相关论文: Solvent Effects on the Menshutkin Reaction
In this paper, we present indirect methods to define the change in the rates of hydrolysis and condensation reactions of a silica oxide network formed of (3-glycidoxypropyl)methyltriethoxysilane (GPTMS) and (3-aminopropyl)triethoxysilane…
The synthesis of the high-$T_c$ superhydride CaH$_6$ has stimulated significant interest in understanding synthesis pathways for metastable hydrides. However, the microscopic mechanisms governing such hydrogenation reactions remain poorly…
The Large Hadron Collider (LHC) at CERN is a 7 TeV proton synchrotron, with a design stored energy of 362 MJ per beam. The high-luminosity (HL-LHC) upgrade will increase this to 675 MJ per beam. In order to protect the superconducting…
Within the recently developed five-dimensional Langevin approach for the description of fission of heavy nuclei, we have calculated the fission fragments mass and kinetic energy distributions for the fission of $^{180}$Hg and $^{190}$Hg…
The charge exchange reaction pp $\rightarrow$ n $\Delta^{++}$ at high energies is examined. The cross section of this reaction is estimated for RHIC and LHC energies based on data taken at the lower energies of the Intersecting Storage Ring…
Cosmic-rays with energies up to $3\times10^{20}$ eV have been observed, as have as have astrophysical neutrinos with energies above 1 PeV. In this talk, I will discuss some of the unique phenomena that occur when particles with TeV energies…
We report measurements of the cross-section and a complete set of polarization transfer coefficients for the ${}^{3}{\rm He}(p,n)$ reaction at a bombarding energy $T_p$ = 346 MeV and a reaction angle $\theta_{\rm lab}$ = $0^{\circ}$. The…
Tetrahedral liquids such as water and silica-melt show unusual thermodynamic behavior such as a density maximum and an increase in specific-heat when cooled to low temperatures. There is a debate in the literature whether these phenomena…
We study the transport of methane in the external water envelopes surrounding water-rich super-Earths and estimate its outgassing into the atmosphere. We investigate the influence of methane on the thermodynamics and mechanics of the water…
Towards the pre-stellar core L1544, the methanol (CH$_3$OH) emission forms an asymmetric ring around the core centre, where CH$_3$OH is mostly in solid form, with a clear peak 4000~au to the north-east of the dust continuum peak. As part of…
The inelastic neutral reaction of neutrino on 4He is calculated microscopically, including full final state interaction among the four nucleons. The calculation is performed using the Lorentz integral transform (LIT) method and the…
Depleted carbonate hydrocarbon reservoirs are promising sites for geological CO2 storage, yet the presence of residual hydrocarbons introduces complex pore-scale interactions that influence the dynamics of solid dissolution. This study…
The spin Seebeck effect (SSE) signal of magnon polarons in bulk-Y3Fe5O12 (YIG)/Pt heterostructures is found to drastically change as a function of temperature. It appears as a dip in the total SSE signal at low temperatures, but as the…
Context: When a rotating neutron star loses angular momentum, the reduction in the centrifugal force makes it contract. This perturbs each fluid element, raising the local pressure and originating deviations from beta equilibrium that…
The incorporation of the Breit interaction in atomic and molecular calculations is discussed in the framework of four-component all-electron and two-component relativistic effective core potential (RECP)formalisms. Contributions of the…
We report adaptive resolution molecular dynamics simulations of a flexible linear polymer in solution. The solvent, i.e., a liquid of tetrahedral molecules, is represented within a certain radius from the polymer's center of mass with a…
The phase behavior of hydrocarbon fluids confined in porous media has been reported to deviate significantly from that in the bulk environment due to the existence of sub-10nm pores. Though experiments and simulations have measured the…
The $pp\to pp\gamma$ bremsstrahlung cross section is calculated within the method of coordinate space representation. It is shown that in the beam energy range of 350--450~MeV a deep attractive NN-potential with forbidden states (Moscow…
The paper presents the results of experiments on measuring the cross sections for elastic scattering and nucleon transfer channels in the $^{6}$Li + $^{9}$Be reaction at an incident energy of 68 MeV: $^{9}$Be($^{6}$Li,$^{6}$Li)$^{9}$Be,…
Excess molar enthalpies, $H_{\text{m}}^{\text{E}}$, have been measured using a Tian-Calvet microcalorimeter for the systems CH$_3$(CH$_2$)$_{u-1}$OH ($u$ = 1,2,3,4,7,10) + cyclohexylamine at 298.15 K and 0.1 MPa. The…