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Grain size engineering, particularly reducing grain size into the nanocrystalline regime, offers a promising pathway to further improve the strength-to-weight ratio of Al alloys. Unfortunately, the fabrication of nanocrystalline metals…

材料科学 · 物理学 2021-10-07 Tianjiao Lei , Jungho Shin , Daniel S. Gianola , Timothy J. Rupert

Although nanocrystalline alloys regularly exhibit high strengths, their use in structural applications often face challenges due to sample size limitations, unstable microstructures, and the limited ability to plastically deform. The…

Amorphous complexions have recently been demonstrated to simultaneously enhance the ductility and stability of certain nanocrystalline alloys. In this study, three quinary alloys (Cu-Zr-Hf-Mo-Nb, Cu-Zr-Hf-Nb-Ti, and Cu-Zr-Hf-Mo-W) are…

材料科学 · 物理学 2022-02-02 Charlette M. Grigorian , Timothy J. Rupert

Solid solution addition and grain boundary segregation have been independently shown to enhance the strength of nanocrystalline alloys. In the present study, the synergy between these two effects is investigated in nanocrystalline Ni-Cr-Y…

材料科学 · 物理学 2026-05-13 Yi Liu , Jason R. Trelewicz , Timothy J. Rupert

Amorphous interfacial complexions have been shown to restrict grain growth and improve damage tolerance in nanocrystalline alloys, with increased chemical complexity stabilizing the complexions themselves. Here, we investigate local…

The mechanical behavior of two nanocrystalline Al alloys, Al-Mg-Y and Al-Fe-Y, is investigated with in-situ micropillar compression testing. Both alloys were strengthened by a hierarchical microstructure including grain boundary…

材料科学 · 物理学 2022-08-02 Tianjiao Lei , Esther C. Hessong , Jungho Shin , Daniel S. Gianola , Timothy J. Rupert

Grain boundary engineering via dopant segregation can dramatically change the properties of a material. For metallic systems, most current studies concerning interfacial segregation and subsequent transitions of grain boundary structure are…

材料科学 · 物理学 2018-12-26 Yang Hu , Timothy J. Rupert

Yttrium and its alloys are promising materials for high-tech applications, particularly in aerospace and nuclear reactors. The doping of metallic elements at grain boundaries can significantly influence the stability, strength, and…

材料科学 · 物理学 2024-11-20 Guanlin Lyu , Yuguo Sun , Ping Qian , Panpan Gao

Complexions are phase-like interfacial features that can influence a wide variety of properties, but the ability to predict which material systems can sustain these features remains limited. Amorphous complexions are of particular interest…

材料科学 · 物理学 2017-08-22 Jennifer D. Schuler , Timothy J. Rupert

Amorphous grain-boundary (GB) complexions in thermally stable nanocrystalline alloys are commonly assumed to be structurally homogeneous, yet their disordered nature makes them susceptible to local short-range ordering (SRO). The influence…

材料科学 · 物理学 2026-05-27 Frederic Sansoz , Eve-Audrey Picard

Amorphous grain boundary complexions have been shown to increase the plasticity of nanocrystalline alloys as compared to ordered grain boundaries. Here, the effect of an important structural descriptor, amorphous complexion thickness, on…

Amorphous grain boundary complexions have been shown to be radiation tolerant interfaces that can also reduce grain boundary embrittlement, marking them as favorable microstructural features. However, the incorporation of these features…

材料科学 · 物理学 2026-04-23 Prince Sharma , Jaime Marian , Jason R. Trelewicz , Timothy J. Rupert

Unique nanorod precipitates with a core-shell structure are found to nucleate from the grain boundaries of a bulk nanocrystalline Al-Ni-Y alloy fabricated via powder consolidation, contributing significantly to stabilization and…

材料科学 · 物理学 2022-01-05 Tianjiao Lei , Mingjie Xu , Jungho Shin , Daniel S. Gianola , Timothy J. Rupert

Nanocrystalline metal alloys show great potential as structural materials, but are often only available in small volumes such as thin films or powders. However, recent research has suggested that dopant segregation and grain boundary…

材料科学 · 物理学 2019-07-01 Olivia K. Donaldson , Timothy J. Rupert

Interfacial segregation can stabilize grain structures and even lead to grain boundary complexion transitions. However, understanding of the complexity of such phenomena in polycrystalline materials is limited, as most studies focus on…

材料科学 · 物理学 2021-07-02 P Garg , Z Pan , V Turlo , TJ Rupert

Building on the recent discovery of tough nanocrystalline Cu-Zr alloys with amorphous intergranular films, this paper investigates ternary nanocrystalline Cu-Zr-Hf alloys with a focus on understanding how alloy composition affects the…

材料科学 · 物理学 2019-08-16 Charlette M. Grigorian , Timothy J. Rupert

Achieving a combination of high mechanical strength and high electrical conductivity in low-weight Al alloys requires a full understanding of the relationships between nanoscaled features and physical properties. Grain boundary…

材料科学 · 物理学 2020-08-27 Xavier Sauvage , Fabien Cuvilly , Alan Russell , Kaveh Edalati

Grain boundary-based mechanisms are known to control the plastic deformation and failure of nanocrystalline metals, with manipulation of the boundary structure a promising path for tuning this response. In this study, the role of…

材料科学 · 物理学 2021-05-26 Jenna L. Wardini , Charlette M. Grigorian , Timothy J. Rupert

Segregation engineering has emerged as a promising pathway towards designing thermally stable nanocrystalline alloys with enhanced mechanical properties. However, the compositional and processing space for solute stabilized microstructures…

材料科学 · 物理学 2023-08-31 W. Streit Cunningham , Jungho Shin , Tianjiao Lei , Timothy J Rupert , Daniel S. Gianola

Solute segregation is used to limit grain growth in nanocrystalline metals, but this stabilization often breaks down at high temperatures. Amorphous intergranular films can form in certain alloys at sufficiently high temperatures, providing…

材料科学 · 物理学 2018-05-16 Jennifer D. Schuler , Olivia K. Donaldson , Timothy J. Rupert
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