相关论文: Orbital polarization, charge transfer, and fluores…

This paper makes a comparison between x-ray absorption (XAS) and resonant inelastic x-ray scattering (RIXS) in the rare earths. Atomic calculations are given for 2p -> 4f and 2p -> 5d XAS. The latter calculation includes the contraction and…

We present a computational study of resonant inelastic x-ray scattering (RIXS) and x-ray absorption in a representative rare-earth nickelate LuNiO$_3$. We study the changes in the spectra across the metal-insulator/site-disproportionation…

Resonant X-ray scattering (RXS) is a spectroscopy where both the power of site selective diffraction and the power of local absorption spectroscopy regarding atomic species are combined. By virtue of the dependence on the core level state…

Although orbital degrees of freedom are a factor of fundamental importance in strongly correlated transition metal compounds, orbital correlations and dynamics remain very difficult to access, in particular by neutron scattering. Via a…

X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS) are powerful probes of electronic structure owing to their chemical and orbital selectivity. For powder samples, however, interpreting RIXS spectral…

We develop a formalism for calculating resonant inelastic x-ray scattering (RIXS) spectra in systems of itinerant electrons with arbitrary band structures, accounting for the effect of the positively-charged core hole exactly. We apply this…

Nonresonant inelastic x-ray scattering (NIXS) is a possible tool to detect charge excitations in electron systems. In addition, multipole transitions at high-momentum-transfer region open a new possibility to determine orbital-selective…

We analyze resonant inelastic x-ray scattering (RIXS) at the Cu K edge in a typical orbital-ordered compound KCuF3 on the basis of a microscopic theory. Spectral shape and its dependence on polarization direction and momentum transfer of…

Ruddlesden-Popper and reduced Ruddlesden-Popper nickelates are intriguing candidates for mimicking the properties of high-temperature superconducting cuprates. The degree of similarity between these nickelates and cuprates has been the…

We analyze theoretically the resonant inelastic x-ray scattering (RIXS) at the Ni K edge in the stripe-ordered state of La_{2-x}Sr_xNiO_4 at x=1/3. In the calculation of RIXS spectra, the stripe-ordered ground state is described within the…

The metal-insulator transitions and the intriguing physical properties of rare-earth perovskite nickelates have attracted considerable attention in recent years. Nonetheless, a complete understanding of these materials remains elusive.…

We used high-resolution resonant inelastic x-ray scattering (RIXS) at the Ni $L_3$ edge to simultaneously investigate high-energy interband transitions characteristic of Ni-O bond ordering and low-energy collective excitations of the Ni…

A new method is presented for describing vibrational effects in x-ray absorption spectroscopy (XAS) and resonant inelastic x-ray scattering (RIXS) using a combination of the classical Franck-Condon (FC) approximation and classical…

We theoretically analyze the intensity of the resonant inelastic X-ray scattering (RIXS) based on Ansatz that the electron is fractionalized into two components. By fitting the angle resolved photoemission spectroscopy (ARPES) data of a…

Resonant Inelastic X-ray Scattering (RIXS) in the soft x-ray range is an element-specific energy-loss spectroscopy used to probe the electronic and magnetic excitations in strongly correlated solids. In the recent years, RIXS has been…

The discovery of superconductivity in square-planar low valence nickelates has ignited a vigorous debate regarding their essential electronic properties: Do these materials have appreciable oxygen charge-transfer character akin to the…

Low-valence nickelates $-$ including infinite-layer (IL) and trilayer (TL) compounds $-$ are longstanding candidates for mimicking the high-temperature superconductivity of cuprates. A recent breakthrough in the field came with the…

We provide a semiquantitative explanation of a recent experiment on the resonant inelastic x-ray scattering (RIXS) in insulating cuprate La2CuO4 (Y.J. Kim et al., Phys. Rev. Lett. 89, 177003 (2002).). We show theoretically that there are…

Results of model calculations using exact diagonalization reveal the orbital character of states associated with different Raman loss peaks in Cu $K$-edge resonant inelastic X-ray scattering (RIXS) from La$_{2}$CuO$_{4}$. The model includes…

We present a study of resonant inelastic X-ray scattering (RIXS) spectra collected at the rare-earth $L$ edges of divalent hexaborides YbB$_6$ and EuB$_6$. In both systems, RIXS-active features are observed at two distinct resonances…