相关论文: Deuterium chemistry and D/H ratios in Class 0/I pr…
Although deuterium enrichment of water may provide an essential piece of information in the understanding of the formation of comets and protoplanetary systems, only a few studies up to now have aimed at deriving the HDO/H2O ratio in…
Deuterated interstellar molecules frequently have abundances relative to their main isotopologues much higher than the overall elemental D-to-H ratio in the cold dense interstellar medium. The H$_3^+$ and its isotopologues play a key role…
The inheritance of material across the star and planet formation process is traced by deuterium fractionation. We report here the first detection of doubly deuterated methanol towards pre-stellar cores. We study the deuterium fractionation…
Theory predicts, and observations confirm, that the column density ratio of a molecule containing D to its counterpart containing H can be used as an evolutionary tracer in the low-mass star formation process. Since it remains unclear if…
We present results from the first molecular line survey to search for the fundamental complex organic molecule, methanol (CH$_{3}$OH), in 14 Class 0/I proto-brown dwarfs (proto-BDs). IRAM 30-m observations over the frequency range of 92-116…
Deuterated molecules can be used to study the physical conditions and the astro-chemical evolution of molecular clouds. large-sample surveys for deuterated molecules are needed to understand the enhancement of deuterated molecules from…
Deuterium fractionation becomes highly efficient in cold, dense cores where CO is frozen out. Cyclopropenylidene (c-C3H2), an early-formed carbon ring, and its deuterated isotopologues trace gas-phase deuteration in these environments. We…
We report the detection of Deuterium absorption at redshift 2.525659 towards Q1243+3047. We describe improved methods to estimate the Deuterium to Hydrogen abundance ratio (D/H) in absorption systems, including improved modeling of the…
Understanding gas-grain chemistry of deuterium in star-forming objects may help to explain their history and present state. We aim to clarify how processes in ices affect the deuterium fractionation. In this regard, we investigate a…
We use spectra and maps of NH2D, ND2H, and ND3, obtained with the CSO, IRAM 30m and Arecibo telescopes, to study deuteration processes in dense cores. The data include the first detection of the hyperfine structure of ND2H. The emission of…
Deuterated molecules are a useful diagnostic tool to probe the evolution and the kinematics in the earliest stages of star formation. Due to the low temperatures and high densities in the centre of pre-stellar cores, the deuterium fraction…
The study of deuteration in pre-stellar cores is important to understand the physical and chemical initial conditions in the process of star formation. In particular, observations toward pre-stellar cores of methanol and deuterated…
High degrees of deuterium fractionation are commonly found in cold prestellar cores and in the envelopes around young protostars. As it brings strong constraints to chemical models, deuterium chemistry is often used to infer core history or…
Deuterium fractionation in molecular ions, in particular HCO+, has been extensively used to estimate the degree of ionization in molecular clouds. This paper reviews recent work on ionization degree in homogeneous clouds. We will show that…
We investigated the chemistry of nitrogen--containing species, principally isotopomers of CN, HCN, and HNC, in a sample of pre-protostellar cores. We used the IRAM 30 m telescope to measure the emission in rotational and hyperfine…
We upgraded the chemical network from the UMIST Database for Astrochemistry 2006 to include isotopes such as ^{13}C and ^{18}O. This includes all corresponding isotopologues, their chemical reactions and the properly scaled reaction rate…
Supernova remnants (SNRs) may regulate star formation in galaxies. For example, SNR-driven shocks may form new molecular gas or compress pre-existing clouds and trigger the formation of new stars. To test this scenario, we measure the…
Deuteration is a crucial tool to understand the complexity of interstellar chemical processes, especially when they involve the interplay of gas-phase and grain-surface chemistry. In the case of multiple deuteration, comparing observation…
Primordial abundances of light elements are sensitive to the physics of the early Universe and can directly constrain cosmological quantities, such as the baryon-to-photon ratio $\eta_{10}$, the baryon density and the number of neutrino…
Deuteration is sensitive to environmental conditions in star-forming regions. To investigate NH$_2$D chemistry, we compared the spatial distribution of ortho-NH$_2$D $1_{11}^s-1_{01}^a$, NH$_3$(1,1) and NH$_3$(2,2) in 12 late-stage massive…