相关论文: Cavity Click Chemistry: Cavity-Catalyzed Azide-Alk…
The ability to control chemical reactions by coupling organic molecules to confined light in a cavity has recently attracted much attention. While most previous studies have focused on single-mode photonic or plasmonic cavities, here we…
Material science is an important foundation of modern society development, covering significant areas like chemosynthesis and metamaterials. Click chemistry provides a simple and efficient paradigm for achieving molecular diversity by…
Quantum electrodynamics coupled-cluster (QED-CC) theory is used to model vacuum-field-induced changes to ground-state properties of a series of sodium halide compounds (NaX, X = F, Cl, Br, I) strongly coupled to an optical cavity.…
The additive-free tetrazine/enol ether click reaction was performed in ultra-high vacuum (UHV) with an enol ether group covalently linked to a silicon surface: Dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate molecules were coupled to the enol…
Suggestion of modifications of finite-dimensional QED models are proposed for interpreting chemical reactions in terms of artificial atoms and molecules on quantum dots placed in optical cavities. Moving both photons and atoms is possible…
Synthesis of organic bi-layers on silicon was realized by a combination of surface functionalization under ultra-high vacuum (UHV) conditions and solution-based click chemistry. The silicon (001) surface was prepared with a high degree of…
A major trend within the field of cavity QED is to boost the interaction strength between the cavity field and the atomic internal degrees of freedom of the trapped atom by decreasing the mode volume of the cavity. In such systems, it is…
Despite tremendous advances in the fundamentals and applications of cavity quantum electrodynamics (CQED), investigations in this field have primarily been limited to optical cavities composed of purely dielectric materials. Here, we…
Chemical clock reactions are characterised by a relatively long induction period followed by a rapid `switchover' during which the concentration of a \emph{clock chemical} rises rapidly. In addition to their interest in chemistry education,…
Cavity quantum electrodynamics (QED) uses a cavity to engineer the mode structure of the vacuum electromagnetic field such as to enhance the interaction between light and matter. Exploiting these ideas in solid-state systems has lead to…
We employ an exact quantum mechanical simulation technique to investigate a model of cavity-modified chemical reactions in the condensed phase. The model contains the coupling of the reaction coordinate to a generic solvent, cavity coupling…
In computational chemistry of molecular materials, strong static correlation effects appear when electronic states, often involving the ground state, become quasi-degenerate, as occurs, for example, in bond-breaking processes. Such…
Narrow linewidth optical atomic transitions provide a valuable resource for frequency metrology, and form the basis of today's most precise and accurate clocks. Recent experiments have demonstrated that ensembles of atoms can be interfaced…
Interfacing stationary qubits with propagating photons is a fundamental problem in quantum technology. Cavity quantum electrodynamics (CQED) invokes a mediator degree of freedom in the form of a far-detuned cavity mode, the adaptation of…
We propose a mechanism to realize high-yield molecular formation from ultracold atoms. Atom pairs are continuously excited by a laser, and a collective decay into the molecular ground state is induced by a coupling to a lossy cavity mode.…
Cavity-QED is a promising avenue for the deterministic generation of entangled and spin-squeezed states for quantum metrology. One archetypal scheme generates squeezing via collective one-axis twisting interactions. However, we show that in…
Cavity quantum electrodynamics (QED), wherein a quantum emitter is coupled to electromagnetic cavity modes, is a powerful platform for implementing quantum sensors, memories, and networks. However, due to the fundamental tradeoff between…
Understanding the cavity formation and cavity growth mechanisms in solids has fundamental and applied importance for the correct determination of their exploitation capabilities and mechanical characteristics. In this work, we present the…
Recent experiments suggest that vibrational strong coupling (VSC) may significantly modify ground-state chemical reactions and their rates even without external pumping. The intrinsic mechanism of this "vacuum-field catalysis" remains…
We propose an alternative scheme to implement the quantum state transfer between two three-level atoms based on the invariant-based inverse engineering in cavity quantum electronic dynamics (QED) system. The quantum information can be…