相关论文: Photochemistry in hot H2-dominated exoplanet atmos…
Photochemistry induced by stellar UV flux should produce haze particles in exoplanet atmospheres. Recent observations indicate that haze and/or cloud layers exist in the atmospheres of exoplanets. However, photochemical processes in…
Photochemistry is expected to change the chemical composition of the upper atmospheres of irradiated exoplanets through the dissociation of species, such as methane and ammonia, and the association of others, such as hydrogen cyanide.…
UV radiation can induce photochemical processes in exoplanet atmospheres and produce haze particles. Recent observations suggest that haze and/or cloud layers could be present in the upper atmospheres of exoplanets. Haze particles play an…
Sulfur gases significantly affect the photochemistry of planetary atmospheres in our Solar System, and are expected to be important components in exoplanet atmospheres. However, sulfur photochemistry in the context of exoplanets is poorly…
New observing capabilities coming online over the next few years will provide opportunities for characterization of exoplanet atmospheres. However, clouds/hazes could be present in the atmospheres of many exoplanets, muting the amplitude of…
A detailed modeling of simultaneous UV-photochemical and thermochemical processes in exoplanet atmosphere-like conditions is essential for the analysis and interpretation of a vast amount of current and future spectral data from exoplanets.…
Photochemical hazes are suspected to obscure molecular features, such as water, from detection in the transmission spectra of exoplanets with atmospheric temperatures < 800 K. The opacities of laboratory produced organic compounds (tholins)…
We have conducted laboratory experiments to study the chemistry in hot Jupiter atmospheres with C/O ratio of 0.35. We have compared our results with the ones obtained previously for atmospheres with a C/O ratio of 1 to investigate the…
In warm (equilibrium temperature <1000 K) gas giant exoplanet atmospheres, the observation of trace species in abundances deviating from thermochemical equilibrium predictions could be used as an indicator of disequilibrium chemical…
Photochemical hazes are expected to form and significantly contribute to the chemical and radiative balance of exoplanets with relatively moderate temperatures, possibly in the habitable zone of their host star. In the presence of humidity,…
Recent infrared spectroscopy of hot exoplanets is beginning to reveal their atmospheric composition. Deep with in the planetary atmosphere, the composition is controlled by thermochemical equilibrium. Photochemistry becomes important higher…
The interaction of exoplanets with their host stars causes a vast diversity in bulk and atmospheric compositions, and physical and chemical conditions. Stellar radiation, especially at the shorter wavelengths, drives the chemistry in the…
We present a comprehensive photochemistry model for exploration of the chemical composition of terrestrial exoplanet atmospheres. The photochemistry model is designed from the ground up to have the capacity to treat all types of terrestrial…
We investigate the impact of photochemical hazes and disequilibrium gases on the thermal structure of hot-Jupiters, using a detailed 1-D radiative-convective model. We find that the inclusion of photochemical hazes results in major heating…
Exoplanets that receive stellar irradiance of approximately Earth's or less have been discovered and many are suitable for spectral characterization. Here we focus on the temperate planets that have massive H2-dominated atmospheres, and…
A primary goal of characterizing exoplanet atmospheres is to constrain planetary bulk properties, such as their metallicity, C/O ratio, and intrinsic heat. However, there are significant uncertainties in many aspects of atmospheric physics,…
Photochemical hazes are expected to form in hot Jupiter atmospheres and may explain the strong scattering slopes and muted spectral features observed in the transmission spectra of many hot Jupiters. Absorption and scattering by…
Many parameters constraining the spectral appearance of exoplanets are still poorly understood. We therefore study the properties of irradiated exoplanet atmospheres over a wide parameter range including metallicity, C/O ratio and host…
Photochemical hazes are important opacity sources in temperate exoplanet atmospheres, hindering current observations from characterizing exoplanet atmospheric compositions. The haziness of an atmosphere is determined by the balance between…
Observational efforts in the last decade suggest the prevalence of photochemical hazes in exoplanetary atmospheres. Recent JWST observations raise growing evidence that exoplanetary hazes tend to have reflective compositions, unlike the…