相关论文: Odd-even effect in n-alkane systems: A molecular d…

The mixtures CH$_3$(CH$_2$)$_{u-1}$COO(CH$_2$)$_{v-1}$CH$_3$ ($u=5-13$, $v=1,2$; $u=1,2,3$, $v=3,4$; $u=1,2,4$, $v=5$) + n-alkane have been investigated using experimental data (viscosity and excess molar functions: enthalpy,…

The model-potential approach previously developed by the authors to study positron interactions with molecules is used to calculate the positron binding energy for $n$-alkanes (C$_n$H$_{2n+2}$) and the corresponding cycloalkanes…

Excess molar enthalpies ($H_{\text{m}}^{\text{E}}$) for iodobenzene, or 1-iodonaphthalene + heptane, + decane, + dodecane, or + tetradecane mixtures at 298.15 K and 93 kPa have been measured using a Tian-Calvet micro-calorimeter. The values…

Spontaneous nuclear ortho-para transitions are shown to be possible in hydrogen molecule and molecular ion as due to hyperfine interaction odd-odd relative to the space or spin nuclear coordinate permutations. A part of this interaction…

The total scattering structure factors of pure liquid n-pentanol, pentanal, and 5 of their mixtures, as determined by high energy synchrotron X-ray diffraction experiments, are presented. For the interpretation of measured data, molecular…

Crystallization of alkane mixtures has been studied extensively for decades. However, majority of the available data consider the behaviour of alkanes with chain length of 21 C-atoms or more. Furthermore, important information about the…

Proper analysis of electron collisions in two spatial dimensions leads to the conclusion, that the odd harmonics of the electron distribution function decay much slower than the even ones at finite temperatures. The number of long-lived odd…

Kinematic viscosities were measured for iodobenzene + n-alkane mixtures at (288.15-308.15) K and atmospheric pressure. Using our previous density data, dynamic viscosities ($\eta$), deviations in absolute viscosity ($\Delta \eta$) and…

Density and viscosity measurements have been performed for the systems 1-iodonaphthalene + heptane, or + decane, or + dodecane, or + tetradecane over the temperature range (288.15-308.15) K and atmospheric pressure. At this end, a…

Systematic odd-even binding energy differences in finite metallic particles are usually attributed to mean-field orbital energy effects or to a coherent pairing interaction. We show analytically and numerically that a purely random two-body…

Alkanes of medium chain length show an unusual wetting behavior on (salt) water, exhibiting a sequence of two changes in the wetting state. When deposited on the water surface at low temperatures, the liquid alkane forms discrete droplets…

Two types of average neutron-proton interaction formulas are compared: In the first type, neutron-proton interactions for even-even and odd-$A$ nuclei extracted from experimental binding energies show a smooth behavior as a function of mass…

Molecular machines described in this paper are meant to be such molecular systems that make use of conformational mobility (i.e. hindered rotation around chemical bonds and molecular construction deformations with formation and breakage of…

Nonlinear effects are omnipresent in thin films of ion conducting materials showing up as a significant increase of the conductivity. For a disordered hopping model general physical mechanisms are identified giving rise to the occurrence of…

Interactions and structure of alkanone, or alkanal or dialkyl carbonate + alkane mixtures, or of 2-alkanone+ 2-alkanone, or of ketone + dialkyl carbonate systems have been investigated by means of a set of thermodynamic properties and by…

The interplay of pairing is explored for the spectral statistics of nuclear systems with emphasis on the nearest neighbor spacing distributions by employing the kernel density and maximum likelihood estimation techniques. Different…

The molecular dynamics in the ambient-pressure solid phase of (1,1,2)-trichloroethane is studied by means of broadband dielectric spectroscopy and molecular dynamics simulations. The dielectric spectra of polycrystalline samples obtained by…

Based on first-principles approaches, we study the ballistic phonon transport properties of finite monatomic carbon chains stretched between graphene nanoribbons, an $sp$-$sp^2$ hybrid carbon nanostructure that has recently seen significant…

A wide range of physical and biological systems, including colloidal magnets, granular spinners, and starfish embryos, are characterized by strongly rotating units that give rise to odd viscosity and odd elasticity. These active systems can…

Odd electrons of benzenoid units and correlation of these electrons having different spins are the main concepts of the molecular theory of graphene. In contrast to the theory of aromaticity, the molecular theory is based on the fact that…