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Separation of the two mirror images of a chiral molecule, the enantiomers, is a historically complicated problem of major relevance for biological systems. Since chiral molecules are optically active, it has been speculated that strong…

化学物理 · 物理学 2024-10-23 Rosario R. Riso , Matteo Castagnola , Enrico Ronca , Henrik Koch

The development of efficient techniques to distinguish mirror images of chiral molecules (enantiomers) is very important in both chemistry and physics. Enantiomers share most molecular properties except, for instance, the absorption of…

化学物理 · 物理学 2023-07-11 Rosario R. Riso , Laura Grazioli , Enrico Ronca , Tommaso Giovannini , Henrik Koch

Enantioselective photochemistry provides access to unique molecular structures and functions, with deep implications for fundamental science and industrial applications. Current methods for highly enantioselective photochemistry critically…

化学物理 · 物理学 2025-03-07 Andrés Ordóñez , Patricia Vindel-Zandbergen , David Ayuso

Detecting and controlling the chirality of materials play an essential role in exploring nature, providing new avenues for material creation, discrimination, and manipulation. In such tasks, chiral reagents are essential in defining or…

光学 · 物理学 2024-06-14 En-Ze Li , Ming-Xin Dong , Dong-Sheng Ding , Bao-Sen Shi , Guang-Can Guo , Franco Nori

Strong-field methods in solids enable new strategies for ultrafast nonlinear spectroscopy and provide all-optical insights into the electronic properties of condensed matter in reciprocal and real space. Additionally, solid-state media…

Chiral excited electronic states of molecules have an intrinsic sense of handedness, or twist, and are the active component in energy efficient display technologies and in new photosynthetic routes to produce pharmaceuticals. Creating…

Synthetic chiral light enables ultrafast and highly efficient imaging of molecular chirality. Unlike standard circularly polarized light, the handedness of synthetic chiral light does not rely on the spatial structure of the light field: it…

光学 · 物理学 2022-06-06 Laura Rego , David Ayuso

Microscopic origin of chirality and possible electric-field induced rotation and rotation-field induced electric polarization are investigated. By building up a realistic tight-binding model for elemental Te crystal in terms of…

材料科学 · 物理学 2022-10-18 Rikuto Oiwa , Hiroaki Kusunose

We introduce and theoretically analyze the concept of manipulating optical chirality via strong coupling of the optical modes of chiral nanostructures with excitonic transitions in molecular layers or semiconductors. With chirality being…

Chirality and chiral molecules are key elements in modern chemical and biochemical industries. Individual addressing, and the eventual separation of chiral enantiomers has been and still is an important elusive task in molecular physics and…

We explore a pure optical method for enantioselective orientation of chiral molecules by means of laser fields with twisted polarization. Several field implementations are considered, including a pair of delayed cross-polarized laser…

化学物理 · 物理学 2018-03-23 I. Tutunnikov , E. Gershnabel , S. Gold , I. Sh. Averbukh

Distinguishing between the left- and right-handed versions of a chiral molecule (enantiomers) is vital, but also inherently difficult. Traditional optical methods using elliptically or circularly polarized light rely on weak linear effects…

光学 · 物理学 2022-06-08 Laura Rego , David Ayuso

Biomolecules that constitute life on Earth are chiral, but the precise mechanism by which homochirality emerged remains a mystery. In this work it is demonstrated that reactions of radical pairs, where one of the radical electron spins is…

化学物理 · 物理学 2025-08-08 Thomas P Fay

Enantioselective orientation of chiral molecules excited by a shaped picosecond laser pulse and a delayed femtosecond pulse is considered. Using quantum mechanical simulations, we demonstrate a strong field-free enantioselective orientation…

光学 · 物理学 2022-03-31 Long Xu

Chirality is an intriguing property of certain molecules, materials or artificial nanostructures, which allows them to interact with the spin angular momentum of the impinging light field. Due to their chiral geometry, they can distinguish…

光学 · 物理学 2016-11-03 Peter Banzer , Pawel Wozniak , Uwe Mick , Israel De Leon , Robert W. Boyd

Enantiodetection is an important and challenging task across natural science. Nowadays, some chiroptical methods of enantiodetection based on decoherence-free cyclic three-level models of chiral molecules can reach the ultimate limit of the…

量子物理 · 物理学 2022-11-29 Chong Ye , Xiaowei Mu , Yifan Sun , Libin Fu , Xiangdong Zhang

Chirality is ubiquitous in nature and fundamental in science, from particle physics to metamaterials.The most established technique of chiral discrimination - photoabsorption circular dichroism - relies on the magnetic properties of a…

Chirality, the absence of mirror symmetry, is a fundamental molecular property with far-reaching consequences from chemistry to biology. Yet enantiosensitive optical responses are very weak. Here, we introduce a theoretical framework in…

光学 · 物理学 2026-01-12 Yang-Cheng Ye , Panpan Zhang , Ajay Jha , Fulu Zheng , Hong-Guang Duan

The use of biomaterials - with techniques such as DNA-directed assembly or bio-directed synthesis - can surpass top-down fabrication techniques in creating plasmonic superstructures, in terms of spatial resolution, range of functionality…

Controlling optical chirality at the subwavelength scales is essential for many applications of nanophotonic structures in polarization optics, sensing, and nonlinear photonics. Achieving a strong chiroptical response in planar dielectric…

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