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Double-perovskite oxides that contain both 3d and 5d transition metal elements have attracted growing interest as they provide a model system to study the interplay of strong electron interaction and large spin-orbit coupling (SOC). Here,…

The synthesis of the double perovskite Sr2FeWO6 through the direct combustion technique is reported. A complete characterization of the crystalline structure is performed from Synchrotron X-ray measurements and subsequent Rietveld analysis.…

A comparative study of the effect of Fe and Ni doping on the bismuth based perovskite La0.6Bi0.4MnO3.1, a projected spintronics magnetic semiconductor has been carried out. The doped systems show an expressive change in magnetic ordering…

Zn1-xRxO (R = Li, Mg, Cr, Mn, Fe and Cd) were obtained by using co-precipitation synthesis technique with constant weight percent of 3% from R ions. The phase composition, crystal structure, morphology, Density Functional Theory (DFT), and,…

材料科学 · 物理学 2021-10-26 T. A. Abdel-Baset , M. Abdel-Hafiez

In this work, we report the synthesis and investigation of structural, electronic, and magnetic properties of La$_{1.5}$Ca$_{0.5}$(Co$_{0.5}$Fe$_{0.5}$)IrO$_6$. Our polycrystalline sample forms as a single-phase double perovskite in…

We report the comprehensive experimental results identifying the magnetic spin ordering and the magnetization dynamics of a double perovskite Pr2CoFeO6 by employing the (dc and ac) magnetization, powder neutron diffraction (NPD) and X-ray…

Exploring new magnetic materials is essential for finding advantageous functional properties such as magnetoresistance, magnetocaloric effect, spintronic functionality, and multiferroicity. Versatile classes of double perovskite compounds…

强关联电子 · 物理学 2019-05-03 M. K. Kim , J. Y. Moon , S. H. Oh , D. G. Oh , Y. J. Choi , N. Lee

Remarkably, doping isovalent $d^{10}$ and $d^0$ cations onto the $B$'' site in $A_2B$'$B$''O$_6$ double perovskites has the power to direct the magnetic interactions between magnetic $B$' cations. This is due to changes in orbital…

Electronic structure calculations indicate that the Sr2FeSbO6 double perovskite has a flat-band set just above the Fermi level that includes contributions from ordinary sub-bands with weak kinetic electron hopping plus a flat sub-band that…

The structure, electronic, and magnetic properties of the Mo-doped perovskite La0.7Ca0.3Mn1-xMoxO3 (x < 0.1) have been studied. A significant increase in resistivity and lattice parameters were observed with Mo doping. A marginal decrease…

强关联电子 · 物理学 2007-05-23 G. Narsinga Rao , J. W. Chen

The magnetic properties of the double perovskite oxide $Sr_{2}$FeMo$O_{6}$ are analyzed using a mixed-spin Ising model with spins $\left( \frac{1}{2},\frac{5}{2}\right) $ in the presence of a random crystal field $\Delta$ and exchange…

We report magnetic and magnetoelectric studies on BiFeO3 and divalent cation (A) suvtitute Bi0.7A0.3FeO3 (A = Sr,Ba, and Sr0.5Ba0.5). It is shown that the rapid increase of magnetization at the Neel temperature (TN = 642 K) is suppressed in…

材料科学 · 物理学 2009-11-13 V. B. Naik , R. Mahendiran

Electronic structure, electrical transport, dc and ac magnetization properties of the hole substituted (Sr2+) partially B-site disordered double perovskite Pr2-xSrxCoMnO6 system have been investigated. Electronic structure was probed by…

Magnetic double perovskite compounds provide a fertile playground to explore interesting electronic and magnetic properties. By complementary macroscopic characterizations, neutron powder diffraction measurements and first-principles…

强关联电子 · 物理学 2024-04-03 Cheng Su , Xu-Tao Zeng , Kaitong Sun , Denis Sheptyakov , Ziyu Chen , Xian-Lei Sheng , Haifeng Li , Wentao Jin

We present neutron diffraction measurements on single crystal samples of non-superconducting Ba(Fe1-xCrx)2As2 as a function of Cr-doping for 0<=x<=0.47. The average SDW moment is independent of concentration for x<=0.2 and decreases rapidly…

The nanoscopic magneto-electronic phase separation in doped La1-xSrxCoO3 perovskites was studied with local probes. The phase separation is directly observed by M\"ossbauer spectroscopy in the studied doping range of 0.05 <= x <= 0.25 both…

The magnetic susceptibility, crystal and magnetic structures, and electronic structure of double perovskite Sr2ScOsO6 are reported. Using both neutron and x-ray powder diffraction we find that the crystal structure is monoclinic P21/n from…

强关联电子 · 物理学 2015-04-06 A. E. Taylor , R. Morrow , D. J. Singh , S. Calder , M. D. Lumsden , P. M. Woodward , A. D. Christianson

The Half-Metallic Ferromagnetic behavior of some double perovskites attracts much interest. In this work, we studied the magnetic behavior of the double perovskite Pb2FeReO6. The magnetic atoms are Fe and Re and have the spins S=5/2 and…

材料科学 · 物理学 2020-02-20 S. Mtougui , S. Idrissi , H. Labrim , N. El Mekkaoui , I. El Housni , S. Ziti , R. Khalladi , L. Bahmad

The 3$d$-5$d$ based double perovskites are of current interest as they provide model system to study the interplay between electronic correlation ($U$) and spin-orbit coupling (SOC). Here we report detailed structural, magnetic and…

强关联电子 · 物理学 2017-10-30 K C Kharkwal , A K Pramanik

The subtle interplay between spin-orbit coupling, exchange interactions, and cation ordering can lead to exotic magnetic states in transition-metal ions. We report a comprehensive study of the Re-based (5$d^1$) ordered double perovskite…