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A wide variation in the charge transport properties of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT-PSS) films is attributed to the degree of phase-segregation of the excess insulating polyanion. The results indicate that…

材料科学 · 物理学 2010-10-06 C. S. Suchand Sangeeth , Manu Jaiswal , Reghu Menon

Highly doped Poly(3,4-ethylenedioxythiophene) or PEDOT is a conductive polymer with a wide range of applications in energy conversion due to its ease of processing, optical properties and high conductivity. The latter is influenced by…

介观与纳米尺度物理 · 物理学 2017-01-04 David Gelbwaser-Klimovsky , Semion K. Saikin , Randall H. Goldsmith , Alán Aspuru-Guzik

Composite materials based on Poly(3,4-ethylenedioxythiophene) (PEDOT) and CoFe$_2$O$_4$ magnetic nanoparticles (NP) were synthesized by chemical oxidative polymerization with varying monomer and surfactant (DBSA) concentrations, and were…

材料科学 · 物理学 2025-07-11 Gabriel Paciaroni , María Ana Castro , Carlos Acha , Paula Soledad Antonel

The conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) is one of the most researched materials. The 1980s bipolaron model remains the dominant interpretation of the electronic structure of PEDOT. Recent theoretical studies have…

材料科学 · 物理学 2024-05-01 Ben Craig , Peter Townsend , Carlos Ponce de Leon , Chris Kriton-Skylaris , Denis Kramer

Cross-plane electrical and thermal transport in thin films of a conducting polymer (poly(3,4-ethylenedioxythiophene), PEDOT) stabilized with trifluoromethanesulfonate (OTf) is investigated in this study. We explore their electrical…

材料科学 · 物理学 2022-06-16 K. Kondratenko , D. Guerin , X. Wallart , S. Lenfant , D. Vuillaume

Recent experimental observations of anisotropic conductivity in stretched polymer electrolytes films of the polyethylene oxide family are discussed. The main experimental observations, enhancement of the ionic diffusion and conductivity in…

软凝聚态物质 · 物理学 2007-05-23 Oliver Duerr , Wolfgang Dieterich , Philipp Maas , Abraham Nitzan

The correlation between the transport properties and structural degrees of freedom of conducting polymers is a central concern in both practical applications and scientific research. In this study, we demonstrated the existence of…

Poly(3,4-ethylenedioxythiophene) : poly(styrene sulfonic acid (PEDOT:PSS), an optically transparent organic semi-conductor, constitutes a suspension of conducting PEDOT:PSS grains, shelled by an insulating layer of PSS. While a percolation…

材料科学 · 物理学 2013-09-19 A. N. Papathanassiou , I. Sakellis , J. Grammatikakis , E. Vitoratos , S. Sakkopoulos

The strikingly different charge transport behaviors in nanocomposites of multiwall carbon nanotubes (MWNTs) and conducting polymer polyethylene dioxythiophene - polystyrene sulfonic acid (PEDOT-PSS) at low temperatures are explained by…

介观与纳米尺度物理 · 物理学 2015-05-28 Paramita Kar Choudhury , S. Ramaprabhu , K. P. Ramesh , Reghu Menon

The transport of polyelectrolytes confined by oppositely charged surfaces and driven by a constant electric field is of interest in studies of DNA separation according to size. Using molecular dynamics simulations that include surface…

软凝聚态物质 · 物理学 2020-09-15 Debarshee Bagchi , Monica Olvera de la Cruz

The \textit{I-V} characteristics of four conducting polymer systems like doped polypyrrole (PPy), poly 3,4 ethylene dioxythiophene (PEDOT), polydiacetylene (PDA) and polyaniline (PA) in as many physical forms have been investigated at…

无序系统与神经网络 · 物理学 2012-10-09 D. Talukdar , U. N. Nandi , K. K. Bardhan , C. C. Bof Bufon , T. Heinzel , A. De , C. D. Mukherjee

Using molecular dynamics simulation, we investigate the effect of confinement on a system that comprises several stiff segmented polymer chains where each chain has similar segments, but length and stiffness of the segments vary among the…

软凝聚态物质 · 物理学 2015-07-14 Arash Azari , Kristian K. Müller-Nedebock

Conjugated polymers are increasingly used as organic mixed ionic-electronic conductors in electrochemical devices for neuromorphic computing, bioelectronics and energy harvesting. The design of efficient applications relies on high…

Small angle X-ray scattering (SAXS) studies in poly[2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylene vinylene] (MEH-PPV) with varying conjugation, and polyethylene dioxythiophene complexed with polystyrene sulfonate (PEDOT-PSS) in different…

软凝聚态物质 · 物理学 2010-11-11 Paramita Kar Choudhury , Debjani Bagchi , C. S. Suchand Sangeeth , Reghu Menon

We investigated the reversible resistive switching of poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS) thin films sandwiched between Al electrodes. The J-V sweep curve showed a hysteretic behavior which depends on the…

材料科学 · 物理学 2015-05-14 Hu Young Jeong , Jong Yun Kim , Tae Hyun Yoon , Sung-Yool Choi

Doped organic semiconductors are critical to emerging device applications, including thermoelectrics, bioelectronics, and neuromorphic computing devices. It is commonly assumed that low conductivities in these materials result primarily…

Electroactive polymers are smart materials that can be used as actuators, sensors, or energy harvesters. We focus on a pseudo trilayer based on PEDOT, a semiconductor polymer: the central part consists of two interpenetrating polymers and…

经典物理 · 物理学 2025-09-11 Mireille Tixier , J Pouget

Diffusive transport of small molecules within the internal structures of biological and synthetic material systems is complex because the crowded environment presents chemical and physical barriers to mobility. We explored this mobility…

软凝聚态物质 · 物理学 2020-09-29 Rajarshi Guha , Subhadip Ghosh , Darrell Velegol , Peter J. Butler , Ayusman Sen , Jennifer L. Ross

We present a numerical study of polyelectrolytes electrophoresing in free solution while squeezed by an axisymmetric confinement force transverse to their net displacement. Hybrid multi-particle collision dynamics and molecular dynamics…

软凝聚态物质 · 物理学 2016-06-22 Tyler N. Shendruk , Martin Bertrand , Gary W. Slater

Research on conjugated polymers for thermoelectric applications has made tremendous progress in recent years, which is accompanied by surging interest in molecular doping as a means to achieve the high electrical conductivities that are…

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