相关论文: Polycyclic Aromatic Hydrocarbon Size Tracers
Based on theoretical spectra computed using Density Functional Theory we study the properties of Polycyclic Aromatic Hydrocarbons (PAH). In particular using bin-average spectra of PAH molecules with varying number of carbons we investigate…
We present a new method to accurately describe the ionization fraction and the size distribution of polycyclic aromatic hydrocarbons (PAHs) within astrophysical sources. To this purpose, we have computed the mid-infrared emission spectra of…
We report new correlations between ratios of band intensities of the 15-20 {\mu}m emission bands of polycyclic aromatic hydrocarbons (PAHs) in a sample of fifty-seven sources observed with Spitzer/IRS. This sample includes Large Magellanic…
Intensity ratios of aromatic emission features are widely used to diagnose the size and ionization state of polycyclic aromatic hydrocarbons (PAHs) in astronomical environments. However, PAHs are known to typically carry aliphatic side…
The mid-infrared (IR; 5-15~$\mu$m) spectrum of a wide variety of astronomical objects exhibits a set of broad emission features at 6.2, 7.7, 8.6, 11.3 and 12.7 $\mu$m. About 30 years ago it was proposed that these signatures are due to…
The mid-infrared spectra of large PAHs ranging from C54H18 to C130H28 are determined computationally using Density Functional Theory. Trends in the band positions and intensities as a function of PAH size, charge and geometry are discussed.…
The observed variations in profiles of the interstellar aromatic infrared bands correlate with the object type and are indicative of PAH populations existing i n different sources. Spectroscopic studies on PAHs can provide tools for the int…
The search for large polycyclic aromatic hydrocarbons (PAHs) with over 100 carbon atoms is crucial to resolving the origin of unidentified infrared emission (UIE) bands. These bands are commonly observed in nebulae and the interstellar…
We present a charge distribution based model that computes the infrared spectrum of polycyclic aromatic hydrocarbon (PAH) molecules using recent measurements or quantum chemical calculations of specific PAHs. The model is applied to a…
Ratios of polycyclic aromatic hydrocarbon (PAH) vibrational bands are a promising tool for measuring the properties of the PAH population and their effect on star formation. The photometric bands of the MIRI and NIRCam instruments on JWST…
We present a systematic study of mid-infrared spectra of galaxies including star-forming galaxies and Active Galactic Nuclei observed with JWST MIRI-MRS and NIRSpec-IFU. We focus on the relative variations of the 3.3, 6.2, 7.7, 11.3, 12.7…
We extend the prediction of vibrational spectra to large sized polycyclic aromatic hydrocarbon (PAH) molecules comprising up to \sim 1500 carbon atoms by evaluating the efficiency of several computational chemistry methodologies. We employ…
We decompose the observed 7.7 $\mu$m polycyclic aromatic hydrocarbon (PAH) emission complexes in a large sample of over 7000 mid-infrared spectra of the interstellar medium (ISM) using spectral cubes observed with the Spitzer/IRS-SL…
The polycyclic aromatic hydrocarbon (PAH) hypothesis proposes that the aromatic infrared bands (AIBs) observed at 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 mic originate from gas-phase PAH molecules. These bands exhibit consistent peak wavelengths…
Context. The 3.3 $\mu$m aromatic C-H stretching band of polycyclic aromatic hydrocarbon (PAH) molecules seen in a wide variety of astrophysical regions is often accompanied by a series of weak satellite bands at ~3.4-3.6 $\mu$m. One of…
In this Letter we report the results of density functional theory calculations on medium-sized neutral Polycyclic Aromatic Hydrocarbon (PAH) molecules with armchair edges. These PAH molecules possess strong C-H stretching and bending modes…
Infrared emission from polycyclic aromatic hydrocarbons (PAHs) play a major role in determining the charge balance of their host environments that include photo-dissociation regions (PDRs) in galaxies, planetary nebulae, and rims of…
Utilizing the data and tools provided through the NASA Ames PAH IR Spectroscopic Database (PAHdb), we study the PAH component of over 900 Spitzer-IRS galaxy spectra. Employing a database-fitting approach, the average PAH size, the PAH size…
We study the Polycyclic Aromatic Hydrocarbons (PAH) bands, ionic emission lines, and Mid-infrared continuum properties, in a sample of 171 emission line galaxies taken from literature plus 15 new active galactic nuclei (AGN) Spitzer…
Polycyclic Aromatic Hydrocarbons (PAHs) are considered as a major constituent of interstellar dust. They have been proposed as the carriers of the Aromatic Infrared Bands (AIBs) observed in emission in the mid-IR. They likely have a…