unique opportunity to tailor structural and optical properties of optically functional nanoparticles and their ensembles. Here, we develop a process to coat Mie-resonant silicon nanospheres (Si NSs) with a…

材料科学 · 物理学 2025-05-12 Oanh Vu , Jialu Song , Hiroshi Sugimoto , Minoru Fujii

Stable and metastable metallic nanoparticles exhibit unique properties compared to the bulk, with potentially important applications for catalysis. This is in particular the case for the AgPt alloy that can exhibit the ordered L1$_1$…

材料科学 · 物理学 2023-07-11 F. Ait Hellal , J. Puibasset , C. Andreazza-Vignolle , P. Andreazza