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Dissociative electron attachment (DEA) to the HNC$_3$ is modeled theoretically using a first-principles approach. In HNC$_3$+$e^-$ collisions, there is a low-energy resonance, which has a repulsive character along the H+NC$_3$ coordinate…

In the present study, dissociative electron attachment (DEA) measurements with gas phase HMX, octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine, $C_4H_8N_8O_8$, have been performed by means of a crossed electron-molecular beam experiment.…

Motivated by the huge need of data for non-equilibrium plasma modeling, a theoretical investigation of dissociative electron attachment to the NO molecule is performed. The calculations presented here are based on the…

原子物理 · 物理学 2020-12-02 V. Laporta , I. F. Schneider , J. Tennyson

We report novel total electron scattering cross sections (TCS) from nitric oxide (NO) in the impact energy range from 1 to 15 eV by using a magnetically confined electron transmission apparatus. The accuracy of the data to within 5% and its…

化学物理 · 物理学 2025-05-09 Ana I. Lozano , Juan C. Oller , Paulo Limão-Vieira , Gustavo García

Using the velocity map imaging technique, we studied and characterized the process of Dissociative Electron Attachment (DEA) in polyatomic molecules like Water, Hydrogen Sulphide, Ammonia, Methane, Formic Acid and Propyl Amine. We present…

化学物理 · 物理学 2010-07-30 N. Bhargava Ram , V. S. Prabhudesai , E. Krishnakumar

In this article, density functional theory (DFT) and natural bond orbital (NBO) calculations are performed to understand experimental observations of dissociative electron attachment (DEA) to SO$_2$. The molecular structure, fundamental…

原子与分子团簇 · 物理学 2018-07-09 Irina Jana , Sumit Naskar , Mousumi Das , Dhananjay Nandi

Kinetic energy and angular distributions of O$^-$ ions formed by dissociative electron attachment to CO molecule have been studied for 9, 9.5, 10, 10.5, 11, 11.5 eV incident electron energies around the resonance using time sliced velocity…

原子与分子团簇 · 物理学 2015-02-10 Pamir Nag , Dhananjay Nandi

An observed broad resonance peak in dissociative electron attachment (DEA) cross sections to a molecule might be due to either closely lying or overlapping resonances involved in the process. We developed a state-of-the-art experimental…

化学物理 · 物理学 2015-06-09 Pamir Nag , Dhananjay Nandi

In this paper, we discuss the dissociative electron attachment process in Ammonia. Kinetic energy and angular distributions of H^{-} and NH_{2}^{-} fragment anions across the two well known resonances at 5.5 eV and 10.5 eV are reported. The…

化学物理 · 物理学 2010-07-30 N. Bhargava Ram , E. Krishnakumar

The article presents an improved theoretical description of dissociative recombination of HCO$^+$ and DCO$^+$ ions with a low energy electron. In the previous theoretical study (Phys. Rev. A {\bf 74}, 032707) on HCO$^+$, the vibrational…

化学物理 · 物理学 2009-11-13 Nicolas Douguet , Viatcheslav Kokoouline , Chris H. Greene

In this study, we examine the interactions of low- to intermediate-energy electrons (0$-$45 eV) with carbonyl sulfide (OCS). These collisions lead to the formation of several anionic fragments, including C$^-$, O$^-$, S$^-$, and SO$^-$.…

原子与分子团簇 · 物理学 2025-12-18 Soumya Ghosh , Narayan Kundu , Aryya Ghosh , Dhananjay Nandi

Dissociative electron attachment (DEA) is one of the processes that shows a strong coupling between the nuclear and electronic degrees of freedom in a molecule. This coupling results in an efficient transformation of the kinetic energy of…

化学物理 · 物理学 2024-04-17 Suvasis Swain , Akshay Kumar , E. Krishnakumar , Vaibhav S. Prabhudesai

Static correlation error(SCE) inevitably emerges when a dissociation of a covalent bond is described with a conventional denstiy-functional theory (DFT) for electrons. SCE gives rise to a serious overshoot in the potential energy at the…

计算物理 · 物理学 2020-08-10 Hideaki Takahashi

Cross sections and thermal rate coefficients are computed for electron-impact dissociative recombination and vibrational excitation/de-excitation of the N$^+_2$ molecular ion in its lowest six vibrational levels, for collision…

Momentum imaging measurements from two experiments are presented and interpreted with the aid of new ab initio theoretical calculations to describe the dissociative electron attachment (DEA) dynamics. We address the problem of how the 4 eV…

We experimentally probe electron collisions with HC$_3$N in the energy range from 0 to 10 eV with the focus on vibrational excitation and dissociative electron attachment. The vibrational excitation cross sections show a number of…

化学物理 · 物理学 2018-12-04 M. Ranković , P. Nag , M. Zawadzki , L. Ballauf , J. Žabka , M. Polášek , J. Kočišek , J. Fedor

Complete dissociation dynamics of low-energy electron attachment to carbon disulfide have been studied using the velocity slice imaging (VSI) technique. The ion yields of S- and CS- fragment ions as the function of incident electron energy…

原子与分子团簇 · 物理学 2022-09-28 Anirban Paul , Dhananjay Nandi

Dissociative electron attachment (DEA) shows functional group-dependent site selectivity in the $H^-$ ion channel. In this context, the thiol functional group has yet to be studied in great detail, although this functional group carries…

化学物理 · 物理学 2024-04-17 Sukanta Das , Vaibhav S. Prabhudesai

The activation cross sections of (d,p), (d,2n), (d,3n), and (d,2p) reactions on 63,65Cu were measured in the energy range from 4 to 20 MeV using the stacked-foils technique. Then, following the available elastic-scattering data analysis…

The fragmentation of 1-propanol resulting from dissociative electron attachment has been explored across an energy range of 3.5 to 16 eV. Four distinct ion species are identified: $\text{H}^{-}$, $\text{O}^{-}$, $\text{OH}^{-}$, and…

原子与分子团簇 · 物理学 2026-02-06 Soumya Ghosh , Dipayan Chakraborty , Anirban Paul , Dhananjay Nandi
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