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Pressure-temperature phase diagram of the organic Mott insulator $\kappa$-(ET)$_2$Cu$_2$(CN)$_3$, a model system of the spin liquid on triangular lattice, has been investigated by $^1$H NMR and resistivity measurements. The spin-liquid…

强关联电子 · 物理学 2007-05-23 Y. Kurosaki , Y. Shimizu , K. Miyagawa , K. Kanoda , G. Saito

The Mott metal-insulator transition-a drastic manifestations of Coulomb interactions among electrons-is the first-order transition of clear discontinuity, as shown by various experiments and the celebrated dynamical mean-field theory.…

强关联电子 · 物理学 2018-03-01 Tetsuya Furukawa , Kazuhiko Kobashi , Yosuke Kurosaki , Kazuya Miyagawa , Kazushi Kanoda

We show that the anisotropy of the effective spin model for the dimer Mott insulator phase of $\kappa$-(BEDT-TTF)$_2X$ salts is dramatically different from that of the underlying tight-binding model. Intra-dimer quantum interference results…

强关联电子 · 物理学 2018-07-11 B. J. Powell , E. P. Kenny , J. Merino

Systematic pressure- and temperature-dependent infrared studies on the two-dimensional organic quantum spin-liquid $\beta^{\prime}$-EtMe$_3$Sb[Pd(dmit)$_2$]$_2$ disclose the electronic and lattice evolution across the Mott insulator-metal…

强关联电子 · 物理学 2019-03-27 Weiwu Li , Andrej Pustogow , Reizo Kato , Martin Dressel

The organic system, $\kappa$-[(BEDT-TTF)$_{1-x}$(BEDT-STF)$_x$]$_2$Cu$_2$(CN)$_3$, showing the Mott transition between a nonmagnetic Mott insulating (NMI) state and a Fermi liquid (FL), is systematically studied by calorimetric…

The electronic properties of molecular conductors can be readily varied via physical or chemical pressure as it increases the bandwidth W; this enables crossing the Mott insulator-to-metal phase transition by reducing electronic…

强关联电子 · 物理学 2019-11-18 Y. Saito , R. Rösslhuber , A. Löhle , M. Sanz Alonso , M. Wenzel , A. Kawamoto , A. Pustogow , M. Dressel

The Mott insulator $\kappa$-(BEDT-TTF)$_2$Ag$_2$(CN)$_3$ forms a highly-frustrated triangular lattice of $S=1/2$ dimers with a possible quantum-spin-liquid state. Our experimental and numerical studies reveal the emergence of a slight…

More than half a century after first being proposed by Sir Nevill Mott, the deceptively simple question of whether the interaction-driven electronic metal-insulator transition may be continuous remains enigmatic. Recent experiments on…

The dimer Mott insulator $\kappa$-(BEDT-TTF)$_2$Cu$_2$(CN)$_3$ exhibits unusual electrodynamic properties. Numerical investigations of the electronic ground state and the molecular and lattice vibrations reveal the importance of the…

强关联电子 · 物理学 2016-02-02 M. Dressel , P. Lazic , A. Pustogow , E. Zhukova , B. Gorshunov , J. A. Schlueter , O. Milat , B. Gumhalter , S. Tomic

We have performed in-plane transport measurements on the two-dimensional organic salt $\kappa$-(BEDT-TTF)$_{2}$Cu[N(CN)$_{2}$]Cl. A variable (gas) pressure technique allows for a detailed study of the changes in conductivity through the…

强关联电子 · 物理学 2009-11-10 P. Limelette , P. Wzietek , S. Florens , A. Georges , T. A. Costi , C. Pasquier , D. Jerome , C. Meziere , P. Batail

Utilizing infrared vibrational spectroscopy we have investigated dimerized two-dimensional organic salts in order to search for possible charge redistribution that might cause electronic dipoles and ferroelectricity: the quantum spin liquid…

The quest for entangled spin excitations has stimulated intense research on frustrated magnetic systems. For almost two decades, the triangular-lattice Mott insulator $\kappa$-(BEDT-TTF)$_2$Cu$_2$(CN)$_3$ has been the hottest candidate for…

强关联电子 · 物理学 2023-06-06 A. Pustogow , Y. Kawasugi , H. Sakurakoji , N. Tajima

The quasi-two-dimensional organic charge-transfer salt $\kappa$-(BEDT-TTF)$_2$Cu$_2$(CN)$_3$ is one of the prime candidates for a quantum spin-liquid due the strong spin frustration of its anisotropic triangular lattice in combination with…

The electrodynamic response of the organic spin-liquid candidate $\kappa$-(BEDT-TTF)$_2$Cu$_2$(CN)$_3$ has been measured in an extremely wide energy range ($10^{-13}$ to 2 eV) as a function of temperature (5 to 300 K). Below the Mott gap,…

强关联电子 · 物理学 2014-12-16 A. Pustogow , E. Zhukova , B. Gorshunov , M. Pinterić , S. Tomić , J. A. Schlueter , M. Dressel

EtMe$_3$Sb[Pd(dmit)$_2$]$_2$, an organic Mott insulator with nearly isotropic triangular lattice, is a candidate material for a quantum spin liquid, in which the zero-point fluctuations do not allow the spins to order. The itinerant gapless…

强关联电子 · 物理学 2020-04-29 M. Yamashita , Y. Sato , T. Tominaga , Y. Kasahara , S. Kasahara , H. Cui , R. Kato , T. Shibauchi , Y. Matsuda

Mott insulators with a half-filled band of electrons on the triangular lattice have been recently studied in a variety of organic compounds. All of these compounds undergo transitions to metallic/superconducting states under moderate…

强关联电子 · 物理学 2008-05-09 Yang Qi , Subir Sachdev

We present a theoretical approach to describing the Mott transition of electrons on a two dimensional lattice that begins with the low energy effective theory of the Fermi liquid. The approach to the Mott transition must be characterized by…

强关联电子 · 物理学 2012-01-25 David F. Mross , T. Senthil

We scrutinize the magnetic properties of $\kappa$-(BEDT-TTF)$_2$Hg(SCN)$_2$Cl through its first-order metal-insulator transition at $T_{\rm CO}=30$ K by means of $^1$H nuclear magnetic resonance (NMR). While in the metal we find…

强关联电子 · 物理学 2020-04-08 A. Pustogow , T. Le , H. -H. Wang , Yongkang Luo , E. Gati , H. Schubert , M. Lang , S. E. Brown

The correlation-driven Mott transition is commonly characterized by a drop in resistivity across the insulator-metal phase boundary; yet, the complex permittivity provides a deeper insight into the microscopic nature. We investigate the…

We review the interplay of frustration and strong electronic correlations in quasi-two-dimensional organic charge transfer salts, such as k-(BEDT-TTF)_2X and Et_nMe_{4-n}Pn[Pd(dmit)2]2. These two forces drive a range of exotic phases…

强关联电子 · 物理学 2011-05-06 B. J. Powell , Ross H. McKenzie
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