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With a microwave-regime cyclic three-state configuration, an enantiomer-selective state transfer~(ESST) is carried out through the two-path interference between a direct one-photon coupling and an effective two-photon coupling. The…

量子物理 · 物理学 2020-04-15 Jin-Lei Wu , Yan Wang , Jin-Xuan Han , Cong Wang , Shi-Lei Su , Yan Xia , Yongyuan Jiang , Jie Song

We here report on a quantitative study of Enantiomer-Specific State Transfer (ESST), performed in a pulsed, supersonic molecular beam. The chiral molecule 1-indanol is cooled to low rotational temperatures (1-2 K) and a selected rotational…

We study the enantio-specific state transfer in a four-level model for symmetric-top chiral molecules. Such a model is formed by coupling the electric-dipole transitions among four appropriate working states with three electromagnetic…

量子物理 · 物理学 2022-04-27 Bo Liu , Chong Ye , C. P. Sun , Yong Li

Three-wave mixing spectroscopy of chiral molecules, which exist in left-handed and right-handed conformations, allows for enantio-selective population transfer despite random orientation of the molecules. This is based on constructive…

量子物理 · 物理学 2019-07-09 Monika Leibscher , Thomas F. Giesen , Christiane P. Koch

State-selective enantiomeric excess is realized using microwave-driven coherent population transfer. The method selectively promotes either R or S molecules to a higher rotational state by phase-controlled microwave pulses that drive…

化学物理 · 物理学 2017-03-23 Sandra Eibenberger , John Doyle , David Patterson

Microwave three-wave mixing allows for enantiomer-selective excitation of randomly oriented chiral molecules into rotational states with different energy. The random orientation of molecules is reflected in the degeneracy of the rotational…

量子物理 · 物理学 2022-08-02 Monika Leibscher , Jonas Kalveram , Christiane P. Koch

We report a combined experimental and theoretical study on the influence of microwave pulse durations on enantiomer-specific state transfer. Two triads of rotational states within a chiral molecule (1-indanol) are selected to address the…

Optical methods of enantiomeric-specific state transfer had been proposed theoretically based on a cyclic three-level system of chiral molecule. According to these theoretical methods, recently the breakthrough progress has been reported in…

量子物理 · 物理学 2020-11-16 Quansheng Zhang , Chong Ye , Yu-Yuan Chen , Yong Li

An interesting method of fast enantio-specific state transfer is proposed for cyclic three-level systems of chiral molecules. We show that the fast population transfer via shortcut to adiabaticity can be accomplished for the cyclic…

量子物理 · 物理学 2023-05-10 Jian-Jian Cheng , Chong Ye , Yong Li

An interesting class of molecules is that in which the molecules do not possess a stereogenic center but can become chiral due to their spatial arrangement. These molecules can be seen as chiral conformers, whose two non-superimposable…

化学物理 · 物理学 2021-06-11 Cristóbal Pérez , Amanda L. Steber , Anna Krin , Melanie Schnell

Enantiomer-specific state transfer (ESST), which involves transferring enantiomers with different handedness of a chiral molecule into different-energy internal states, is a challenging yet significant task. Previous ESST methods are based…

量子物理 · 物理学 2024-10-30 Fen Zou , Yong Li , Peng Zhang

We explore the spatial enantioseparation of gaseous chiral molecules for the cyclic three-level systems coupled with three electromagnetic fields. Due to molecular rotations, the specific requirements of the polarization directions of the…

原子物理 · 物理学 2021-11-16 Bo Liu , Chong Ye , C. P. Sun , Yong Li

We perform a combined analytical and numerical investigation to explore how an analytically designed pulse can precisely control the rotational motions of a single-molecular polariton formed by the strong coupling of two low-lying…

量子物理 · 物理学 2023-08-04 Li-Bao Fan , Chuan-Cun Shu

Enantio-conversion with the help of electromagnetic fields is an essential issue due to the chirality-dependence of many chemical, biological, and pharmaceutical processes. Here, we propose a method for this issue based on a five-level…

量子物理 · 物理学 2021-03-03 Chong Ye , Bo Liu , Yu-Yuan Chen , Yong Li

Single-loop cyclic three-level ($\Delta$-type) configuration of chiral molecules was used for enantio-separation in many theoretical works. Considering the effect of molecular rotation, this simple single-loop configuration is generally…

量子物理 · 物理学 2018-12-12 Chong Ye , Quansheng Zhang , Yong Li

Controlling the internal quantum states of chiral molecules for a selected enantiomer has a wide range of fundamental applications. Using tailored microwave fields, a chosen rotational state can be enriched for a selected enantiomer, even…

We show that the position of the exceptional points (EPs) in the parameter space of a chiral molecule coupled to the photoionization continuum by a three-color field is enantiosensitive. Using a minimal model of a three-level system driven…

量子物理 · 物理学 2023-07-11 Nicola Mayer , Nimrod Moiseyev , Olga Smirnova

Distinguishing between enantiomers is crucial in the study of chiral molecules in chemistry and pharmacology. Many optical approaches rely on enantiospecific cyclic electric-dipole transitions induced by three microwave or laser beams.…

量子物理 · 物理学 2025-12-11 Fen Zou , Yong Li , Peng Zhang

We theoretically study the carrier-envelope phase dependent inversion generated in a two-level system by excitation with a few-cycle pulse. Based on the invariance of the inversion under time reversal of the exciting field, parameters are…

We report an analytic solution for a three-level atom driven by arbitrary time-dependent electromagnetic pulses. In particular, we consider far-detuned driving pulses and show an excellent match between our analytic result and the numerical…

量子物理 · 物理学 2018-12-14 Gavriil Shchedrin , Chris O'Brien , Yuri Rostovtsev , Marlan O. Scully
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