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Using polarization-resolved Raman spectroscopy, we investigate layer number, temperature, and magnetic field dependence of Raman spectra in one- to four-layer $\mathrm{CrI_{3}}$. Layer-number-dependent Raman spectra show that in the…

We report the connection between the stacking order and magnetic properties of bilayer CrI$_3$ using first-principles calculations. We show that the stacking order defines the magnetic ground state. By changing the interlayer stacking order…

材料科学 · 物理学 2018-11-19 Nikhil Sivadas , Satoshi Okamoto , Xiaodong Xu , Craig. J. Fennie , Di Xiao

The discovery of spontaneous magnetism in van der Waal (vdW) magnetic monolayers has opened up an unprecedented platform for investigating magnetism in purely two-dimensional systems. Recently, it has been shown that the magnetic properties…

介观与纳米尺度物理 · 物理学 2022-01-19 Eliot Heinrich , Xin Li , Benedetta Flebus

Two-dimensional (2D) magnetic materials are promising candidates for spintronics and quantum technologies. One extensively studied example is the ferromagnetic (FM) CrI$_3$ monolayer with the honeycomb Cr$^{3+}$ ($t_{2g}^3$, $S$ = 3/2) spin…

材料科学 · 物理学 2025-04-17 Ke Yang , Yueyue Ning , Yaozhenghang Ma , Yuxuan Zhou , Hua Wu

We report on a combined experimental and theoretical study on CrI3 single crystals by employing the polarization dependence of resonant inelastic X-ray scattering (RIXS). Our investigations reveal multiple Cr 3d orbital splitting (dd…

Diverse interlayer tunability of physical properties of two-dimensional layers mostly lies in the covalent-like quasi-bonding that is significant in electronic structures but rather weak for energetics. Such characteristics result in…

材料科学 · 物理学 2019-04-03 Peiheng Jiang , Cong Wang , Dachuan Chen , Zhicheng Zhong , Zhe Yuan , Zhong-Yi Lu , Wei Ji

Ultrathin films of the itinerant ferromagnet SrRuO$_3$ were studied using transport and magnto-optic polar Kerr effect. We find that below 4 monolayers the films become insulating and their magnetic character changes as they loose their…

强关联电子 · 物理学 2015-05-13 Jing Xia , W. Siemons , G. Koster , M. R. Beasley , A. Kapitulnik

Spin-orbit coupling (SOC) gives rise to complex magnetic states such as spin liquids, skyrmion crystals, and topological spin-wave excitations. We consider exchange interactions in multi-orbital Mott insulators where SOC is strong on ligand…

强关联电子 · 物理学 2026-03-23 Evgenii Barts , Paolo Barone , Maxim Mostovoy

Understanding magnetoelectric coupling in emerging van der Waals multiferroics is crucial for developing atomically thin spintronic devices. Here, we present a comprehensive first-principles investigation of magnetoelectric coupling in…

材料科学 · 物理学 2026-03-06 Hui-Shi Yu , Xiao-Sheng Ni , Kun Cao

We report intrinsic ferromagnetism in monolayer electrides or electrenes, in which excess electrons act as anions. Our first-principles calculations demonstrate that magnetism in such electron-rich two-dimensional (2D) materials originates…

计算物理 · 物理学 2020-11-25 Jun Zhou , Yuan Ping Feng , Lei Shen

First-principles calculations, in combination with the four-state energy mapping method, are performed to extract the magnetic interaction parameters of multiferroic BiFeO$_3$. Such parameters include the symmetric exchange (SE) couplings…

材料科学 · 物理学 2019-03-20 Changsong Xu , Bin Xu , Bertrand Dupé , L. Bellaiche

We investigate the magnetocrystalline anisotropy, critical behavior, and magnetocaloric effect in ferromagnetic-layered Cr$_2$Te$_3$. We have studied the critical behavior around the Curie temperature ($T_C$) using various techniques,…

材料科学 · 物理学 2024-07-26 Shubham Purwar , Tushar Kanti Bhowmik , Soumya Ghorai , Setti Thirupathaiah

Control of magnetism by an applied electric field is a desirable technique for the functionalization of magnetic materials. Motivated by recent experiments, we study the electric field control of the interfacial magnetism of…

材料科学 · 物理学 2023-08-21 Churna Bhandari , S Satpathy

When combined with transition metals with partially filled $d$-orbitals, magnetism can be incorporated in two-dimensional materials, which greatly expands the scope for fundamental researches and potential applications of these materials.…

材料科学 · 物理学 2019-12-24 Ming An , Yang Zhang , Jun Chen , Hui-Min Zhang , Yunjun Guo , Shuai Dong

The extraordinary properties of a heterostructure by stacking atom-thick van der Waals (vdW) magnets have been extensively studied. However, the magnetocaloric effect (MCE) of heterostructures that are based on monolayer magnets remains to…

材料科学 · 物理学 2023-04-26 Weiwei He , Ziming Tang , Qihua Gong , Min Yi , Wanlin Guo

The development of room-temperature magnetic semiconductors is critical for advancing spintronic technologies, yet van der Waals magnets like CrI3 exhibit intrinsically low Curie temperatures (Tc = 45 K). This study employs first-principles…

材料科学 · 物理学 2025-08-12 Qing-Han Yang , Jia-Wen Li , Xin-Wei Yi , Xiang Li , Jing-Yang You , Gang Su , Bo Gu

While tremendous success has been achieved to date in creating both single phase and composite magnetoelectric materials, the quintessential electric-field control of magnetism remains elusive. In this work, we demonstrate a linear…

材料科学 · 物理学 2011-11-10 J. M. Rondinelli , M. Stengel , N. A. Spaldin

Two-dimensional (2D) materials can host stable, long-range magnetic phases in the presence of underlying magnetic anisotropy. The ability to realize the full potential of 2D magnets necessitates systematic investigation of the role of…

The linear magnetoelectric effect was measured in 500 nm Cr2O3 films grown by rf sputtering on Al2O3 substrates between top and bottom thin film Pt electrodes. Magnetoelectric susceptibility was measured directly by applying an AC electric…

材料科学 · 物理学 2016-05-25 P. Borisov , T. Ashida , T. Nozaki , M. Sahashi , D. Lederman

The monolayer halides CrX$_3$ (X=Cl, Br, I) attract significant attention for realizing 2D magnets with genuine long-range order (LRO), challenging the Mermin-Wagner theorem. Here, we show that monolayer CrCl$_3$ has the unique benefit of…