相关论文: First detection of CHD$_{2}$OH towards pre-stellar…
The deuteration of molecules forming in the ices such as methanol (CH$_3$OH) is sensitive to the physical conditions during their formation in dense cold clouds and can be probed through observations of deuterated methanol in hot cores.…
The study of deuteration in pre-stellar cores is important to understand the physical and chemical initial conditions in the process of star formation. In particular, observations toward pre-stellar cores of methanol and deuterated…
Using the IRAM 30m telescope, we mapped the methanol emission in the pre-stellar core L1544 and observed singly deuterated methanol (CH$_2$DOH and CH$_3$OD) towards the dust peak of L1544. Non-LTE radiative transfer modelling was performed…
We report the first detection of triply-deuterated methanol, with 12 observed transitions, towards the low-mass protostar IRAS 16293-2422, as well as multifrequency observations of 13CH3OH, used to derive the column density of the main…
Recent observations indicate that organic molecules are prevalent towards starless and prestellar cores. Deuteration of these molecules has not been well-studied during the starless phase. Published observations of singly-deuterated…
We report the first detection of doubly-deuterated methanol (CHD2OH), as well as firm detections of the two singly-deuterated isotopomers of methanol (CH2DOH and CH3OD), towards the solar-type protostar IRAS16293-2422. From the present…
Isotopic fractionation is a very powerful tool to follow the evolution of material from one stage to the next in the star-formation process. Pre-stellar cores exhibit some of the highest levels of deuteration because their physical…
We investigate the deuteration of methanol towards the high-mass star forming region NGC 7538-IRS1. We have carried out a multi-transition study of CH$_3$OH, $^{13}$CH$_3$OH and of the deuterated fllavors, CH$_2$DOH and CH$_3$OD, between…
Deuterated methanol is one of the most robust windows astrochemists have on the individual chemical reactions forming deuterium-bearing molecules and the physicochemical history of the regions where they reside. The first-time detection of…
Context: Methanol is thought to be mainly formed during the prestellar phase and its deuterated form keeps memory of the conditions at that epoch. Thanks to the unique combination of high angular resolution and sensitivity provided by ALMA,…
Aims. We aim to improve a previous model for the prediction of column densities and deuterium fractions of non- and singly deuterated methanol. Thereby, we try to identify crucial chemical and physical parameters, for which the study of…
Deuterium fractionation, as studied through mono-deuterated methanol, is frequently used as a diagnostic tool to trace the physical conditions and chemical evolution of interstellar sources. This study investigates methanol deuteration in…
The abundance of deuterated molecules in a star-forming region is sensitive to the environment in which they are formed. Deuteration fractions therefore provide a powerful tool for studying the physical and chemical evolution of a…
The relative abundances of singly-deuterated methanol isotopologues, [CH$_{2}$DOH]/[CH$_{3}$OD], in star-forming regions deviate from the statistically expected ratio of 3. In Orion KL, the nearest high-mass star-forming region to Earth,…
We investigate the molecular evolution and D/H abundance ratios that develop as star formation proceeds from a dense-cloud core to a protostellar core, by solving a gas-grain reaction network applied to a 1-D radiative hydrodynamic model…
The isotopic ratios of deuterated methanol derived around protostars are commonly used to infer the physical conditions under which they formed in the earlier prestellar stage. However, there is a discrepancy in the ratio of the singly…
Mono-deuterated methanol is thought to form during the prestellar core stage of star formation. Observed variations in the CH2DOH/CH3OD ratio suggest that its formation is strongly dependent on the surrounding cloud conditions. Thus, it is…
Deuterated molecules have been detected and studied toward Orion BN/KL in the past decades, mostly with single-dish telescopes. However, high angular resolution data are critical not only for interpreting the spatial distribution of the…
The chemical evolution in high-mass star-forming regions is still poorly constrained. Studying the evolution of deuterated molecules allows to differentiate between subsequent stages of high-mass star formation regions due to the strong…
The deuterium fractionation of gas-phase molecules in hot cores is believed to reflect the composition of interstellar ices. The deuteration of methanol is a major puzzle, however, because the isotopologue ratio [CH2DOH]/[CH3OD], which is…