相关论文: On the thermodynamic theory of curvature-dependent…
The interfacial tension of a liquid droplet surrounded by another liquid in the presence of microscopic ions is studied as a function of the droplet radius. An analytical expression for the interfacial tension is obtained within a linear…
The classical nucleation theory (CNT) concept of a nucleus as a fragment of the bulk new phase fails for nanosized nuclei. An extension of CNT taking into account the properties of the transition region between coexisting bulk phases is…
We demonstrate that the multi-phase Shan-Chen lattice Boltzmann method (LBM) yields a curvature dependent surface tension $\sigma$ as computed from three-dimensional hydrostatic droplets/bubbles simulations. Such curvature dependence is…
Surface tension is a macroscopic manifestation of the cohesion of matter, and its value $\sigma_\infty$ is readily measured for a flat liquid-vapor interface. For interfaces with a small radius of curvature $R$, the surface tension might…
We report on the size dependence of the surface tension of a free surface of an isotropic fluid. The size dependence of the surface tension is evaluated based on the Gibbs-Tolman-Koenig-Buff equation for positive and negative values of…
The influence of the surface curvature on the surface tension of small droplets at equilibrium with a surrounding vapour, or small bubbles at equilibrium with a surrounding liquid, can be expanded as {\gamma}(R) = {\gamma}(planar) - .../R +…
The curvature dependence of the surface tension is related to the excess equimolar radius of liquid drops, i.e., the deviation of the equimolar radius from that defined with the macroscopic capillarity approximation. Based on the Tolman [J.…
We redefine the surface tension coefficient for a nuclear Fermi-liquid drop with a finite diffuse layer. Following Gibbs-Tolman concept, we introduce the equimolar radius R_e of sharp surface droplet at which the surface tension is applied…
In this paper, using an unified approach, estimates are given of the magnitude of the surface tension of water for planar and curved interfaces in the pairwase interaction approximation based on the Lennard-Jones potential. It is shown that…
We evaluate how the curvature dependence of surface tension affects the shape of electrically charged interfaces between a perfectly conducting fluid and its vapour. We consider two cases: i) spherical droplets in equilibrium with their…
In this work I derive analytic expressions for the curvature dependent fluid-substrate surface tension of a hard sphere fluid on a hard curved wall. In a first step, the curvature thermodynamic properties are found as truncated power series…
The curvature dependence of interfacial free energy, which is crucial in quantitatively predicting nucleation kinetics and the stability of bubbles and droplets, can be described in terms of the Tolman length {\delta}. For solid-liquid…
We numerically check that the surface tension of membranes is independent of the shape of surface boundary. The surface tension is calculated by means of the Monte Carlo simulation technique on two types of cylinders made of rubans of size…
Surface tension in drops has been investigated mainly from a thermodynamic standpoint, more rarely with kinetic methods. In the present work, this problem is studied in the framework of kinetic theory, starting from Sutherland's…
We explore the pressure of active particles on curved surfaces and its relation to other interfacial properties. We use both direct simulations of the active systems as well as simulations of an equilibrium system with effective (pair)…
Interfacial flows close to a moving contact line are inherently multi-scale. The shape of the interface and the flow at meso- and macroscopic scales inherit an apparent interface slope and a regularization length, both called after Voinov,…
Efforts to estimate the magma decompression rate from the vesicular texture of volcanic products have progressed through the development of theoretical models and laboratory experiments. The theoretical model is based on nucleation theory,…
A new approach that is a combination of classical thermodynamics and macroscopic kinetics is offered for studying the nucleation kinetics in condensed binary solutions. The theory covers the separation of liquid and solid solutions…
With an aim to include the contribution of surface tension in the action of the boundary, we define the tangential pressure in terms of surface tension and Normal curvature in a more naturally geometric way. First, we show that the negative…
Combining analytic calculations, computer simulations, and classical density functional theory we determine the interfacial tension of orientable two-dimensional hard rectangles near a curved hard wall. Both a circular cavity holding the…