相关论文: Chemical nitrogen fractionation in dense molecular…
Clouds of high infrared extinction are promising sites of massive star/cluster formation. A large number of cloud cores discovered in recent years allows investigation of possible evolutionary sequence among cores in early phases. We have…
Nitrogen is one of the most abundant metals in the interstellar medium (ISM), and thus it constitutes an excellent test to study a variety of astrophysical environments, ranging from nova to active galactic nuclei. We present a detailed…
We study infrared emission of 17 isolated, diffuse clouds with masses of order solar masses, to test the hypothesis that grain property variations cause the apparently low gas-to-dust ratios that have been measured in those clouds. Maps of…
We survey the current situation regarding chemical modelling of the synthesis of molecules in the interstellar medium. The present state of knowledge concerning the rate coefficients and their uncertainties for the major gas-phase processes…
Although chemical models predict that the deuterium fractionation in N$_2$H$^+$ is a good evolutionary tracer in the star formation process, the fractionation of nitrogen is still a poorly understood process. Recent models have questioned…
We present an analysis of "bistability" in gas-phase chemical models of dark interstellar clouds. We identify the chemical mechanisms that allow high- and low-ionization solutions to the chemical rate-equations to coexist. We derive simple…
The diffusion of atoms and radicals on interstellar dust grains is a fundamental ingredient for predicting accurate molecular abundances in astronomical environments. Quantitative values of diffusivity and diffusion barriers usually rely…
We have studied the chemistry of nitrogen--bearing species during the initial stages of protostellar collapse, with a view to explaining the observed longevity of N2H+ and NH3 and the high levels of deuteration of these species. We followed…
Processing by interstellar photons affects the composition of the icy mantles on interstellar grains. The rate of photodissociation in solids differs from that of molecules in the gas phase. The aim of this work was to determine an average,…
We construct the gas-grain chemical network model which includes carbon isotopes (12C and 13C) with an emphasis on isotopomer-exchange reactions. Temporal variations of molecular abundances, the carbon isotope ratios (12CX/13CX) and the…
Context. The nitrogen isotopic ratio is considered an important diagnostic tool of the star formation process, and $N_2H^+$ is particularly important because it is directly linked to molecular nitrogen $N_2$. However, theoretical models…
We have studied deuterium fractionation on interstellar grains with the use of an exact method known as the direct master equation approach. We consider conditions pertinent to dense clouds at late times when the hydrogen is mostly in…
Magnetic fields play such essential roles in star formation as transporting angular momentum and driving outflows from a star-forming cloud, thereby controlling the formation efficiency of a circumstellar disc and also multiple stellar…
In the interstellar medium (ISM), the formation of complex organic molecules (COMs) is largely facilitated by surface reactions. However, in cold dark clouds, thermal desorption of COMs is inefficient because of the lack of thermal energy…
Long-chain hydrocarbon anions CnH- (n=4, 6, 8) have recently been found to be abundant in a variety of interstellar clouds. In order to explain their large abundances in the denser (prestellar/protostellar) environments, new chemical models…
The formation of singly and doubly deuterated isotopomers of formaldehyde and of singly, doubly, and multiply deuterated isotopomers of methanol on interstellar grain surfaces has been studied with a semi-empirical modified rate approach…
Sensitive measurements of the interstellar gas-phase oxygen abundance have revealed a slight oxygen deficiency ($\sim$ 15%) toward stars within 500 pc of the Sun as compared to more distant sightlines. Recent $FUSE$ observations of the…
The isotopic ratio of nitrogen presents a wide range of values in the Solar System and in star forming system whose origin is still unclear. Chemical reactions in the gas phase are one of the possible processes that could modify the…
Observations have revealed that the elemental abundances of carbon and oxygen in the warm molecular layers of some protoplanetary disks are depleted compared to those is the interstellar medium by a factor of ~10-100. Meanwhile, little is…
Observations of diffuse clouds showed that they contain a number of simple hydrocarbons (e.g. CH, C$_2$H, (l- and c-)C$_3$H$_2$, and C$_4$H) in abundances that may be difficult to understand on the basis of conventional gas-phase chemical…