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Thermomechanical processing alters the microstructure of metallic alloys through coupled plastic deformation and thermal exposure, with dislocation motion driving plasticity and microstructural evolution. Our previous work (Islam et al.,…

材料科学 · 物理学 2025-12-25 Mahmudul Islam , Killian Sheriff , Rodrigo Freitas

Chemical short-range order (CSRO) is believed to be a key contributor to the exceptional properties of multicomponent alloys. However, direct validation and confirmation of CSRO has been highly elusive in most compounds. Recent studies for…

材料科学 · 物理学 2022-11-11 A. Naghdi , F. J. Dominguez-Gutierrez , W. Y. Huo , K. Karimi , S. Papanikolaou

Chemical short-range order (CSRO), a form of nanoscale special atom arrangement, has been found to significantly alter material properties such as dislocation motion and defect dynamics in various alloys. Here, we use Fe-Ni-Cr alloys to…

材料科学 · 物理学 2023-05-19 Hamdy Arkoub , Miaomiao Jin

Hydrogen embrittlement (HE) in austenitic stainless steels is advanced by hydrogen enhanced localized plasticity (HELP), typically accompanied by a transition from homogeneous to localized slip. Short-range order (SRO) in face-centered…

High-entropy alloys (HEAs) were presumed to have a configurational entropy as high as that of an ideally mixed solid solution (SS) of multiple elements in near-equal proportions. However, enthalpic interactions inevitably render such…

材料科学 · 物理学 2019-09-11 Qing-Jie Li , Howard Sheng , Evan Ma

Refractory multi-principal element alloys (RMPEAs) are promising materials for high-temperature structural applications. Here, we investigate the role of chemical short-range ordering (CSRO) on dislocation glide in two model RMPEAs - TaNbTi…

Traditional metallic alloys are mixtures of elements where the atoms of minority species tend to distribute randomly if they are below their solubility limit, or lead to the formation of secondary phases if they are above it. Recently, the…

We investigate the short-range order (SRO) and phase stability of the equiatomic CoCrFeMnNi high-entropy alloy using cluster expansion supplemented by an eigen-decomposition analysis of the SRO parameters. Our results reveal that the…

材料科学 · 物理学 2026-05-19 Wei Chen , Gian-Marco Rignanese , Geoffroy Hautier

Metallic alloys are routinely subjected to nonequilibrium processes during manufacturing, such as rapid solidification and thermomechanical processing. It has been suggested in the high-entropy alloy literature that chemical short-range…

材料科学 · 物理学 2025-10-10 Mahmudul Islam , Killian Sheriff , Yifan Cao , Rodrigo Freitas

Metallic alloys often form phases - known as solid solutions - in which chemical elements are spread out on the same crystal lattice in an almost random manner. The tendency of certain chemical motifs to be more common than others is known…

材料科学 · 物理学 2024-06-21 Killian Sheriff , Yifan Cao , Tess Smidt , Rodrigo Freitas

Electronic-structure methods based on density-functional theory (DFT) were used to directly quantify the effect of chemical short-range order (SRO) on thermodynamic, structural, and electronic properties of archetypal face-centered-cubic…

材料科学 · 物理学 2023-05-16 Will Morris , Duane D. Johnson , Prashant Singh

This paper studies short-range order (SRO) in the semiconductor alloy (GaN)$_{1-x}$(ZnO)$_x$. Monte Carlo simulations performed on a density functional theory (DFT)-based cluster expansion model show that the heterovalent alloys exhibit…

材料科学 · 物理学 2016-06-03 Jian Liu , Maria V. Fernández-Serra , Philip B. Allen

We investigate the effect of short-range order (SRO) on the electronic structure in alloys from the theoretical point of view using density of states (DOS) data. In particular, the interaction between the atoms at different lattice sites is…

Short-range order (SRO) in Fe-rich Fe-Cr alloys is investigated by means of atomistic off-lattice Monte Carlo simulations in the semi-grand canonical ensemble using classical interatomic potentials. The SRO parameter defined by Cowley…

材料科学 · 物理学 2010-09-03 Paul Erhart , Alfredo Caro , Magdalena Serrano de Caro , Babak Sadigh

Short-range ordering (SRO) tendency for disordered alloys is considered as competition between chemical ordering and geometric (mainly, difference in atomic radius for constituents) effects. Especially for multicomponent (including the…

材料科学 · 物理学 2019-05-22 Koretaka Yuge , Shouno Ohta

Recent developments in the percolation theory of passivation have shown that chemical short-range order (SRO) affects the aqueous passivation behavior of alloys. However, there has been no systematic exploration to quantify these SRO…

材料科学 · 物理学 2025-12-22 Abhinav Roy , Karl Sieradzki , Michael J. Waters , James M. Rondinelli , Ian D. McCue

Chemical short-range order (CSRO) has emerged as a critical structural feature in concentrated alloys, yet its coupling with hydrogen remains an active discussion. Here, we develop a machine-learning interatomic potential for the Co-Ni-V-H…

材料科学 · 物理学 2026-04-08 Beihan Chen , Dalia Sayed Ahmed , Yang Yang , Miaomiao Jin

This study delves into bcc HfNbTaTiZr refractory high entropy alloys, focusing on the $\frac{1}{2}\langle111\rangle$ screw dislocation core structures. While traditional observations in pure elements often revealed compact dislocation…

材料科学 · 物理学 2024-05-07 Asif Iqbal Bhatti , David Tingaud , M. Seydou , Sylvain Queyreau

The exceptional mechanical strengths of medium and high-entropy alloys have been attributed to hardening in random solid solutions. Here, we evidence non-random chemical mixings in CrCoNi alloys, resulting from short range ordering. A novel…

材料科学 · 物理学 2022-06-07 H. W. Hsiao , R. Feng , H. Ni , K. An , J. D. Poplawsky , P. K. Liaw , J. M. Zuo

Nitrogen (N) is a key alloying element that enhances the performance of Fe-Ni-Cr austenitic stainless steels, improving austenite stability, corrosion resistance, and yield strength. However, the role of N in modifying chemical ordering,…

材料科学 · 物理学 2025-07-08 Tianyu Su , Brian J. Blankenau , Namhoon Kim , Jessica A. Krogstad , Elif Ertekin
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