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The magnetic susceptibility, crystal and magnetic structures, and electronic structure of double perovskite Sr2ScOsO6 are reported. Using both neutron and x-ray powder diffraction we find that the crystal structure is monoclinic P21/n from…

强关联电子 · 物理学 2015-04-06 A. E. Taylor , R. Morrow , D. J. Singh , S. Calder , M. D. Lumsden , P. M. Woodward , A. D. Christianson

Here, the first-principles predictions on the structural stability, magnetic behavior and electronic structure of B-site ordered double perovskite Nd$_{2}$FeCrO$_{6}$ have been reported. Initially, the ground state of the parent single…

材料科学 · 物理学 2022-01-10 M. D. I. Bhuyan , Rana Hossain , Ferdous Ara , M. A. Basith

The complex perovskite Pb2CoTeO6 (PCTO) has been prepared as polycrystalline powders by solid state reaction route, and the crystal structure and magnetic properties have been investigated using a combination of X-ray and neutron powder…

材料科学 · 物理学 2010-12-01 S. A. Ivanov , P. Nordblad , R. Mathieu , R. Tellgren , C. Ritter

We present a comprehensive study on the magnetic structure, dynamics, and phase evolution in the single-phase double perovskite $La_2CoMnO_6$. The mixed valence state due to oxygen deficiency is verified by X-ray photoelectron spectroscopy,…

Single phase polycrystalline sample of perovskite Sr2TiMnO6 (STMO) has been successfully synthesized via solid state reaction route. Its detailed structural and physical properties have been studied using x-ray diffraction, transmission…

材料科学 · 物理学 2016-09-06 Shivani Sharma , R. Rawat , N. P. Lalla

The field of double perovskites is now advancing to three magnetic elements on the A, B and B$'$ sites. A series of iridium-based double perovskite compounds, $Ln_2$CoIrO$_6$ ($Ln$ = Eu, Tb, Ho) with three magnetic elements were synthesized…

The synthesis and physical properties of the double perovskite (DP) compound Ba2CdReO6 with the 5d1 electronic configuration are reported. Three successive phases originating from a spin-orbit-entangled Jeff = 3/2 state, confirmed by the…

强关联电子 · 物理学 2021-04-06 Daigorou Hirai , Zenji Hiroi

The 3$d$-5$d$ based double perovskites offer an ideal playground to study the interplay between electron correlation ($U$) and spin-orbit coupling (SOC) effect, showing exotic physics. The Sr$_2$FeIrO$_6$ is an interesting member in this…

Coupling between different interactions allows to control physical aspects in multifunctional materials by perturbing any of the degrees of freedom. Here, we aim to probe the correlation among structural, electronic and magnetic observables…

The 3$d$-5$d$ based double perovskites are of current interest as they provide model system to study the interplay between electronic correlation ($U$) and spin-orbit coupling (SOC). Here we report detailed structural, magnetic and…

强关联电子 · 物理学 2017-10-30 K C Kharkwal , A K Pramanik

Oxide double perovskites wherein octahedra formed by both 3d elements and sp-based heavy elements give rise to unconventional magnetic ordering and correlated quantum phenomena crucial for futuristic applications. Here, by carrying out…

We report here a comprehensive study on structural, magnetic, caloric and electronic properties of the monoclinic phase of double perovskite compound Tm2CoMnO6 (TCMO) in its polycrysttaline format. Magnetic measurements confirm the presence…

材料科学 · 物理学 2023-07-13 A. Banerjee , Gangadhar Das , V. Rajaji , S. Majumdar , P. K. Chakrabarti

3$d$ based double perovskite materials have received much attention in recent years due to their exotic magnetic structure and magneto-electric coupling. In this work we have prepared and studied the nano-crystalline sample of…

强关联电子 · 物理学 2019-09-25 Ilyas Noor Bhatti , Imtiaz Noor Bhatti , Rabindra Nath Mahato , M. A. H. Ahsan

Double-perovskite oxides that contain both 3d and 5d transition metal elements have attracted growing interest as they provide a model system to study the interplay of strong electron interaction and large spin-orbit coupling (SOC). Here,…

Materials with a 5d4 electronic configuration are generally considered to have a nonmagnetic ground state (J=0). Interestingly, Sr2YIrO6 (Ir5+ having 5d4 electronic configuration) was recently reported to exhibit long-range magnetic order…

We investigated the anisotropy of the magnetic and magnetocaloric properties of singlecrystalline double perovskite Tb2CoMnO6, which crystallizes in a monoclinic P21/n structure. Due to dissimilar magnetic anisotropy, the ferromagnetic…

强关联电子 · 物理学 2018-12-17 J. Y. Moon , M. K. Kim , D. G. Oh , J. H. Kim , H. J. Shin , Y. J. Choi , N. Lee

The subtle interplay between spin-orbit coupling, exchange interactions, and cation ordering can lead to exotic magnetic states in transition-metal ions. We report a comprehensive study of the Re-based (5$d^1$) ordered double perovskite…

The magnetic correlations in double perovskites La2Mn2-xNixO6 (x = 0.5, 0.75, 1.0, 1.25 and 1.5) have been systematically investigated across macroscopic, mesoscopic, and microscopic length scales using temperature-dependent bulk DC…

材料科学 · 物理学 2025-10-14 A. K. Bera , K. S. Chikara , B. Saha , S. M. Yusuf , Mohd. Nasir , S. Sen

Double perovskite Bi$_2$FeCrO$_6$, related with BiFeO$_3$, is very interesting because strong ferroelectricity and high magnetic Curie temperature beyond room temperature are observed in it. However, existing density-functional-theory (DFT)…

材料科学 · 物理学 2014-03-18 Zhe-Wen Song , Bang-Gui Liu

Using density functional calculations we explore the properties of as-yet-unsynthesized $3d - 5d$ ordered double perovskites ($A_2BB'$O$_6$) with highly polarizable Bi$^{3+}$ ions on the $A$ site. We find that the Bi$_2$NiReO$_6$ and…

材料科学 · 物理学 2015-03-13 Marjana Ležaić , Nicola A. Spaldin
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