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A fascinating aspect of Rydberg atoms is their ability to form huge but very weakly bound molecules with a ground state atom, only held together by a scattering process between the latter and the Rydberg electron. Beyond the usual way of…

原子物理 · 物理学 2012-07-31 Andrej Junginger , Jörg Main , Günter Wunner

Atoms can form molecules if they attract each other. Here, we show that atoms are also able to form bound states not due to the attractive interaction but because of destructive interference. If the interaction potential changes in a…

量子气体 · 物理学 2021-02-22 Paweł Matus , Krzysztof Giergiel , Krzysztof Sacha

The formation of ultralong-range Rydberg molecules is a result of the attractive interaction between Rydberg electron and polarizable ground state atom in an ultracold gas. In the nondegenerate case the backaction of the polarizable atom on…

原子物理 · 物理学 2015-07-10 A. Gaj , A. T. Krupp , P. Ilzhöfer , R. Löw , S. Hofferberth , T. Pfau

We examine topological phases and symmetry-protected electronic edge states in the context of a Rydberg composite: a Rydberg atom interfaced with a structured arrangement of ground-state atoms. The electronic Hamiltonian of such a composite…

量子物理 · 物理学 2024-05-20 Matthew T. Eiles , Christopher W. Wächtler , Alexander Eisfeld , Jan M. Rost

The internal electric field of a Rydberg atom electron can bind a polar molecule to form a giant ultralong-range stable polyatomic molecule. Such molecules not only share their properties with Rydberg atoms, they possess huge permanent…

原子物理 · 物理学 2015-05-27 Seth T. Rittenhouse , M. Mayle , P. Schmelcher , H. R. Sadeghpour

We propose a simple setup of Rydberg atoms in a honeycomb lattice which gives rise to topologically protected edge states. The proposal is based on the combination of dipolar exchange interaction, which couples the internal angular momentum…

We present a novel binding mechanism where a neutral Rydberg atom and an atomic ion form a molecular bound state at large internuclear distance. The binding mechanism is based on Stark shifts and level crossings which are induced in the…

原子物理 · 物理学 2021-12-28 Markus Deiß , Shinsuke Haze , Johannes Hecker Denschlag

The formation of molecules and supramolecular structures results from bonding by conservative forces acting among electrons and nuclei and giving rise to equilibrium configurations defined by minima of the interaction potential. Here we…

原子物理 · 物理学 2015-02-23 Mikhail Lemeshko , Hendrik Weimer

Topological physics opens up a plethora of exciting phenomena allowing to engineer disorder-robust unidirectional flows of light. Recent advances in topological protection of electromagnetic waves suggest that even richer functionalities…

We study the possibility to use interaction between a polar molecule in the ground electronic and vibrational state and a Rydberg atom to construct two-qubit gates between molecular qubits and to coherently control molecular states. A polar…

量子物理 · 物理学 2017-09-13 Elena Kuznetsova , Seth T. Rittenhouse , Hossein R. Sadeghpour , Susanne F. Yelin

A generalized class of ultra-long-range Rydberg molecules is proposed which consist of a multichannel Rydberg atom whose outermost electron creates a chemical bond with a distant ground state atom. Such multichannel Rydberg molecules…

原子物理 · 物理学 2015-11-11 Matthew T. Eiles , Chris H. Greene

We unravel some peculiar properties of ultralong-range Rydberg molecules formed by an $s$-state $^{87}$Rb Rydberg atom and a corresponding ground-state atom whose electronic orbitals are spherically symmetric and therefore should not be…

原子物理 · 物理学 2019-02-06 Frederic Hummel , Christian Fey , Peter Schmelcher

A Rydberg and a ground-state atom can form ultralong range diatomic molecules provided the interaction between the ground-state atom and the Rydberg electron is attractive [C. H. Greene, et al., Phys. Rev. Lett. 85, 2458 (2000)]. A…

原子物理 · 物理学 2008-07-15 Ivan C. H. Liu , Jovica Stanojevic , Jan M. Rost

Rydberg molecule, formed by one or more Rydberg atoms, exhibits remarkable properties, including an exceptionally large spatial extent, rich rovibrational level structures, permanent electric dipole moments, and a pronounced sensitivity to…

原子物理 · 物理学 2026-03-11 Jingxu Bai , Yuechun Jiao , Xiao-Qiang Shao , Weibin Li , Jianming Zhao

A Rydberg molecule is composed of an outer electron that collides on the residual ionic core. Typical states of Rydberg molecules display entanglement between the outer electron and the core. In this work we quantify the average…

量子物理 · 物理学 2007-05-23 M Lombardi , A Matzkin

This Ph.D. tutorial discusses ultra-long-range Rydberg molecules, the exotic bound states of a Rydberg atom and one or more ground state atoms immersed in the Rydberg electron's wave function. This novel chemical bond is distinct from an…

原子物理 · 物理学 2019-09-04 Matthew T Eiles

The groundstate configuration and the eigenmodes of two parallel two-dimensional classical atoms are obtained as function of the inter-atomic distance (d). The classical particles are confined by identical harmonic wells and repel each…

凝聚态物理 · 物理学 2009-10-30 B. Partoens , V. A. Schweigert , F. M. Peeters

We review ultralong-range Rydberg molecules (ULRM), which are bound states between a Rydberg atom and one or more ground-state atoms with bond lengths on the order of thousands of Bohr radii. The binding originates from multiple…

原子物理 · 物理学 2020-03-18 Christian Fey , Frederic Hummel , Peter Schmelcher

Topological behavior has been observed in quantum systems including ultracold atoms. However, background harmonic traps for cold-atoms hinder direct detection of topological edge states arising at the boundary because the distortion fuses…

量子气体 · 物理学 2017-08-17 Mekena Metcalf , Chen-Yen Lai , Kevin Wright , Chih-Chun Chien

Optically trapped Rydberg atoms are a suitable platform to explore quantum many-body physics mediated by long-range atom--atom interactions that can be engineered through externally applied light fields. However, this approach is limited to…

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