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Ferroelectrics and ionic conductors are important functional materials, each supporting a plethora of applications in information and energy technology. The underlying physics governing their functional properties is ionic motion, and yet…

材料科学 · 物理学 2023-12-22 Liyang Ma , Jing Wu , Tianyuan Zhu , Yiwei Huang , Qiyang Lu , Shi Liu

Nanoscale ferroelectrics that can be integrated into microelectronic fabrication processes are highly desirable for low-power computing and non-volatile memory devices. However, scalable novel ferroelectric materials, such as hafnium oxide…

Ferroelectricity, especially in hafnia-based thin films at nanosizes, has been rejuvenated in the fields of low-power, nonvolatile and Si-compatible modern memory and logic applications. Despite tremendous efforts to explore the formation…

Hafnium dioxide (HfO2) is a promising ferroelectric (FE) material for achieving high-density nonvolatile memory and neuromorphic computing, due to its compatibility with the mainstream integrated circuit technology and the surprisingly…

材料科学 · 物理学 2022-08-16 Guo-Dong Zhao , Xingen Liu , Wei Ren , Xiaona Zhu , Shaofeng Yu

Using first principles calculations, we study the microscopic origin of ferroelectricity (FE) induced by magnetic order in the orthorhombic HoMnO3. We obtain the largest ferroelectric polarization observed in the whole class of improper…

材料科学 · 物理学 2009-11-13 Silvia Picozzi , Kunihiko Yamauchi , Biplab Sanyal , Ivan A. Sergienko , Elbio Dagotto

Ferroelectricity in binary oxides including hafnia and zirconia have riveted the attention of the scientific community due to highly unconventional physical mechanisms and the potential for integration of these materials into semiconductor…

HfO$_{2}$-based ferroelectric thin films are promising for their application in ferroelectric devices. Predicting the ultimate magnitude of polarization and understanding its switching mechanism are critical to realize the optimal…

材料科学 · 物理学 2023-04-04 Yao Wu , Yuke Zhang , Jie Jiang , Limei Jiang , Minghua Tang , Yichun Zhou , Min Liao , Qiong Yang , Evgeny Y. Tsymbal

Unique polar properties of nanoscale hafnia-zirconia oxides (Hf$_x$Zr$_{1-x}$O$_2$) are of great interest for condensed matter physics, nanophysics and advanced applications. These properties are connected (at least partially) to the…

材料科学 · 物理学 2025-01-22 Eugene A. Eliseev , Sergei V. Kalinin , Anna N. Morozovska

The question of whether one can systematically identify (previously unknown) ferroelectric phases of a given material is addressed, taking hafnia (HfO$_2$) as an example. Low free energy phases at various pressures and temperatures are…

材料科学 · 物理学 2014-08-28 Tran Doan Huan , Vinit Sharma , George A. Rossetti, , Rampi Ramprasad

Because of its compatibility with semiconductor-based technologies, hafnia (HfO$_{2}$) is today's most promising ferroelectric material for applications in electronics. Yet, knowledge on the ferroic and electromechanical response properties…

Fluorite-type $\mathrm{HfO_2}$-based ferroelectric (FE) oxides have rekindled interest in FE memories due to their compatibility with silicon processing and potential for high-density integration. The polarization characteristics of FE…

The ferroelectric polarization switching in ferroelectric hafnium zirconium oxide (Hf0.5Zr0.5O2, HZO) in the HZO/Al2O3 ferroelectric/dielectric stack is investigated systematically by capacitance-voltage and polarization-voltage…

应用物理 · 物理学 2019-06-25 Mengwei Si , Xiao Lyu , Peide D. Ye

The cross-unitcell long displacements in some recent emergent ferroelectrics have actually challenged the classical definition of ferroelectricity, while the relative explorations are still in the early stage and even controversial. In this…

材料科学 · 物理学 2026-01-21 Yuanhang Yan , Menghao Wu

In this work, we carry out first-principles calculations and lattice mode analysis to investigate the polarization switching mechanism in HfO$_2$. Because the stability of the polar orthorhombic $Pca2_1$ phase of HfO$_2$ arises from a…

材料科学 · 物理学 2021-08-31 Yubo Qi , Sobhit Singh , Karin M. Rabe

In this work, we investigate the accumulative polarization (P) switching characteristics of ferroelectric (FE) thin films under the influence of sequential electric-field pulses. By developing a dynamic phase-field simulation framework…

应用物理 · 物理学 2019-06-26 Atanu K Saha , Kai Ni , Sourav Dutta , Suman Datta , and Sumeet Gupta

Since the first report of ferroelectricity in nanoscale HfO$_2$-based thin films in 2011, this silicon-compatible binary oxide has quickly garnered intense interest in academia and industry, and continues to do so. Despite its deceivingly…

材料科学 · 物理学 2024-08-27 Tianyuan Zhu , Liyang Ma , Shiqing Deng , Shi Liu

Ferroelectrics that are also ionic conductors offer possibilities for novel applications with high tunability, especially if the same atomic species causes both phenomena. In particular, at temperatures just below the Curie temperature,…

材料科学 · 物理学 2022-03-04 Andrew O'Hara , Nina Balke , Sokrates T. Pantelides

We have investigated the variation of induced ferroelectric polarization under magnetic field with various directions and magnitudes in a staggered antiferromagnet Ba$_2$CoGe$_2$O$_7$. While the ferroelectric polarization cannot be…

强关联电子 · 物理学 2015-05-19 H. Murakawa , Y. Onose , S. Miyahara , N. Furukawa , Y. Tokura

Ferroelectricity in hafnia is often regarded as a breakthrough discovery in ferroelectrics, potentially able to revolutionize the whole field. Despite increasing interests, a comprehensive understanding of the many factors driving the…

材料科学 · 物理学 2021-06-16 Francesco Delodovici , Paolo Barone , Silvia Picozzi

Unconventional ferroelectricity, robust at reduced nanoscale sizes, exhibited by hafnia-based thin-films presents tremendous opportunities in nanoelectronics. However, the exact nature of polarization switching remains controversial. Here,…

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