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A stochastic model for the dynamics of enzymatic catalysis in explicit, effective solvents under physiological conditions is presented. Analytically-computed first passage time densities of a diffusing particle in a spherical shell with…

生物大分子 · 定量生物学 2015-06-04 Jeremy Schofield , Paul Inder , Raymond Kapral

Current theories of diffusiophoresis in porous media are limited to a porous medium saturated with a valence symmetric electrolyte. A predictive model for diffusiophoresis in porous media saturated with a valence asymmetric electrolyte, or…

软凝聚态物质 · 物理学 2024-12-03 Siddharth Sambamoorthy , Henry C. W. Chu

We study the phase behaviour of a binary mixture of colloidal hard spheres and freely-jointed chains of beads using Monte Carlo simulations. Recently Panagiotopoulos and coworkers predicted [Nat. Commun. 5, 4472 (2014)] that the hexagonal…

软凝聚态物质 · 物理学 2016-08-24 John R Edison , Tonnishtha Dasgupta , Marjolein Dijkstra

We use dynamic light scattering and computer simulations to study equilibrium dynamics and dynamic heterogeneity in concentrated suspensions of colloidal hard spheres. Our study covers an unprecedented density range and spans seven decades…

DNA is now firmly established as a versatile and robust platform for achieving synthetic nanostructures. While the folding of single molecules into complex structures is routinely achieved through engineering basepair sequences, much less…

软凝聚态物质 · 物理学 2025-05-15 Soumen De Karmakar , Thomas Speck

Past experimental observations of gas-liquid and gas-crystal coexistence in low-salinity suspensions of highly charged colloids have suggested the existence of like charge attraction. Evidence for this phenomenon was also observed in…

软凝聚态物质 · 物理学 2025-12-23 Thijs ter Rele , René van Roij , Marjolein Dijkstra

When polyelectrolyte-neutral block copolymers are mixed in solutions to oppositely charged species (e.g. surfactant micelles, macromolecules, proteins etc), there is the formation of stable supermicellar aggregates combining both…

软凝聚态物质 · 物理学 2007-05-23 J. -F. Berret , K. Yokota , M. Morvan

Dynamic processes in dispersions of charged spherical particles are of importance both in fundamental science, and in technical and bio-medical applications. There exists a large variety of charged-particles systems, ranging from…

软凝聚态物质 · 物理学 2013-11-25 G. Nägele , M. Heinen , A. J. Banchio , C. Contreras-Aburto

Conducting Polymer Dendrites (CPD) are truly inspiring for unconventional electronics that shapes topological circuitries evolving upon an application. Driven by electrochemical processes, an electrochemical impedance rules signal…

应用物理 · 物理学 2024-07-02 Antoine Baron , Enrique Hernández-Balaguera , Sébastien Pecqueur

Phase separation in salt-free symmetric mixtures of oppositely charged rodlike polyelectrolytes is studied using quasi-analytical calculations. Stability analyses for the isotropic-isotropic and the isotropic-nematic phase transitions in…

软凝聚态物质 · 物理学 2010-07-20 Rajeev Kumar , Debra Audus , Glenn H. Fredrickson

Colloidal suspensions with free polymer coils which are larger than the colloidal particles are considered. The polymer-colloid interaction is modeled by an extension of the Asakura-Oosawa model. Phase separation occurs into dilute and…

软凝聚态物质 · 物理学 2009-10-31 Richard P. Sear

Concentrated colloidal suspensions are a well-tested model system which has a glass transition. Colloids are suspensions of small solid particles in a liquid, and exhibit glassy behavior when the particle concentration is high; the…

软凝聚态物质 · 物理学 2010-10-01 Luca Cipelletti , Eric R. Weeks

The equilibrium phase diagram of a 1:1 symmetrical mixture composed of oppositely charged colloids is calculated using Monte Carlo simulations. We model the system by the DLVO effective interaction potential. The phase diagram is similar to…

软凝聚态物质 · 物理学 2007-05-23 José B. Caballero , Antonio M. Puertas

The adsorption of highly \textit{oppositely} charged flexible polyelectrolytes (PEs) on a charged planar substrate is investigated by means of Monte Carlo (MC) simulations. We study in detail the equilibrium structure of the first few PE…

软凝聚态物质 · 物理学 2007-05-23 Rene Messina

We investigate with Monte Carlo computer simulations the capillary phase behaviour of model colloid-polymer mixtures confined between a flat wall and a corrugated wall. The corrugation is modelled via a sine wave as a function of one of the…

软凝聚态物质 · 物理学 2014-06-20 Andrea Fortini , Matthias Schmidt

Using Monte Carlo simulations, we investigate the structural characteristics of an interacting hard sphere system with shifted charge to elucidate the effect of the non-centrosymmetric interaction on its phase behavior. Two different phase…

化学物理 · 物理学 2014-04-28 Luis E. Sánchez-Díaz , Chwen-Yang Shew , Xin Li , Bin Wu , Gregory S. Smith , Wei-Ren Chen

Using molecular dynamics simulations we study the slow dynamics of a hard sphere fluid confined in a disordered porous matrix. The presence of both discontinuous and continuous glass transitions as well as the complex interplay between…

软凝聚态物质 · 物理学 2009-09-29 Jan Kurzidim , Daniele Coslovich , Gerhard Kahl

A theoretical model of vapor-liquid phase transition in a system of charged hard cores of different diameters is suggested (with the parameters of the transition obtained in a number of studies using the Monte Carlo method). The model is…

等离子体物理 · 物理学 2007-05-23 A. L. Khomkin , I. A. Mulenko

Purely quantum electron systems exhibit intriguing correlated electronic phases by virtue of quantum fluctuations in addition to electron-electron interactions. To realize such quantum electron systems, a key ingredient is dense electrons…

The coherent dynamics of bubble clusters in liquid are of fundamental and industrial importance and are elusive due to the complex interactions of disordered bubble oscillations. Here we introduce and demonstrate unsupervised learning of…

流体动力学 · 物理学 2024-06-03 Kazuki Maeda , Daniel Fuster