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Insulators containing chains of magnetic transition metal cations provide platforms for probing spin-$\frac{1}{2}$ dynamics and quantum critical behavior. Li$_2$CoCl$_4$ contains edge-sharing CoCl$_6$ octahedra that form chains along the…

强关联电子 · 物理学 2025-09-08 Zachary W. Riedel , Mykhaylo Ozerov , Stuart Calder , Daniel P. Shoemaker

In this study the magnetic order of the spin-1/2 XXZ chain system Cs$_2$CoCl$_4$ in a temperature range from 50 mK to 0.5 K and in applied magnetic fields up to 3.5 T is investigated by high-resolution measurements of the thermal expansion…

强关联电子 · 物理学 2015-03-13 O. Breunig , M. Garst , A. Rosch , E. Sela , B. Buldmann , P. Becker , L. Bohaty , R. Müller , T. Lorenz

We have investigated the magnetic and magnetocaloric properties of antiferromagnetic Ising spin chain CoV$_{2}$O$_{6}$ by magnetization and heat capacity measurements. Both monoclinic $\alpha$-CoV$_{2}$O$_{6}$ and triclinic…

强关联电子 · 物理学 2016-05-04 M. Nandi , P. Mandal

A positive muon spin rotation and relaxation ($\mu^+$SR) experiment on [Ca$_2$CoO$_3$]$_{0.62}$[CoO$_2$], ({\sl i.e.}, Ca$_3$Co$_4$O$_9$, a layered thermoelectric cobaltite) indicates the existence of two magnetic transitions at $\sim$ 100…

强关联电子 · 物理学 2009-11-10 J. Sugiyama , J. H. Brewer , E. J. Ansaldo , H. Itahara , K. Dohmae , Y. Seno , C. Xia , T. Tani

Co10Ge3O16 crystallizes in an intergrowth structure featuring alternating layers of spinel and rock salt. Variable-temperature powder synchrotron X-ray and neutron diffraction, magnetometry, and heat capacity experiments reveal a…

材料科学 · 物理学 2013-07-12 Phillip T. Barton , Ram Seshadri , Anna Llobet , Matthew R. Suchomel

We report on a 59Co NMR investigation of the trigonal cobaltate Ca3Co2O6 carried out on a single crystal, providing precise determinations of the electric field gradient and chemical shift tensors, and of the internal magnetic fields at the…

强关联电子 · 物理学 2015-05-20 G. Allodi , R. De Renzi , S. Agrestini , C. Mazzoli , M. R. Lees

The antiferromagnetic - ferromagnetic phase transition in YBaCo2O5.50 and YBaCo2O5.44 cobaltites with different types of oxygen-ion ordering in the [YO0.5/0.44] layers has been studied by neutron powder diffraction. Using the magnetic…

材料科学 · 物理学 2007-05-23 D. D. Khalyavin , D. N. Argyriou , U. Amann , A. A. Yaremchenko , V. V. Kharton

We present the magnetic properties of complete solid solutions of ZnCr$_2$O$_4$ and CoCr$_2$O$_4$: two well-studied oxide spinels with very different magnetic ground states. ZnCr$_2$O$_4$, with non-magnetic $d^{10}$ cations occupying the A…

材料科学 · 物理学 2009-06-04 Brent C. Melot , Jennifer E. Drewes , Ram Seshadri , Arthur P. Ramirez

We describe neutron scattering experiments performed to investigate the magnetic order and dynamics of half-doped La1.5Sr0.5CoO4. This layered perovskite exhibits a near-ideal checkerboard pattern of Co2+/Co3+ charge order at temperatures…

CoSe$_2$O$_5$ has a crystal structure consisting of zig-zag chains of edge shared CoO$_6$ octahedra running along the c axis, with the chains separated by Se$_2$O$_5^{2-}$ units. Magnetic susceptibility measurements indicate a transition at…

材料科学 · 物理学 2012-02-02 Brent C. Melot , Brian Paden , Ram Seshadri , Ambesh Dixit , Gavin Lawes , Emmanuelle Suard

Heat-capacity behavior in the presence of externally applied magnetic field (H) up to 140 kOe is investigated (2-35 K) for the quasi-1-dimensional compound, Ca3Co2O6, believed to order magnetically with the so-called partially disordered…

强关联电子 · 物理学 2009-11-10 E. V. Sampathkumaran , Z. Hiroi , S. Rayaprol , Y. Uwatoko

Co4Nb2O9 (CNO) having {\alpha}-Al2O3 crystal structure with Co chains along c-direction shows gigantic magnetoelelctric coupling below antiferromagnetic ordering temperature of 27 K but above a spin flop field of 1.6 T. We have investigated…

材料科学 · 物理学 2016-06-16 C. Dhanasekhar , S. K. Mishra , R. Rawat , A. K. Das , A. Venimadhav

To study the relationship between the properties of low-dimensional spin systems with weakly coupled Cu-triangles and their crystal structure, single crystals of $Cs_3Cu_3Cl_8OH$ (1) and the new $Cs_3Cu_3Cl_{7.6}Br_{0.4}OH$ (2) were grown.…

We have investigated the temperature and magnetic field dependence of magnetization ($M$), specific heat ($C_p$), and relative sample length change ($\Delta L/L_0$) for understanding the field-induced metamagnetic transitions in…

强关联电子 · 物理学 2016-01-20 M. Nandi , P. Mandal

Identifying and characterizing new magnetic systems with Co2+ ions can enhance our understanding of quantum behavior since Co2+ can host a pseudospin-1/2 magnetic ground state. Understanding the magnetic ground state and the phase diagrams…

Cs2CuCl4 is known to possess a quantum spin liquid phase with antiferromagnetic interaction below 2.8 K. We report the observation of a new metastable magnetic phase of the triangular frustrated quantum spin system Cs2CuCl4 induced by the…

We report the magnetism and transport measurements of CaCo$_2$As$_2$ and Ca$_{0.9}$Sr$_{0.1}$Co$_2$As$_2$ single crystals. Antiferromagnetic transition was observed at about 70 K and 90 K for CaCo$_2$As$_2$ and…

强关联电子 · 物理学 2012-06-15 J. J. Ying , Y. J. Yan , A. F. Wang , Z. J. Xiang , P. Cheng , G. J. Ye , X. H. Chen

The magnetic and structural phase transitions occurring in K$_2$ReCl$_6$ were studied by macroscopic and microscopic techniques. Structural phase transitions associated with rotations of the ReCl$_6$ octahedra lower the symmetry from cubic…

The magnetic-field and temperature dependencies of ultrasound propagation and magnetization of single-crystalline CoCr2O4 have been studied in static and pulsed magnetic fields up to 14 T and 62 T, respectively. Distinct anomalies with…

Although (CH3)2NH2CuCl3 (MCCL) was first examined in the 1930's [1], there are open questions regarding the magnetic dimensionality and nature of the magnetic properties. MCCL is proposed to be a S=1/2 alternating ferromagnetic…

强关联电子 · 物理学 2009-11-11 M. B. Stone , W. Tian , T. P. Murphy , S. E. Nagler , D. G. Mandrus
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