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Optical chirality plays an essential role in chiral light-matter interactions with broad applications in sensing and spectroscopy. Conventional methods of generating optical chirality usually employ chiral structures or chiral excitations.…

光学 · 物理学 2023-06-21 Shiqi Jia , Tong Fu , Jie Peng , Shubo Wang

Enantioselective interactions of chiral molecules include distinct absorptions to opposite-handed circularly polarized light, known as chiral absorption. Traditionally, chiral absorption has been primarily attributed to electric dipole and…

光学 · 物理学 2024-06-03 Hanwei Wang , Yang Zhao

A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal…

化学物理 · 物理学 2017-05-04 Andrey Yachmenev , Sergei N. Yurchenko

A recently proposed theory of chiral discrimination in NMR spectroscopy based on the detection of a molecular electric polarization $\mathbf{P}$ rotating in a plane perpendicular to the NMR magnetic field [A. D. Buckingham, J. Chem. Phys.…

化学物理 · 物理学 2016-04-26 Alessandro Soncini , Simone Calvello

Chiral spectroscopy is a powerful technique that enables to identify the chirality of matter through optical means. So far, experiments to check the chirality of matter or nanostructures have been carried out using free-space propagating…

光学 · 物理学 2019-11-26 J. Enrique Vázquez-Lozano , Alejandro Martínez

Strong light-matter coupling in chiral cavities has been proposed as an effective way to selectively interact with an enantiomer that shares the same handedness as the cavity's chiral mode. We show that surface plasmons supported by a…

It has been long recognized that the spatial polarization of the electronic clouds in molecules, and the spatial arrangements of atoms into chiral molecular structures, play crucial roles in physics, chemistry and biology. However, these…

光学 · 物理学 2020-04-14 David Ayuso , Andres Ordonez , Piero Decleva , Misha Ivanov , Olga Smirnova

The on-chip measurement of polarization states plays an increasingly crucial role in modern sensing and imaging applications. While high-performance monolithic linearly polarized photodetectors have been extensively studied, integrated…

We present a scheme to realize precise discrimination of chiral molecules in a cavity. Assisted by additional laser pulses, cavity fields can evolve to different coherence states with contrary-sign displacements according to the handedness…

量子物理 · 物理学 2023-07-19 Yi-Hao Kang , Zhi-Cheng Shi , Jie Song , Yan Xia

Designing objects with predefined optical properties is a task of fundamental importance for nanophotonics, and chirality is a prototypical example of such a property, with applications ranging from photochemistry to nonlinear photonics. A…

Accurate characterization of polarization dependent light matter interactions in nanostructured systems is paramount for the development of chiral metasurfaces. It is also often challenging, because multiple anisotropic mechanisms, such as…

光学 · 物理学 2026-04-27 Jeeban Kumar Nayak , Ebru Buhara , Olivier J. F. Martin

Chirality is an intriguing property of certain molecules, materials or artificial nanostructures, which allows them to interact with the spin angular momentum of the impinging light field. Due to their chiral geometry, they can distinguish…

光学 · 物理学 2016-11-03 Peter Banzer , Pawel Wozniak , Uwe Mick , Israel De Leon , Robert W. Boyd

Chiroptical techniques for detecting and characterizing the chirality of matter and artificial nanostructures are traditionally based on their interaction with chiral light, typically circularly-polarized fields propagating in free space.…

Light scattering from chiral plasmonic structures can create near fields with an asymmetry greater than the equivalent circularly polarised light, a property sometimes referred to as superchirality. These near fields with enhanced chiral…

We demonstrate that electric-dipole scatterers can mimic chiral light-matter interaction by generating far-field circular polarization upon scattering, even though the optical chirality of the incident field as well as that of the scattered…

光学 · 物理学 2019-06-12 Sergey Nechayev , Peter Banzer

Strong enhancement of molecular circular dichroism has the potential to enable efficient asymmetric photolysis, a method of chiral separation that has conventionally been impeded by insufficient yield and low enantiomeric excess. Here, we…

Recently, there is growing interest in integrating alkali vapors with nanoscale photonic structures, such as nano-waveguides, resonators and nanoantennas. Nanoscale confinement of electromagnetic fields may introduce a longitudinal electric…

光学 · 物理学 2021-02-10 Roy Zektzer , Eliran Talker , Yefim Barash , Noa Mazurski , Uriel Levy

Mirror symmetry is among the most fundamental concepts of physics and its spontaneous breaking at the molecular level allows chiral molecules to exist in two enantiomers that are mirror images of each other. The majority of chiro-optical…

光学 · 物理学 2021-09-29 Alessandro Ciattoni

Circular dichroism spectroscopy is an essential technique for understanding molecular structure and magnetic materials, but spatial resolution is limited by the wavelength of light, and sensitivity sufficient for single-molecule…

Prospects of using metal hole arrays for the enhanced optical detection of molecular chirality in nanosize volumes are investigated. Light transmission through the holes filled with an optically active material is modeled and the activity…

光学 · 物理学 2017-01-17 Maxim V. Gorkunov , Alexander N. Darinskii , Alexey V. Kondratov
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