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Double perovskites containing heavy transition metal ions are an important family of compounds for the study of the interplay between electron correlation and spin-orbit coupling. Here, by combining magnetic susceptibility, heat capacity,…

Conventional perovskite-type ferroelectrics are based on octahedral units of oxygen, and often comprise toxic Pb to achieve robust ferroelectricity. Here, we report the ferroelectricity in a silicate-based compound, Bi2SiO5 (BSO), induced…

The coexistence and coupling of magnetic and ferroelectric orderings in single phase multiferroics has evinced enormous scientific interest as it involves breaking of time reversal and space inversion symmetries in the same material. The…

Magnetoelectric coupling in the polycrystalline antiferromagnets CuFe0.95Rh0.05O2 and CuFeO2 has been investigated. For both samples, electric polarization was observed in the absence of an applied external magnetic field demonstrating that…

材料科学 · 物理学 2009-05-27 B. Kundys , A. Maignan , D. Pelloquin , Ch. Simon

Magnetic properties of an antiferromagnetic double perovskite oxide Ba2CaReO6, where Re6+ (5d1) ions with large spin-orbit coupling are arranged on the face-centered-cubic lattice, are investigated using pulsed high magnetic field up to 66…

We have observed a sizable positive magnetocapacitance ($\sim$$5-90\%$) in perovskite Pr$_{0.55}$Ca$_{0.45}$MnO$_3$ and bilayer Pr(Sr$_{0.1}$Ca$_{0.9}$)$_2$Mn$_2$O$_7$ system under 5T magnetic field across 20-100 K below the magnetic…

Multiferroic materials, characterized by the coexisting of ferroelectric polarization (breaking spatial inversion symmetry) and magnetism (breaking time-reversal symmetry), with strong magnetoelectric coupling, are highly sought after for…

材料科学 · 物理学 2025-04-14 Wei Sun , Wenxuan Wang , Changhong Yang , Ying Liu , Xiaotian Wang , Shifeng Huang , Zhenxiang Cheng

ABO3 perovskite multiferroic La0.5Bi0.5Mn0.5Fe0.5O3.09 where the B-site cations is responsible for the magnetic properties and the A-site cation with lone pair electron is responsible for the ferroelectric properties was synthesized at…

材料科学 · 物理学 2008-08-25 Asish K. Kundu , R. Ranjith , V. Pralong , N. Nguyen , B. Kundys , V. Caignaert , W. Prellier , B. Raveau

BiFeO3 is a model multiferroic in which the ferroelectric polarization is coupled to ferroelastic lattice distortions, yet deterministic control of its domain structure remains limited by high switching fields and competing polarization…

Competing interactions and geometric frustration provide favourable conditions for exotic states of matter. Such competition often causes multiple phase transitions as a function of temperature and can lead to magnetic structures that break…

Specific heat studies of the Sr$_{1-x}$Ba$_x$Mn$_{1-y}$Ti$_y$O$_3$ polycrystalline samples performed by the relaxation and DSC methods over the temperature range 2 - 450 K are reported. Anomalies accompanying the…

统计力学 · 物理学 2025-07-31 J. Wieckowski , A. Szewczyk , M. U. Gutowska , B. Dabrowski

Single phase multiferroics in which ordered magnetic and ferroelectricity coexist, are of great interest for new multifunctional devices, and among them Y-type hexaferrites are good candidates. Transverse susceptibility measurements, which…

材料科学 · 物理学 2024-03-03 P. Hernández-Gómez , D. Martín-González , C. Torres , J. M. Muñoz

In this paper the structural, magnetic, and dielectric properties of langasite compound Pb$_3$TeMn$_3$P$_2$O$_{14}$ have been investigated as a candidate of short-range magnetic correlations driven development of dielectric anomaly above…

材料科学 · 物理学 2021-07-01 Rafikul Ali Saha , Desheng Fu , Mitsuru Itoh , Sugata Ray

Cupric oxide is multiferroic at unusual high temperatures. From density functional calculations we find that the low-T magnetic phase is paraelectric and the higher-T one ferroelectric, with a size and direction of polarization in good…

Magnetic and dielectric properties of the hexagonal triangular lattice antiferromagnet 2H-AgFeO2 have been studied by neutron diffraction, magnetic susceptibility, specific heat, pyroelectric current, and dielectric constant measurements.…

强关联电子 · 物理学 2019-03-05 Noriki Terada , Dmitry D. Khalyavin , Pascal Manuel , Yoshihiro Tsujimoto , Alexei A. Belik

A metastable perovskite BiFe0.5Sc0.5O3 synthesized under high-pressure (6 GPa) and high- temperature (1500 K) conditions was obtained in two different polymorphs, antipolar Pnma and polar Ima2, through an irreversible behaviour under a…

We have fabricated a variety of "PZT-PFW" (PbZr0.52Ti0.48O3)1-x(PbFe2/3W1/3O3)x [PZTFWx; 0.2 < x < 0.4] single-phase tetragonal ferroelectrics via chemical solution deposition (CSD) [polycrystalline] and pulsed laser deposition (PLD)…

材料科学 · 物理学 2010-06-18 Ashok Kumar , Ram S. Katiyar , James F. Scott

We report on the synthesis and characterization of BiFe0.5Mn0.5O3, a potential type-I multiferroic compound displaying temperature induced magnetization reversal. Bulk samples were obtained by means of solid state reaction carried out under…

A transition in a spheroidal particle from the paraelectric to the ferroelectric phase as well as dynamic susceptibility are studied without approximation in the paraphase. It is assumed that the surface charge is compensated and the…

材料科学 · 物理学 2008-07-22 O. Hudak

Magnetoelectric (ME) effect is recognized for its utility for low-power electronic devices.Largest ME coefficients are often associated with phase transitions in which ferroelectricity is induced by magnetic order. Unfortunately, in these…