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Lithium metal cells are key towards achieving high specific energy and energy density for electrification of transportation and aviation. Anode-free cells are the limiting case of lithium metal cells involving no excess lithium and the…

材料科学 · 物理学 2019-12-04 Vikram Pande , Venkatasubramanian Viswanathan

"Anode-free" lithium-metal batteries promise significantly higher energy density than conventional graphite-based lithium-ion batteries; however, lithium dendrite growth can lead to internal short circuits with associated safety risks.…

The properties of rechargeable lithium-ion batteries are determined by the electrochemical and kinetic properties of their constituent materials as well as by their underlying microstructure. Microstructural design can be leveraged to…

材料科学 · 物理学 2022-03-11 Giovanna Bucci , Tushar Swamy , W. Craig Carter , Morad Behandish

The ever-increasing number of spent lithium-ion batteries (LIBs) has presented a serious waste-management challenge. Aluminium and copper current collectors are important components in LIBs and take up a weight percentage of more than 15%.…

The structure of lithium ion battery components, such as electrodes and separators, are commonly characterised in terms of their porosity and tortuosity. The ratio of these values gives the effective transport of lithium ions in the…

应用物理 · 物理学 2018-06-04 Marie Francine Lagadec , Raphael Zahn , Simon Müller , Vanessa Wood

A three-dimensional model of a single-layer lithium-ion pouch cell is presented which couples conventional porous electrode theory describing cell electrochemical behaviour with an energy balance describing cell thermal behaviour.…

应用物理 · 物理学 2020-05-12 Robert Timms , Scott G. Marquis , Valentin Sulzer , Colin Please , S. Jon Chapman

Silicon anodes offer high energy densities for next-generation lithium-ion batteries; however, their application is limited by severe volume expansion during cycling. Making silicon porous or nanostructured mitigates this expansion but…

The basic principle for achieving high-power capability on an electrochemical energy storage cell is minimizing the overall resistance. The resistance due to current collecting systems has not received sufficient attention in the past,…

应用物理 · 物理学 2025-01-16 Jose Miguel Campillo-Robles , Xabier Artetxe , Karmele del Teso Sánchez

A stochastic 3D modeling approach for the nanoporous binder-conductive additive phase in hierarchically structured cathodes of lithium-ion batteries is presented. The binder-conductive additive phase of these electrodes consists of carbon…

Employing two-dimensional (2D) materials as anodes for lithium-ion batteries (LIBs) is believed to be an effective approach to meet the growing demands of high-capacity next-generation LIBs. In this work, the first-principles density…

应用物理 · 物理学 2020-07-31 Ke Fan , Yiran Ying , Xin Luo , Haitao Huang

The porosities and tortuosities are commonly utilized to characterize the microstructure of a Li-ion battery's separator and are adopted as key input parameters in advanced battery models. Herein, a general classification of the tortuosity…

应用物理 · 物理学 2024-07-30 Wei Sun , Q. M. Li , Ping Xiao , Paola Carbone

Two-dimensional (2D) materials have received considerable attention as possible electrodes in Li-ion batteries (LIBs), although a deeper understanding of the Li adsorption behavior as well as broad screening of the materials space is still…

材料科学 · 物理学 2022-03-22 Sheng Gong , Shuo Wang , Taishan Zhu , Xi Chen , Jeffrey C. Grossman

In this paper, we introduce a density-based topology optimization framework to design porous electrodes for maximum energy storage. We simulate the full cell with a model that incorporates electronic potential, ionic potential, and…

A flexible, light weight and high conductivity current collector is the key element that enables fabrication of high performance flexible lithium ion battery. Here we report a thin, light weight and flexible lithium ion battery that uses…

化学物理 · 物理学 2015-11-13 Hang Qu , Jingshan Hou , Yufeng Tang , Oleg Semenikihin , Maksim Skorobogatiy

Distributions of potential and lithium content inside lithium ion batteries highly affects their performance and durability. An increased heterogeneity of the lithium distribution is expected in thick electrodes with high energy densities…

Liquid metal batteries are possible candidates for large scale energy storage offering a possible breakthrough of intermittent wind and solar energy exploitations. The major concern over their practical implementation is the operation at…

应用物理 · 物理学 2018-02-20 V. Bojarevics , A. Tucs

Higher energy density and longer lifetime are the requirements for next-generation lithium-ion batteries. A promising anode material is silicon, which offers high specific capacity, but its significant volume change during lithiation and…

This article reviews the development of cathode materials for secondary lithium ion batteries since its inception with the introduction of lithium cobalt oxide in early 1980s. The time has passed and numerous cathode materials are designed…

材料科学 · 物理学 2021-09-07 Ambesh Dixit

The lithium (Li) metal anode is essential for next generation high energy density rechargeable Li metal batteries. Although extensive studies have been performed to prolong the cycle life of Li metal batteries, the calendar life, which…

It is well-known that the microstructure of electrodes in lithium-ion batteries strongly affects their performance. Vice versa, the microstructure can exhibit strong changes during the usage of the battery due to aging effects. For a better…

材料科学 · 物理学 2018-01-15 Klaus Kuchler , Daniel Westhoff , Julian Feinauer , Tim Mitsch , Ingo Manke , Volker Schmidt
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