相关论文: Deuterated Polycyclic Aromatic Hydrocarbons in the…

Small organic molecules are thought to provide building blocks for the formation of complex interstellar polycyclic aromatic hydrocarbons (PAHs). However, the underlying chemical mechanisms remain unclear, particularly concerning the role…

On the basis of arguments from galactic chemical evolution we suggest that the recent observations of D/H vs. metallicity in several high redshift absorbers are best understood if the primordial D value is in the range 2-3 10$^{-5}$. This…

The abundance of polycyclic aromatic hydrocarbons (PAHs) in low- and high-metallicity galaxies has been widely discussed since the time when detailed infrared data for extragalactic objects were first obtained. On the scales of entire…

Using a large collection of near-infrared spectra (2.5-5.4 um) of Galactic HII regions and HII region-like objects, we perform a systematic investigation of the astronomical polycyclic aromatic hydrocarbon (PAH) features. 36 objects were…

In this Letter we report the results of density functional theory calculations on medium-sized neutral Polycyclic Aromatic Hydrocarbon (PAH) molecules with armchair edges. These PAH molecules possess strong C-H stretching and bending modes…

This work presents theoretical calculations of infrared spectra of nitrogen (N)-containing polycyclic aromatic hydrocarbon (PAH) molecules with incorporation of N, NH and NH$_2$ using density functional theory (DFT). The properties of their…

While the abundance of elemental deuterium is relatively low (D/H ~ a few 1E-5), orders of magnitude higher D/H abundance ratios have been found for many interstellar molecules, enhanced by deuterium fractionation. In cold molecular clouds…

In this work we present the predictions of the ``two-infall model'' concerning the evolution of D, 3He and 4He in the solar vicinity, as well as their distribution along the Galactic disk. Our results show that, when adopting detailed…

Nitrogen-bearing polycyclic aromatic hydrocarbons (N-PAHs) are key precursors to complex organic molecules in both the interstellar medium and the nitrogen-rich planetary atmospheres. Despite the recent detections of nitrogen-functionalized…

We present recent UV laboratory spectra of various polycyclic aromatic hydrocarbons (PAHs) and explore the potential of these molecules as carriers of the DIBs. From a detailed comparison of gas-phase and Ne-matrix absorption spectra of…

Two key questions of the chemistry of Polycyclic Aromatic Hydrocarbons (PAHs) in the interstellar medium (ISM) are addressed: i) the way carbon is returned from PAHs to the interstellar gas after the very efficient accretion of C+ ions onto…

Using the AKARI, Wide-field Infrared Survey Explorer (WISE), Infrared Astronomical Satellite (IRAS), Sloan Digital Sky Survey (SDSS) and Hubble Space Telescope (HST) data, we investigated the relation of polycyclic aromatic hydrocarbon…

Polycyclic Aromatic Hydrocarbons (PAHs) are carbon-based molecules resulting from the union of aromatic rings and related species, which are likely responsible for strong infrared emission features (3.3, 6.2, 7.7, 8.6, 11.3 and 12.7…

The D/H ratio in interstellar gas varies on scales of a few hundred pc in the local Milky Way, with D/H values ranging from ~7 ppm to ~22 ppm. The reduction in D/H relative to the primordial value of D/H (~ 26 ppm) is usually attributed to…

Interstellar carbonaceous dust is mainly formed in the innermost regions of circumstellar envelopes around carbon-rich asymptotic giant branch (AGB) stars. In these highly chemically stratified regions, atomic and diatomic carbon, along…

(Abridged) Estimates of the interstellar deuterium abundance span a wide range of values. Here we study the evolution of deuterium in the framework of successful models for the chemical evolution of the Milky Way able to reproduce the…

The theory of Big Bang nucleosynthesis, coupled with an estimate of the primordial deuterium abundance (D/H)_pr, offers insights into the baryon density of the Universe. Independently, the baryon density can be constrained during a…

A new observation of D in a primordial gas cloud, made using the high resolution spectrograph at the Keck telescope, indicates an abundance $ D/H =(1.9-2.5) \times 10^{-4}$ \cite{SCHR}. Since deuterium is destroyed by stars, and the…

We performed mid-infrared spectroscopic observations of 18 local dusty elliptical galaxies by using the Infrared Spectrograph (IRS) on board Spitzer. We have significantly detected polycyclic aromatic hydrocarbon (PAH) features from 14 out…

Dust grains absorb half of the radiation emitted by stars throughout the history of the universe, re-emitting this energy at infrared wavelengths. Polycyclic aromatic hydrocarbons (PAHs) are large organic molecules that trace…