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The effects of water wetting conditions on the transport properties of molecular nano-junctions are investigated theoretically by using a combination of classical molecular dynamics and first principles electronic transport calculations.…

介观与纳米尺度物理 · 物理学 2015-05-18 I. Rungger , X. Chen , U. Schwingenschlögl , S. Sanvito

Water-flow in carbon nanotubes (CNT's) starkly contradicts classical fluid mechanics, with permeabilities that can exceed no-slip Haagen-Poiseuille predictions by two to five orders of magnitude. Semi-classical molecular dynamics accounts…

材料科学 · 物理学 2022-07-27 Alberto Ambrosetti , Giorgio Palermo , Pier Luigi Silvestrelli

Experiments and computer simulations demonstrate that water spontaneously fills the hydrophobic cavity of a carbon nanotube. To gain a quantitative thermody- namic understanding of this phenomenon, we use the recently developed Two Phase…

介观与纳米尺度物理 · 物理学 2011-08-22 Hemant Kumar , Biswaroop Mukherjee , Shiang-Tai Lin Chandan Dasgupta , A. K. Sood , Prabal K. Maiti

Narrow carbon nanotubes (CNTs) desalinate water, mimicking water channels of biological membranes, yet the physics behind selectivity, especially, the effect of the membrane embedding CNTs on water and ion transfer, is still unclear. Here,…

材料科学 · 物理学 2020-12-22 Vadim Neklyudov , Viatcheslav Freger

The self-assembly mechanism of one-end-open carbon nanotubes (CNTs) suspended in an aqueous solution was studied by molecular dynamics simulations. It was shown that two one-end-open CNTs with different diameters can coaxially self-assemble…

介观与纳米尺度物理 · 物理学 2017-07-31 Hang Xiao , Xiaoyang Shi , Xi Chen

Using molecular dynamics simulations, we investigate systematically the water permeation properties across the single-walled carbon nanotube (SWCNT) in the presence of the terahertz electric field (TEF). With the TEF normal to the nanotube,…

介观与纳米尺度物理 · 物理学 2016-02-17 Qi-Lin Zhang , Rong-Yao Yang , Wei-Zhou Jiang , Zi-Qian Huang

In this work the conduction of ion-water solution through two discrete bundles of armchair carbon and silicon carbide nanotubes, as useful membranes for water desalination, is studied. In order that studies on different types of nanotubes…

原子与分子团簇 · 物理学 2017-08-17 Mara Cantoni , Edovardo Imalini

We have used atomistic molecular dynamics (MD) simulations to study the structure and dynamics of water molecules inside an open ended carbon nanotube placed in a bath of water molecules. The size of the nanotube allows only a single file…

统计力学 · 物理学 2007-12-20 Biswaroop Mukherjee , Prabal K. Maiti , Chandan Dasgupta , A. K. Sood

The equilibrium density of fluids under nanoconfinement can differ substantially from their bulk density. Using a mean-field approach to describe the energetic landscape near the carbon nanotube (CNT) wall, we obtain analytical results…

流体动力学 · 物理学 2015-06-11 Gerald J. Wang , Nicolas G. Hadjiconstantinou

Efficient water transport through nanostructure membranes is essential for advancing filtration and desalination technologies. In this study, we investigate the flow of water through molybdenum disulfide (MoS$_{2}$) nanopores of varying…

Water molecules, confined in a carbon nanotube, were monitored using molecular dynamics simulation. Spontaneous directional transportation during a long timescale was observed in the symmetrical nanochannel by a ratchet-like mechanism. This…

生物物理 · 物理学 2008-03-21 Rongzheng Wan , Hangjun Lu , Jinyuan Li , Jingdong Bao , Jun Hu , Haiping Fang

Water confinement inside a carbon nanotube (CNT) has been one of the most exciting subjects of both experimental and theoretical interest. Most of the previous studies, however, considered CNT structures with simple cylindrical shapes. In…

介观与纳米尺度物理 · 物理学 2020-02-03 Taehoon Kim , Gwan Woo Kim , Hyunah Jeong , Gunn Kim , Soonmin Jang

In this study, using non-equilibrium molecular dynamics simulation, the flow of water in deformed carbon nanotubes is studied for two water models TIP4P/2005 and SPC/FH. The results demonstrated a non-uniform dependence of the flow on the…

The orientation of water molecules is the key factor for the fast transport of water in small nanotubes. It has been accepted that the bidirectional water burst in short nanotubes can be transformed into unidirectional transport when the…

计算物理 · 物理学 2020-08-13 Le Jin , Depeng Zhang , Yu Zhu , Xinrui Yang , Yi Gao , Zhigang Wang

We show using molecular dynamics simulation that spatial confinement of water inside carbon nanotubes (CNT) substantially increases its boiling temperature and that a small temperature growth above the boiling point dramatically raises the…

材料科学 · 物理学 2012-02-08 Vitaly V. Chaban , Oleg V. Prezhdo

Using Molecular Dynamics approach we investigated the structure, dynamics of water confined inside pristine and charged 6,6 carbon nanotubes (CNTs). This study reports the breakdown of 1D water wires and the emergence of triangular faced…

软凝聚态物质 · 物理学 2016-11-23 Shashank Pant

The aim of the paper is the study of fluid mixtures in nanotubes by the methods of continuum mechanics. The model starts from a statistical distribution in mean-field molecular theory and uses a density expansion of Taylor series. We get a…

流体动力学 · 物理学 2018-08-01 Henri Gouin , Augusto Muracchini , Tommaso Ruggeri

We use DFT to study the effect of molecular adsorbates on the conductance of metallic carbon nanotubes. The five molecules considered (NO2, NH2, H, COOH, OH) lead to similar scattering of the electrons. The adsorption of a single molecule…

介观与纳米尺度物理 · 物理学 2008-10-02 Juan Maria Garcia-Lastra , Kristian S. Thygesen , Mikkel Strange , Angel Rubio

The one-dimensional confinement of quasiparticles in individual carbon nanotubes (CNTs) leads to extremely anisotropic electronic and optical properties. In a macroscopic ensemble of randomly oriented CNTs, this anisotropy disappears…

A simple model for the friction experienced by the one dimensional water chains that flow through subnanometer diameter carbon nanotubes is studied. The model is based on a lowest order perturbation theory treatment of the friction…

流体动力学 · 物理学 2023-05-17 J. B. Sokoloff , A. W. C. Lau
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