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First-principles calculations were performed to investigate the ferroelectric properties of barium titanate and bismuth ferrite, as well as phonon dispersion of BaTiO3, using density functional theory and density functional perturbation…

材料科学 · 物理学 2014-12-08 Hong-Jian Feng

Multiferroic perovskites that exhibit room temperature magnetization and polarization have immense potential in the next generation of magneto-electric and spintronic memory devices. In this work, the magnetic and ferroelectric properties…

BiFeO3 is the most famous multiferroic material, but its G-type antiferromagnetism is highly desirable to be replaced by strong macroscopic magnetism beyond room temperature. Here we obtain double perovskite Bi2FeMoO6 with R3 (#146) space…

材料科学 · 物理学 2014-10-20 Peng Chen , Bang-Gui Liu

Bismuth ferrite is one of the most widely studied multiferroic materials because of its large ferroelectric polarisation coexisting with magnetic order at room temperature. Using density functional theory (DFT), we identify several…

材料科学 · 物理学 2021-05-12 Bastien F. Grosso , Nicola A. Spaldin

Solid solution BiFe1-xCoxO3 shows anti-ferromagnetic order and pyroelectric order, simultaneously. It has been known that BiFe1-xCoxO3 exhibits a structural phase transition between monoclinic and tetragonal phases as x increases. This…

材料科学 · 物理学 2021-12-15 Hiroshi Katsumoto , Kunihiko Yamauchi , Tamio Oguchi

Structural, impedance, ferroelectric and magnetic properties were examined in multiferroic Bi_{2}Fe_{4(1-x)}Co_{4x}O_{9} (0$\leq$x$\leq$0.02) ceramics synthesized via solid-state reaction method. X-ray diffraction analysis and Rietveld…

材料科学 · 物理学 2016-05-06 S. R. Mohapatra , B. Sahu , M. Chandrasekhar , P. Kumar , S. D. Kaushik , S. Rath , A. K. Singh

The substitution of bismuth by samarium in BiFeO3 is known to induce a structural phase transition from the polar phase to a non-polar phase, with a possible antiferroelectric intermediate structure. In this paper, we investigate the impact…

Advancing the functional performance of bismuth ferrite (BiFeO$_3$) requires precise control over phase stability and microstructure, challenges often complicated by secondary phase formation within the Bi$_2$O$_3$-Fe$_2$O$_3$ system. In…

材料科学 · 物理学 2025-11-27 Subir Majumder , Paul Ben Ishai , Gilad Orr

First principles calculations were performed to study the ground state electronic properties of BaFeO3 (BFO) within the density functional theory (DFT). Adopting generalized gradient approximation (GGA) exchange and correlation functional…

材料科学 · 物理学 2007-05-23 Hong-Jian Feng , Fa-Min Liu

Thermal excitations typically reduce the electric polarization in ferroelectric materials. Here, we show by means of first-principles calculations that multiferroic BiFe$_{1-x}$Co$_{x}$O$_{3}$ solid solutions with $0.25 \le x \le 0.50$…

材料科学 · 物理学 2020-09-16 Cesar Menendez , Claudio Cazorla

Due to its multiferroic properties and narrow optical bandgap, Bismuth ferrite has been widely explored for spintronics, photovoltaics, and photocatalysis applications. Bismuth ferrite can be synthesized in various forms like bulk, thin…

材料科学 · 物理学 2025-09-10 Naresh Prajapati , G. Surya Prakash , Manoj Kumar , Himanshu Pandey

BiVO3F is a promising material used in solar energy conversion systems. Here, we first report the calculated structural, electronic, and surface reaction properties using PBE and hybrid density functionals. We found it is a direct band gap…

材料科学 · 物理学 2021-06-25 Taifeng Liu* , Tongling Liu , Yongqiang Zheng

BiFeO$_3$ is a technologically relevant multiferroic perovskite featuring ferroelectricity and antiferromagnetism. Its lattice, magnetic, and ferroelectric degrees of freedoms are coupled to its optically active excitations and thus hold…

材料科学 · 物理学 2024-10-17 Aseem Rajan Kshirsagar , Sven Reichardt

Oxide superlattices represent a potent avenue for tailoring emergent electronic phases through sophisticated interfacial charge transfer and dynamic lattice distortions. This study systematically investigates the structural and electronic…

材料科学 · 物理学 2026-03-27 Rajan Gowsalya , Monirul Shaikh , Sathiyamoorthy Buvaneswaran , Saurabh Ghosh

BiFeO$_3$ (BFO) shows both ferroelectricity and magnetic ordering at room temperature but its ferromagnetic component, which is due to spin canting, is negligible. Substitution of transition-metal atoms such as Co for Fe is known to enhance…

The probability density function (PDF) and cumulative density function (CDF) of bulk BiFeO3, nanostructured BiFeO$_3$, and thick film of BiFeO$_{2.85}$ were studied in detail based on their experimental absorption data. The goal of this…

材料科学 · 物理学 2025-10-21 Ramachandran Balakrishnan

BiFeO3 is a model multiferroic in which the ferroelectric polarization is coupled to ferroelastic lattice distortions, yet deterministic control of its domain structure remains limited by high switching fields and competing polarization…

There have been a large number of papers on bismuth ferrite (BiFeO3) over the past few years, trying to exploit its room-temperature magnetoelectric multiferroic properties. Although these are attractive, BiFeO3 is not the ideal…

Designing materials with controlled photovoltaic response may lead to improved solar cells or photosensors. In this regard, ferroelectric superlattices have emerged as a rich platform to engineer functional properties. In addition,…

材料科学 · 物理学 2025-02-20 Francesco Delodovici , Charles Paillard

Magnetoelectric multiferroic composite of two types of multiferroic (Type I and II) consisting BiFeO3 and TbMnO3 is studied for enhanced magnetic and transport properties. A narrower band gap is estimated from the UV-visible absorption…

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