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The ionic selectivity of nanopores is crucial for the energy conversion based on nanoporous membranes. It can be significantly affected by various parameters of nanopores and the applied fields driving ions through porous membranes. Here,…

软凝聚态物质 · 物理学 2024-10-29 Chao Zhang , Mengnan Guo , Hongwen Zhang , Xiuhua Ren , Yinghao Gao , Yinghua Qiu

High-performance osmotic energy conversion requires both large ionic throughput and high ionic selectivity, which can be significantly promoted by exterior surface charges simultaneously, especially for short nanopores. Here, we investigate…

化学物理 · 物理学 2022-06-08 Long Ma , Xuan An , Fenhong Song , Yinghua Qiu

There has been tremendous experimental progress in the last decade in identifying the structure and function of biological pores (ion channels) and fabricating synthetic pores. Despite this progress, many questions still remain about the…

软凝聚态物质 · 物理学 2015-03-17 Michael Zwolak , James Wilson , Massimiliano Di Ventra

It has been recently shown that a viscosity gradient could drive electrical current through a negatively charged nanochannel (Wiener and Stein, arXiv: 1807.09106). To understand the physics underlying this phenomenon, we employed the…

流体动力学 · 物理学 2021-11-02 Amer Alizadeh , Hirofumi Daiguji , Anne M. Benneker

Single nanopores have attracted much scientific interest due to their versatile applications. The majority of experiments have been performed with nanopores being in contact with the same electrolyte on both sides of the membrane, while…

化学物理 · 物理学 2018-12-11 Yinghua Qiu , Zuzanna S. Siwy , Meni Wanunu

Solid-state nanopores are promising tools for single molecule detection of both DNA and proteins. In this study, we investigate the patterns of ionic current blockades as DNA translocates into or out of the geometric confinement of such…

生物物理 · 物理学 2017-04-05 Kaikai Chen , Nicholas A. W. Bell , Jinglin Kong , Yu Tian , Ulrich F. Keyser

Ionic transport in nanopores is a fundamentally and technologically important problem in view of its occurrence in biological processes and its impact on novel DNA sequencing applications. Using microscopic calculations, here we show that…

软凝聚态物质 · 物理学 2009-09-26 Michael Zwolak , Johan Lagerqvist , Massimiliano Di Ventra

In this paper we report the theory describing the electro-osmotic flow in charged nanopores with constant radius and charge density driven by alternating current. We solve the ion and solution transport in unsteady conditions as described…

化学物理 · 物理学 2018-10-17 J. Catalano , P. M. Biesheuvel

Short nanopores find extensive applications capitalizing on their high throughput and detection resolution. Ionic behaviors through long nanopores are mainly determined by charged inner-pore walls. When pore lengths decrease to sub-200 nm,…

化学物理 · 物理学 2024-02-19 Long Ma , Zhe Liu , Bowen Ai , Jia Man , Jianyong Li , Kechen Wu , Yinghua Qiu

Nanoporous membranes, leveraging their high-throughput characteristics, have been widely applied in fields such as molecular separation and energy conversion. Due to interpore interactions, besides the applied voltage and solution…

软凝聚态物质 · 物理学 2025-10-21 Hongwen Zhang , Bowen Ai , Zekun Gong , Tianyi Sui , Zuzanna S. Siwy , Yinghua Qiu

We investigate the ionic current modulation in DNA nanopore translocation setups by numerically solving the electrokinetic mean-field equations for an idealized model. Specifically, we study the dependence of the ionic current on the…

软凝聚态物质 · 物理学 2021-10-13 Kai Szuttor , Patrick Kreissl , Christian Holm

With controlled ionic current rectification (ICR) achieved through a strategically designed non-uniform surface charge distribution, short unipolar nanopores exhibit promising applications in nanofluidic sensors, ionic circuits, and ion…

化学物理 · 物理学 2025-12-08 Hongwen Zhang , Long Ma , Di Liu , Tianyi Sui , Zuzanna S. Siwy , Yinghua Qiu

Ionic current rectification (ICR) induced by electroosmotic flow (EOF) under concentration gradients can find many applications in micro/nanofluidic sensing and ionic circuits. Here, we focused on the cases with micropores of moderate…

化学物理 · 物理学 2025-10-21 Long Ma , Hongwen Zhang , Bowen Ai , Jiakun Zhuang , Guanghua Du , Yinghua Qiu

Short nanopores have various applications in biosensing, desalination, and energy conversion. Here, the modulation of charged exterior surfaces on ionic transport is investigated through simulations with sub-200 nm long nanopores under…

软凝聚态物质 · 物理学 2024-02-08 Long Ma , Zhe Liu , Jia Man , Jianyong Li , Zuzanna S. Siwy , Yinghua Qiu

Fundamental understanding of ionic transport at the nanoscale is essential for developing biosensors based on nanopore technology and new generation high-performance nanofiltration membranes for separation and purification applications. We…

Bipolar nanopores, with asymmetric charge distributions, can induce significant ionic current rectification (ICR) at ultra-short lengths, finding potential applications in nanofluidic devices, energy conversion, and other related fields.…

化学物理 · 物理学 2024-10-29 Hongwen Zhang , Long Ma , Chao Zhang , Yinghua Qiu

Porous graphene has high mechanical strength and atomic layer thickness, which make it a promising material for material separation and biomolecule sensing. Electrostatic interactions between charges in aqueous solution are a kind of strong…

化学物理 · 物理学 2016-08-02 Yinghua Qiu , Kun Li , Weiyu Chen , Wei Si , Qiyan Tan , Yunfei Chen

Ionic current rectification (ICR) of charged conical nanopores has various applications in fields including nanofluidics, bio-sensing, and energy conversion, whose function is closely related to the dynamic response of nanopores. The…

化学物理 · 物理学 2024-10-29 Zhe Liu , Long Ma , Hongwen Zhang , Jiakun Zhuang , Jia Man , Zuzanna S. Siwy , Yinghua Qiu

Membranes consist of pores and the walls of these pores are often charged. In contact with an aqueous solution, the pores fill with water and ions migrate from solution into the pores until chemical equilibrium is reached. The distribution…

化学物理 · 物理学 2024-03-06 R. Wang , M. Elimelech , P. M. Biesheuvel

Nanopores in solid state membranes are a tool able to probe nanofluidic phenomena or can act as a single molecular sensor. They also have diverse applications in filtration, desalination or osmotic power generation. Many of these…

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