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The chiral state of a molecule plays a crucial role in molecular recognition and biochemical reactions. Because of this and owing to the fact that most modern drugs are chiral, the sensitive and reliable detection of the chirality of…

介观与纳米尺度物理 · 物理学 2019-04-30 Luisa M. Kneer , Eva-Maria Roller , Lucas V. Besteiro , Robert Schreiber , Alexander O. Govorov , Tim Liedl

Molecular chirality plays a crucial role in innumerable biological processes. The chirality of a molecule can typically be identified by its characteristic optical response, the circular dichroism (CD). CD signals have thus long been used…

Chirality is at the origin of life and is ubiquitous in nature. An object is deemed chiral if it is non-superimposable with its own mirror image. This relates to how circularly polarized light interacts with such object, a circular…

Chirality is an intriguing property of certain molecules, materials or artificial nanostructures, which allows them to interact with the spin angular momentum of the impinging light field. Due to their chiral geometry, they can distinguish…

光学 · 物理学 2016-11-03 Peter Banzer , Pawel Wozniak , Uwe Mick , Israel De Leon , Robert W. Boyd

Circular dichroism (CD), induced by chirality, is an important tool for manipulating light or for characterizing morphology of molecules, proteins, crystals and nano-structures. CD is manifested over a wide size-range, from molecules to…

Chirality, the property of asymmetry, is of great importance in biological and physical phenomena. This prospective offers an overview of the emerging field of chiral bioinspired plasmonics and metamaterials, aiming to uncover nature's…

Chirality is a fundamental asymmetry phenomenon, with chiral optical elements exhibiting asymmetric response in reflection or absorption of circularly polarized light. Recent realizations of such elements include nanoplasmonic systems with…

Chirality is a highly important topic in modern chemistry, given the dramatically different pharmacological effects that enantiomers can have on the body. Chirality of natural molecules can be controlled by reconfiguration of molecular…

光学 · 物理学 2018-03-21 Xiaoyang Duan , Simon Kamin , Florian Sterl , Harald Giessen , Na Liu

We present a comprehensive overview of chirality and its optical manifestation in plasmonic nanosystems and nanostructures. We discuss top-down fabricated structures that range from solid metallic nanostructures to groupings of metallic…

光学 · 物理学 2021-05-07 Mario Hentschel , Martin Schaeferling , Xiaoyang Duan , Harald Giessen , Na Liu

Molecular chirality plays an important role in chemistry and biology, allows control of biological interactions, affects drugs efficacy and safety, and promotes synthesis of new materials. In general, chirality manifests itself in optical…

光学 · 物理学 2026-04-10 Yuanyang Xie , Alexey V. Krasavin , Anatoly V. Zayats

In the close vicinity of a chiral nanostructure, the circular dichroism of a biomolecule could be greatly enhanced, due to the interaction with the local superchiral fields. Modest enhancement of optical activity using a planar…

In chemistry and biochemistry, chirality represents the structural asymmetry characterized by non-superimposable mirror images for a material like DNA. In physics, however, chirality commonly refers to the spin-momentum locking of a…

材料科学 · 物理学 2024-08-07 Binghai Yan

Chirality is a concept that one object is not superimposable on its mirror image by translation and rotation. In particular, chiral plasmonics have been widely investigated due to their excellent optical chiral properties, and have led to…

光学 · 物理学 2023-07-18 Yuqing Cheng , Mengtao Sun

The plasmonic chirality has drawn a lot of attention because of the tunable circular dichroism (CD) and the enhancement for the signal of chiral molecules. Different mechanisms have been proposed for explaining the plasmonic CD, however, a…

介观与纳米尺度物理 · 物理学 2016-03-23 Li Hu , Xiaorui Tian , Yingzhou Huang , Xinqiang Wang , Yurui Fang

Chirality refers to a geometric phenomenon in which objects are not superimposable on their mirror image. Structures made of nano-scale chiral elements can display chiroptical effects, such as dichroism for left- and right- handed…

光学 · 物理学 2020-02-25 Behrooz Semnani , Jeremy Flannery , Rubayet Al Maruf , Michal Bajcsy

Circular dichroism (CD) caused by the response of a chiral object to circularly polarized light has been well established, and the strong CD of plasmonic meta-molecules has also become of interest in recent years; however, their response if…

光学 · 物理学 2020-09-30 Yangzhe Guo , Guodong Zhu , Wanlu Bian , Bin Dong , Yurui Fang

Chirality is ubiquitous from microscopic to macroscopic phenomena in physics and biology, such as fermionic interactions and DNA duplication. In photonics, chirality has traditionally represented differentiated optical responses for right…

光学 · 物理学 2019-09-02 Sunkyu Yu , Xianji Piao , Namkyoo Park

Mirror symmetry is among the most fundamental concepts of physics and its spontaneous breaking at the molecular level allows chiral molecules to exist in two enantiomers that are mirror images of each other. The majority of chiro-optical…

光学 · 物理学 2021-09-29 Alessandro Ciattoni

Molecular chirality is a geometric property that is of great importance in chemistry, biology, and medicine. Recently, plasmonic nanostructures that exhibit distinct chiroptical responses have attracted tremendous interest, given their…

光学 · 物理学 2021-05-17 Frank Neubrech , Mario Hentschel , Na Liu

Dark-field illumination is shown to make planar chiral nanoparticle arrangements exhibit circular dichroism in extinction analogous to true chiral scatterers. Circular dichrosim is experimentally observed at the maximum scattering of single…

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