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Physical vapor deposition (PVD) is widely used in manufacturing ultra-thin layers of amorphous organic solids. Here, we demonstrate that these films exhibit a sharp transition from glassy solid to liquid-like behavior with thickness below…

软凝聚态物质 · 物理学 2016-10-12 Yue Zhang , Ethan Glor , Mu Li , Tianyi Liu , kareem Wahid , William Zhang , Robert Riggleman , Zahra Fakhraai

The EUV photoionizing radiation and FUV dissociating radiation from newly born stars photoevaporate their parental neutral cloud, leading to the formation of dense clumps that could eventually form additional stars. We study the effects of…

太阳与恒星天体物理 · 物理学 2013-06-24 V. Lora , M. J. Vasconcelos , A. C. Raga , A. Esquivel , A. H. Cerqueira

We report the first detection of the ground transition of the deuterated water at 464 GHz in the young proto-planetary disk surrounding the solar type protostar DM Tau. The line is observed in absorption against the continuum from the cold…

天体物理学 · 物理学 2009-11-13 C. Ceccarelli , C. Dominik , E. Caux , B. Lefloch , P. Caselli

The dust in nearby galaxies absorbs a fraction of the UV-optical-near-infrared radiation produced by stars. This energy is consequently re-emitted in the infrared. We investigate the portion of the stellar radiation absorbed by spiral…

Experimental and theoretical infrared spectra, between 4000-500 cm$^{-1}$ (2.5-20 microns), and infrared band strengths of two solid phases of indene, amorphous and crystalline, are given for the first time. The samples were generated via…

天体物理仪器与方法 · 物理学 2023-07-06 Belén Maté , Isabel Tanarro , Vicente Timón , José Cernicharo , Victor J. Herrero

(Abridged) Gas-phase complex organic molecules are commonly detected in the warm inner regions of protostellar envelopes. Recent models show that photochemistry in ices followed by desorption may explain the observed abundances. This study…

星系天体物理 · 物理学 2015-05-13 K. I. Oberg , R. T. Garrod , E. F. van Dishoeck , H. Linnartz

Time resolved transient absorption spectroscopy has been used to determine quantum yields for electron photodetachment in 193 nm and (where possible) 248 nm laser excitation of miscellaneous aqueous anions, including hexacyanoferrate(II),…

化学物理 · 物理学 2016-09-28 Myran C. Sauer , R. A. Crowell , Ilya A. Shkrob

The main goal of this work is to compare the effects induced in ices of astrophysical relevance by high-energy ions, simulating cosmic rays, and by vacuum ultraviolet (UV) photons. This comparison relies on in situ infrared spectroscopy of…

太阳与恒星天体物理 · 物理学 2019-08-13 G. M. Munoz Caro , E. Dartois , P. Boduch , H. Rothard , A. Domaracka , A. Jimenez-Escobar

We describe the phase diagram of amorphous solid water by performing molecular dynamics simulations. Our simulations follow different paths in the phase diagram: isothermal compression/decompression, isochoric cooling/heating and isobaric…

软凝聚态物质 · 物理学 2009-11-11 Nicolas Giovambattista , H. Eugene Stanley , Francesco Sciortino

We propose a new simple computational model to estimate adsorption energies of atoms and molecules to low-temperature amorphous water ice, and we present the adsorption energies of carbon (3P), nitrogen (4S), and oxygen (3P) atoms based on…

星系天体物理 · 物理学 2018-03-14 Takashi Shimonishi , Naoki Nakatani , Kenji Furuya , Tetsuya Hama

Nonthermal desorption of molecules from icy grain surfaces is required to explain molecular line observations in the cold gas of star-forming regions. Chemical desorption is one of the nonthermal desorption processes and is driven by the…

星系天体物理 · 物理学 2022-03-02 Kenji Furuya , Yasuhiro Oba , Takashi Shimonishi

Spectra obtained with the Hubble Space Telescope GHRS are combined with high-resolution optical spectra and UV spectra from Copernicus to study the abundances and physical conditions in the diffuse interstellar clouds seen along the line of…

天体物理学 · 物理学 2008-11-26 D. E. Welty , L. M. Hobbs , J. T. Lauroesch , D. C. Morton , L. Spitzer , D. G. York

Volatile organic molecules formed by photochemistry in the upper atmosphere of Titan can undergo condensation as pure ices in the stratosphere and the troposphere as well as condense as ice layers onto the organic aerosols that are visible…

地球与行星天体物理 · 物理学 2019-04-02 Benjamin Fleury , Murthy S. Gudipati , Isabelle Couturier-Tamburelli , Nathalie Carrasco

This paper describes the accuracy and the errors of water vapour content measurements in the atmosphere using optical methods, especially starphotometer. After the general explanations of the used expressions for the star-magnitude…

大气与海洋物理 · 物理学 2010-10-19 V. D. Galkin , U. Leiterer , G. A. Alekseeva , V. V. Novikov , V. P. Pakhomov

Although water is almost transparent to visible light, we demonstrate that the air-water interface interacts strongly with visible light via what we hypothesize as the photomolecular effect. In this effect, transverse-magnetic polarized…

光学 · 物理学 2023-11-01 Guangxin Lv , Yaodong Tu , James H. Zhang , Gang Chen

Close-in hot Jupiters are exposed to a tremendous photon flux that ionizes the neutral escaping material from the planet leaving an observable imprint that makes them an interesting laboratory for testing theoretical models. In this work we…

地球与行星天体物理 · 物理学 2016-02-17 E. M. Schneiter , A. Esquivel , C. S. Villarreal D'Angelo , P. F. Velazquez , A. C. Raga , A. Costa

Mid-infrared spectroscopy is one of the few ways to observe the composition of the terrestial planet forming zone, the inner few au, of proto-planetary disks. The species currently detected in the disk atmosphere, for example CO, CO2, H2O…

地球与行星天体物理 · 物理学 2022-05-25 Arthur D. Bosman , Edwin A. Bergin , Jenny Calahan , Sara E. Duval

We present a computational study into the adsorption properties of CO$_2$ on amorphous and crystalline water surfaces under astrophysically relevant conditions. Water and carbon dioxide are two of the most dominant species in the icy…

星系天体物理 · 物理学 2017-09-13 L. J. Karssemeijer , G. A. de Wijs , H. M. Cuppen

We obtained laboratory spectra of absorption by water vapor at the wavelengths 6500-10500 {\AA} with the multipass cell. The water vapor content along the line of view varied from 0.1 to 3.0 cm of precipitated water, the pressure from 0.1…

天体物理仪器与方法 · 物理学 2010-10-26 G. A. Alekseeva , V. D. Galkin , I. B. Sal'nikov

Context. Interstellar surface chemistry is a complex process that occurs in icy layers accumulated onto grains of different sizes. Efficiency of surface processes often depends on the immediate environment of adsorbed molecules. Aims. We…

星系天体物理 · 物理学 2024-07-31 Juris Kalvāns , Aija Kalniņa , Kristaps Veitners