相关论文: Abiotic molecular oxygen production -- ionic pathw…
Competing geophysical/geochemical hypotheses for how Earth's surface became oxygenated - organic carbon burial, hydrogen escape to space, and changes in the redox state of volcanic gases - are examined and a more biologically-based…
Ozone is a potential biosignature and disambuguator between Earth-like and Venus-like exoplanets due to its association on Earth with photosynthetically produced oxygen (O$_2$). However, the existence of ozone in Venus's observable…
Rocky planets may acquire a primordial atmosphere by outgassing of volatiles from their magma ocean. The distribution of O between H$_2$O, CO and CO$_2$ in chemical equilibrium subsequently changes significantly with decreasing temperature.…
Oxygen is a promising exoplanet biosignature due to the evolutionary advantage conferred by harnessing starlight for photosynthesis, and the apparent low likelihood of maintaining oxygen-rich atmospheres without life. Hypothetical scenarios…
Earth is expected to have acquired a reduced proto-atmosphere enriched in H2 and CH4 through the accretion of building blocks that contain metallic Fe and/or the gravitational trapping of surrounding nebula gas. Such an early, wet, reduced…
Planet Earth has evolved from an entirely anoxic planet with possibly a different tectonic regime to the oxygenated world with horizontal plate tectonics that we know today. For most of this time, Earth has been inhabited by a purely…
We report a combined experimental and theoretical study on the formation of O2+ by electronimpact double ionization and fragmentation of carbon dioxide (CO2) molecule. Through fragment ions and electron coincidence momentum imaging, we…
Since the Archean, N2 has been a major atmospheric constituent in Earth's atmosphere. Nitrogen is an essential element in the building blocks of life, therefore the geobiological nitrogen cycle is a fundamental factor in the long term…
This work presents theoretical studies which combine aspects of combustion and explosion theory with exoplanetary atmospheric science. Super Earths could possess a large amount of molecular hydrogen depending on disk, planetary and stellar…
In the modern search for life elsewhere in the Universe, we are broadly looking for the following: the planets similar to Earth - physical indicators of habitability, and the manifestation of life - the biological signatures. A biosignature…
Efforts to spectrally characterize the atmospheric compositions of temperate terrestrial exoplanets orbiting M-dwarf stars with the James Webb Space Telescope (JWST) are now underway. Key molecular targets of such searches include O$_2$ and…
We present a study of the photochemistry of abiotic habitable planets with anoxic CO$_2$-N$_2$ atmospheres. Such worlds are representative of early Earth, Mars and Venus, and analogous exoplanets. H$_2$O photodissociation controls the…
In the search for life in the Universe, molecular oxygen (O$_2$) combined with a reducing species, such as methane (CH$_4$), is considered a promising disequilibrium biosignature. In cases where it would be difficult or impossible to detect…
After Earth's origin, our host star, the Sun, was shining 20 to 25 percent less brightly than today. Without greenhouse-like conditions to warm the atmosphere, our early planet would have been an ice ball and life may never have evolved.…
Ocean planets are volatile rich planets, not present in our Solar System, which are thought to be dominated by deep, global oceans. This results in the formation of high-pressure water ice, separating the planetary crust from the liquid…
Multiphase oxidation of sulfur dioxide (SO2) is an important source of sulfate in the atmosphere. There are, however, concerns that protons produced during SO2 oxidation may cause rapid acidification of aerosol water and thereby quickly…
Organic haze plays a key role in many planetary processes ranging from influencing the radiation budget of an atmosphere to serving as a source of prebiotic molecules on the surface. Numerous experiments have investigated the aerosols…
Earth's volatile elements (H, C, and N) are essential to maintaining habitable conditions for metazoans and simpler life forms. However, identifying the sources (comets, meteorites, and trapped nebular gas) that supplied volatiles to Earth…
Characterizing the bulk atmosphere of a terrestrial planet is important for determining surface pressure and potential habitability. Molecular nitrogen (N$_2$) constitutes the largest fraction of Earth$'$s atmosphere and is likely to be a…
Water is abundantly present in the Universe. It is the main component of interstellar ice mantles and a key ingredient for life. Water in space is mainly formed through surface reactions. Three formation routes have been proposed in the…