相关论文: Proton transfer at subkelvin temperatures
We report bulk, room-temperature hyperpolarization of 13C nuclear spins observed via high-field nuclear magnetic resonance (NMR). The hyperpolarization is achieved by optical pumping (OP) of nitrogen vacancy defect centers in diamond…
One of considered nowadays scenarios of proton - nucleus reaction is spallation. Its motivation is based on experimental final-state observations of one heavy nucleus, a small number of light fragments and numerous individual nucleons. It…
A new neutron detection concept is presented that is based on superconductive niobium (Nb) strips coated by a boron (B) layer. The working principle of the detector relies on the nuclear reaction 10B+n $\rightarrow$ $\alpha$+ 7Li , with…
Liquid Helium is used widely, from hospitals to characterization of materials at low temperatures. Many experiments at low temperatures require liquid Helium, particularly when vibration isolation precludes the use of cryocoolers and when…
High-energy hadronic reactions with proton-to-neutron transitions (and vice versa) with small momentum transfer allow to study the properties of nearly on-shell pions, which cannot be accessed otherwise. We overview the recent results for…
Dynamic nuclear polarization (DNP) of molecules in a solution at room temperature has potential to revolutionize nuclear magnetic resonance spectroscopy and imaging. The prevalent methods for achieving DNP in solutions are typically most…
The isomerization of hydrogen cyanide to hydrogen isocyanide on icy grain surfaces is investigated by an accurate composite method (jun-Cheap) rooted in the coupled cluster ansatz and by density functional approaches. After benchmarking…
We propose a highly feasible technique with no experimental overhead to rapidly cool the in-plane degrees of freedom of large two-dimensional ion crystals in Penning traps. Through simulations, we demonstrate that our approach enables the…
We discuss a new mechanism for the electron capture in fast ion-atom collisions. Similarly like in the radiative capture, where the electron transfer occurs due to photon emission, within the mechanism under consideration the electron…
Radiative decay processes at cold and ultra cold temperatures for Sulfur atoms colliding with protons are investigated. The MOLPRO quantum chemistry suite of codes was used to obtain accurate potential energies and transition dipole…
Using the pseudopotential density functional method as well as equilibrium thermodynamic functions, we explore the process of releasing H2 molecules adsorbed on a transition metal atom caused by the hydrogen-ammonia partial pressure…
When electron doped, the layered transition metal nitrides ${\cal T}$NCl (${\cal T}$ = group IVB transition metal ion) become impressive superconductors with critical temperature T$_c$= 15-26K. Here we take the most studied member, ZrNCl,…
Polarizing nuclear spins is of fundamental importance in biology, chemistry and physics. Methods for hyperpolarizing 13C nuclei from free electrons in bulk, usually demand operation at cryogenic temperatures. Room-temperature approaches…
The strong magnetic fields (B ~ 10^{12} - 10^{13} G) characteristic of neutron stars make all the properties of an atom strongly dependent on the transverse component K_\perp of its generalized momentum. In particular, the photoionization…
As pointed out by Kutschera and W{\'o}jcik, very low concentration of protons combined with a specific density dependence of effective neutron-proton interaction could lead to a localization of ``proton impurities'' in neutron medium at…
Proton transport (PT) in bulk liquid water and within a thin water-filled carbon nanotube has been examined with ab initio pathintegral molecular dynamics (PIMD). Barrierless proton transfer is observed in each case when quantum nuclear…
We systematically investigate the formation and stability of snowballs formed by femtosecond photo-ionization of small alkali clusters bound to helium nanodroplets. For all studied alkali species Ak=(Na, K, Rb, Cs) we observe the formation…
Electric deflection measurements on liquid helium nanodroplets doped with individual polar molecules demonstrate that the cold superfluid matrix enables full orientation of the molecular dipole along the external field. This translates into…
Photoionization spectroscopy and mass spectrometry of doped helium (He) nanodroplets rely on the ability to efficiently detect ions and/or electrons. Using a commercial quadrupole mass spectrometer and a photoelectron-photoion coincidence…
Despite widespread interest, a detailed understanding of the dynamics of proton transfer at interfaces is lacking. Here we use ab initio molecular dynamics to unravel the connection between interfacial water structure and proton transfer…