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FeSe-derived superconductors show some unique behaviors relative to iron-pnictide superconductors, which are very helpful to understand the mechanism of superconductivity in high-Tc iron-based superconductors. The low-energy electronic…

超导电性 · 物理学 2014-12-17 X. F. Lu , N. Z. Wang , H. Wu , Y. P. Wu , D. Zhao , X. Z. Zeng , X. G. Luo , T. Wu , W. Bao , G. H. Zhang , F. Q. Huang , Q. Z. Huang , X. H. Chen

We report the superconductivity at above 30 K in a new FeSe-layer compound K0.8Fe2Se2 (nominal composition) achieved by metal K intercalating in between FeSe layers. It is isostructural to BaFe2As2 and possesses the highest Tc for…

超导电性 · 物理学 2019-06-12 Jiangang Guo , Shifeng Jin , Gang Wang , Shunchong Wang , Kaixing Zhu , Tingting Zhou , Meng He , Xiaolong Chen

The FeSe superconductor and its related systems have attracted much attention in the iron-based superconductors owing to their simple crystal structure and peculiar electronic and physical properties. The bulk FeSe superconductor has a…

超导电性 · 物理学 2015-06-24 Xu Liu , Lin Zhao , Shaolong He , Junfeng He , Defa Liu , Daixiang Mou , Bing Shen , Yong Hu , Jianwei Huang , X. J. Zhou

The recent discovery of high temperature superconductivity in a layered iron arsenide has led to an intensive search to optimize the superconducting properties of iron-based superconductors by changing the chemical composition of the spacer…

New iron selenide superconductors by intercalating smaller-sized alkali metals (Li, Na) and alkaline earths using high-temperature routes have been pursued ever since the discovery of superconductivity at about 30 K in KFe2Se2, but all have…

超导电性 · 物理学 2012-05-30 T. P. Ying , X. L. Chen , G. Wang , S. F. Jin , T. T. Zhou , X. F. Lai , H. Zhang , W. Y. Wang

A series of (Li$_{0.8}$Fe$_{0.2}$)OHFeSe$_{1-x}$S$_x$ (0 $\leq$ x $\leq$ 1) samples were successfully synthesized via hydrothermal reaction method and the phase diagram is established. Magnetic susceptibility suggests that an…

超导电性 · 物理学 2015-01-07 X. F. Lu , N. Z. Wang , X. G. Luo , G. H. Zhang , X. L. Gong , F. Q. Huang , X. H. Chen

Using angle-resolved photoemission spectroscopy (ARPES), we revealed the surface electronic structure and superconducting gap of (Li$_{0.8}$Fe$_{0.2}$)OHFeSe, an intercalated FeSe-derived superconductor without antiferromagnetic phase or…

Superconductivity with transition temperature Tc above 40 K was observed in protonated FeSe (Hy-FeSe) previously with the ionic liquid of EMIM-BF4 used in the electrochemical process. However, the real superconducting phase is not clear…

超导电性 · 物理学 2021-11-23 Jinhua Wang , Qing Li , Wei Xie , Guanyu Chen , Xiyu Zhu , Hai-Hu Wen

The recently discovered (Li$_{0.8}$Fe$_{0.2}$)OHFeSe superconductor provides a new platform for exploiting the microscopic mechanisms of high-$T_c$ superconductivity in FeSe-derived systems. Using density functional theory calculations, we…

超导电性 · 物理学 2016-02-26 Wei Chen , Changgan Zeng , Efthimios Kaxiras , Zhenyu Zhang

Superconductivity has been found in the iron-arsenides with different structures by alternative stacking of the conducting Fe2As2 layers and spacer layers including alkali- or alkali-earth metal ions and PbO- or perovskite-type oxides…

超导电性 · 物理学 2015-06-17 X. F. Lu , N. Z. Wang , G. H. Zhang , X. G. Luo , Z. M. Ma , B. Lei , F. Q. Huang , X. H. Chen

There is an ongoing debate about the relative importance of structural change versus doping charge carriers on the mechanism of superconductivity in Fe-based materials. Elucidating this issue is a major challenge since it would require a…

Binary stoichiometry FeSe (s-FeSe) is a well-known parent of high-temperature unconventional superconductors owing to its charge-neutral layer, highly tunable structure and electronic properties, and rich interplays among multiple…

As the simplest iron-based superconductor, FeSe forms a tetragonal structure with transition temperature Tc ~ 8 K. With assistance of pressure, or other techniques, Tc can be greatly enhanced, even to above liquid nitrogen temperature. The…

超导电性 · 物理学 2017-10-16 J. Zhang , F. L. Liu , T. P. Ying , N. N. Li , Y. Xu , L. P. He , X. C. Hong , Y. J. Yu , M. X. Wang , J. Shen , W. G. Yang , S. Y. Li

The recent discovery of superconductivity with relatively high transition temperature Tc in the layered iron-based quaternary oxypnictides La[ O1-xFx] FeAs was a real surprise. The excitement generated can be seen by the number of…

Following a recent proposal by Burrard-Lucas et al. [unpublished, arXiv: 1203.5046] we intercalated FeSe by Li in liquid ammonia. We report on the synthesis of new LixFe2Se2(NH3)y phases as well as on their magnetic and superconducting…

超导电性 · 物理学 2012-09-28 E. -W. Scheidt , V. R. Hathwar , D. Schmitz , A. Dunbar , W. Scherer , V. Tsurkan , J. Deisenhofer , A. Loidl

We have successfully synthesized FeSe films by the electrochemical deposition in the electrolyte containing FeCl_{2}\cdot4H_{2}O, SeO_{2} and Na_{2}SO_{4}. The composition ratio of Fe and Se was controlled by the synthesis voltage and pH…

The discovery of high-temperature (Tc) superconductivity in monolayer FeSe on SrTiO3 raised a fundamental question whether high Tc is commonly realized in monolayer iron-based superconductors. Tetragonal FeS is a key material to resolve…

Superconducting FeSe0.8Te0.2 thin films on SrTiO3, LaAlO3 and CaF2 substrates were electrochemically etched in an ionic liquid DEME-TFSI electrolyte with a gate bias of 5 V. Superconductivity at 38 K was commonly observed on all substrates…

We have synthesized 10 new iron oxyarsenides, K$Ln_2$Fe$_4$As$_4$O$_2$ ($Ln$ = Gd, Tb, Dy, and Ho) and Cs$Ln_2$Fe$_4$As$_4$O$_2$ ($Ln$ = Nd, Sm, Gd, Tb, Dy, and Ho), with the aid of lattice-match [between $A$Fe$_2$As$_2$ ($A$ = K and Cs)…

超导电性 · 物理学 2017-09-13 Si-Qi Wu , Zhi-Cheng Wang , Chao-Yang He , Zhang-Tu Tang , Yi Liu , Guang-Han Cao

A general feature of unconventional superconductors is the existence of a superconducting dome in the phase diagram as a function of carrier concentration. For the simplest iron-based superconductor FeSe (with transition temperature Tc ~ 8…

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