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Recent observations indicated that the photoelectric conversion properties of perovskite materials are intimately related to the presence of superlattice structures and other unusual nanoscale features in them. The low dimensional or mixed…

介观与纳米尺度物理 · 物理学 2021-05-11 Susmita Bhattacharya , Goutam Kumar Chandra , P. Predeep

Metal halide perovskite solar cells being one of the fastest emerging technologies for renewable energy still has to become more industry friendly in a way that will allow using it for thin film modules or tandems with conventional silicon…

We report that device architecture engineering has a substantial impact on the reverse bias instability that has been reported as a critical issue in commercializing perovskite solar cells. We demonstrate breakdown voltages exceeding -15 V…

Lead sulfide (PbS) quantum dot (QD) photovoltaics have reached impressive efficiencies of 12%, making them particularly promising for future applications. Like many other types of emerging photovoltaic devices, their environmental…

Lead poisoning and notorious ambient instability in lead-based halide perovskites pave the way for the exploration of alternative materials for affordable and efficient solar cell fabrication. An important prerequisite to this end is the…

Hybrid perovskites have received tremendous attention due to their exceptional photovoltaic and optoelectronic properties. Among the two widely used perovskite solar cell device architectures of n-ip and p-i-n, the latter is interesting in…

Lead-free tin-based perovskites are highly appealing for the next generation of solar cells due to their intriguing optoelectronic properties. However, the tendency of Sn2+ oxidation to Sn4+ in the tin-based perovskites induces serious film…

化学物理 · 物理学 2022-06-15 Hejin Yan , Bowen Wang , Xuefei Yan , Qiye Guan , Hongfei Chen , Zheng Shu , Dawei Wen , Yongqing Cai

Metal-halide perovskites are promising materials for future optoelectronic applications. One intriguing property, important for many applications, is the tunability of the band gap via compositional engineering. While experimental reports…

材料科学 · 物理学 2019-06-27 Shuxia Tao , Ines Schmidt , Geert Brocks , Junke Jiang , Ionut Tranca , Klaus Meerholz , Selina Olthof

CsPbI3 has recently received tremendous attention as a possible absorber of perovskite solar cells (PSCs). However, CsPbI3-based PSCs have yet to achieve the high performance of the hybrid PSCs. In this work, we performed a density…

Solar to power conversion certified efficiencies of formamidinium lead iodide based single-junction perovskite solar cell is now 26%, all perovskite-perovskite tandem $\sim$28%, and the perovskite-silicon tandem solar cell is $\sim$34%…

材料科学 · 物理学 2023-06-27 Paramvir Ahlawat

Inorganic halide perovskite \ce{Cs(Rb)PbI3} has attracted significant research interest in the application of light-absorbing material of perovskite solar cells (PSCs). Although there have been extensive studies on structural and electronic…

材料科学 · 物理学 2018-07-09 Un-Gi Jong , Chol-Jun Yu , Yun-Hyok Kye , Chol-Ho Kim , Son-Guk Ri , Yue Chen

Using density-functional theory calculations, we analyze the optical absorption properties of lead (Pb)-free metal halide perovskites (AB$^{2+}$X$_3$) and double perovskites (AB$^+$B$^{3+}$X$_6$) (A = Cs or monovalent organic ion, B$^{2+}$…

材料科学 · 物理学 2017-06-19 Weiwei Meng , Xiaoming Wang , Zewen Xiao , Jianbo Wang , David Mitzi , Yanfa Yan

Open circuit voltage decay measurements are performed on methylammonium lead iodide (CH3NH3PbI3) perovskite solar cells to investigate the charge carrier recombination dynamics. The measurements are compared to the two reference…

材料科学 · 物理学 2014-07-07 A. Baumann , K. Tvingstedt , M. C. Heiber , S. Väth , C. Momblona , H. J. Bolink , V. Dyakonov

The basic processes of perovskite radiation resistance are discussed for photo- and high-energy electron irradiation. It is shown that ionization of iodine ions and a staged mechanism of elastic scattering (upon intermediate scattering on…

介观与纳米尺度物理 · 物理学 2018-12-17 Boris L. Oksengendler , Nigora N. Turaeva , Marlen I. Akhmedov

Methylammonium lead triiodide (CH3NH3PbI3) perovskite solar cell is a gem in the list of photovoltaic semiconductors. Although there are numerous fundamental and technological questions yet to be addressed covering various aspects of this…

材料科学 · 物理学 2017-04-20 Pradeep R. Varadwaj , Arpita Varadwaj , Koichi Yamashita

A modified detailed balance model is built to understand and quantify efficiency loss of perovskite solar cells. The modified model captures the light-absorption dependent short-circuit current, contact and transport-layer modified carrier…

Methylammonium lead iodide (CH3NH3PbI3) perovskite solar cell has produced a remarkable breakthrough in the photovoltaic history of solar cell technology because of its outstanding device based performance as a light-harvesting…

化学物理 · 物理学 2017-03-31 Arpita Varadwaj , Pradeep R Varadwaj , Koichi Yamashita

Pnictogen chalcohalides (MChX) have recently emerged as promising nontoxic and environmentally friendly photovoltaic absorbers, combining strong light absorption coefficients with favorable low-temperature synthesis conditions. Despite…

Organohalide perovskite with a variety of surface structures and morphologies have shown promising potential owing to the choice of the type of heterostructure dependent stability. We systematically investigate and discuss the impact of…

应用物理 · 物理学 2022-07-18 Rahul Singh , Prashant Singh , Ganesh Balasubramanian

The MAPbI$_3$ halide perovskite single crystals are studied at 5 K temperature using the photoluminescence excitation spectroscopy. Two non-interacting types of states are determined: bound excitons and defect-related states. Excitation of…

介观与纳米尺度物理 · 物理学 2020-05-07 A. O. Murzin , N. I. Selivanov , V. O. Kozlov , I. I. Ryzhov , A. V. Emeline , Yu. V. Kapitonov