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The reactivity of interstellar carbon atoms (C) on the water-dominated ices is one of the possible ways to form interstellar complex organic molecules (iCOMs). In this work, we report a quantum chemical study of the coupling reaction of C…

星系天体物理 · 物理学 2023-10-24 Stefano Ferrero , Cecilia Ceccarelli , Piero Ugliengo , Mariona Sodupe , Albert Rimola

Interstellar complex organic molecules (iCOMs) can be loosely defined as chemical compounds with at least six atoms in which at least one is carbon. The observations of iCOMs in star-forming regions have shown that they contain an important…

太阳与恒星天体物理 · 物理学 2019-09-30 Joan Enrique-Romero , Albert Rimola , Cecilia Ceccarelli , Piero Ugliengo , Nadia Balucani , Dimitrios Skouteris

Simple and complex organic molecules (COMs) are observed along different phases of star and planet formation and have been successfully identified in prestellar environments such as dark and translucent clouds. Yet the picture of organic…

Icy interstellar dust grains are a source of complex organic molecule (COM) production, although their formation mechanisms are debated. Laboratory experiments show that atomic C deposited onto interstellar ice analogs can react with…

星系天体物理 · 物理学 2025-10-27 Sydney A. Willis , Serge A. Krasnokutski , Nathaniel J. Morin , Robin T. Garrod

Acetaldehyde (CH$_3$CHO) is one of the most detected interstellar Complex Organic Molecule (iCOM) in the interstellar medium (ISM). These species have a potential biological relevance, as they can be precursors of more complex species from…

星系天体物理 · 物理学 2023-08-15 Jessica Perrero , Piero Ugliengo , Cecilia Ceccarelli , Albert Rimola

The formation of the interstellar complex organic molecules (iCOMs) is a hot topic in astrochemistry. One of the main paradigms trying to reproduce the observations postulates that iCOMs are formed on the ice mantles covering the…

星系天体物理 · 物理学 2022-03-30 Joan Enrique-Romero , Albert Rimola , Ceccarelli , Piero Ugliengo , Nadia Balucani , Dimitrios Skouteris

Ice chemistry in the dense, cold interstellar medium (ISM) is probably responsible for the formation of interstellar complex organic molecules (COMs). Recent laboratory experiments performed at T=4 K have shown that irradiation of CO:N2 ice…

星系天体物理 · 物理学 2024-01-09 Rafael Martín-Doménech , Alexander DelFranco , Karin I. Öberg , Mahesh Rajappan

The simultaneous detection of organic molecules of the form C$_2$H$_{\text{n}}$O, such as ketene (CH$_2$CO), acetaldehyde (CH$_3$CHO), and ethanol (CH$_3$CH$_2$OH), toward early star-forming regions offers hints of shared chemical history.…

星系天体物理 · 物理学 2021-06-16 K. -J. Chuang , G. Fedoseev , C. Scirè , G. A. Baratta , C. Jäger , Th. Henning , H. Linnartz , M. E. Palumbo

A prevailing theory for the interstellar production of complex organic molecules (COMs) involves formation on warm dust-grain surfaces, via the diffusion and reaction of radicals produced through grain-surface photodissociation of stable…

星系天体物理 · 物理学 2020-08-19 Mihwa Jin , Robin T. Garrod

Complex Organic Molecules (COMs) have been detected in the interstellar medium (ISM). However, it is not clear whether their synthesis occurs on the icy surfaces of interstellar grains or via a series of gas-phase reactions. As a test case…

地球与行星天体物理 · 物理学 2016-03-31 Joan Enrique-Romero , Albert Rimola , Cecilia Ceccarelli , Nadia Balucani

The solid-state C$_2$H$_2$ chemistry in interstellar H$_2$O-rich ice has been proposed to explain astronomically observed complex organic molecules (COMs), including ketene (CH$_2$CO), acetaldehyde (CH$_3$CHO), and ethanol (CH$_3$CH$_2$OH),…

星系天体物理 · 物理学 2024-05-14 K. -J. Chuang , C. Jäger , J. C. Santos , Th. Henning

The interstellar medium is characterized by a rich and diverse chemistry. Many of its complex organic molecules are proposed to form through radical chemistry in icy grain mantles. Radicals form readily when interstellar ices (composed of…

星系天体物理 · 物理学 2016-09-13 Karin I. Oberg

Interstellar complex organic molecules (iCOMs) are assumed to be mainly formed on dust-grain surfaces. However, neutral gas-phase reactions in the interstellar medium (ISM) can play an important role. In this paper, by investigating the…

星系天体物理 · 物理学 2020-09-09 F. Tonolo , J. Lupi , C. Puzzarini , V. Barone

Complex organic molecules (COMs) have been identified toward high- and low-mass protostars as well as molecular clouds, suggesting that these interstellar species originate from the early stage(s) of starformation. The reaction pathways…

太阳与恒星天体物理 · 物理学 2020-04-08 K. -J. Chuang , G. Fedoseev , D. Qasim , S. Ioppolo , C. Jäger , Th. Henning , M. E. Palumbo , E. F. van Dishoeck , H. Linnartz

Isolated dense molecular cores are investigated to study the onset of complex organic molecule formation in interstellar ice. Sampling three cores with ongoing formation of low-mass stars (B59, B335, and L483) and one starless core (L694-2)…

星系天体物理 · 物理学 2020-12-02 Laurie E. U. Chu , Klaus W. Hodapp , A. C. Adwin Boogert

The recent observation of complex organic molecules (COMs) in interstellar ices by the James Webb Space Telescope (JWST), along with previous gas-phase detections, underscores the importance of grain surface and ice mantle chemistry in the…

星系天体物理 · 物理学 2025-12-16 Ryota Ichimura , Hideko Nomura , Kenji Furuya , Tetsuya Hama , T. J. Millar

Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…

星系天体物理 · 物理学 2015-05-14 H. M. Cuppen , E. F. van Dishoeck , E. Herbst , A. G. G. M. Tielens

The interaction of carbon atoms with solid carbon monoxide (CO) is a fundamental process in astrochemistry, influencing the formation of complex organic molecules in interstellar environments. This study investigates the adsorption and…

星系天体物理 · 物理学 2025-09-23 Masashi Tsuge , Germán Molpeceres , Ryota Ichimura , Hideko Nomura , Kenji Furuya , Naoki Watanabe

Interstellar grains are known to be important actors in the formation of interstellar molecules such as H$_2$, water, ammonia, and methanol. It has been suggested that the so-called interstellar complex organic molecules (iCOMs) are also…

In cold molecular clouds, UV photolysis of icy grain mantles generates radicals that lead to new molecule formation. When radical diffusion is limited by low temperatures, oxygen atom addition and insertion reactions, enabled by photolysis…

星系天体物理 · 物理学 2025-07-29 Michelle R. Brann , Karin I. Öberg , Mahesh Rajappan
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