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We report the experimental discovery of superconductivity with critical temperature Tc above 70 K in zirconium polyhydrides, the record high so far for 3d transition metal hydrides. The superconducting zirconium polyhydrides are synthesized…

超导电性 · 物理学 2022-04-01 C. L. Zhang , X. He , Z. W. Li , S. J. Zhang , S. M. Feng , X. C. Wang , R. C. Yu , C. Q. Jin

Motivated by the recent claim of hot superconductivity with critical temperatures up to 550 K in La + x hydrides (arXiv:2006.03004), we investigate the high-pressure phase diagram of possible compounds that may have formed in the…

超导电性 · 物理学 2021-06-15 Simone Di Cataldo , Wolfgang von der Linden , Lilia Boeri

Discovery of high-temperature superconductivity in hydrogen-rich compounds has fuelled the enthusiasm for finding materials with more promising superconducting properties among hydrides. However, the ultrahigh pressure needed to synthesize…

超导电性 · 物理学 2021-09-22 Miao Gao , Xun-Wang Yan , Zhong-Yi Lu , Tao Xiang

Following the discovery of high-temperature superconductivity in the La-H system, where for the recently discovered fcc-LaH10 a record critical temperature Tc = 250 K was achieved [Drozdov et al., Nature, 569, 528 (2019) and Somayazulu et…

Room-temperature superconductivity has been one of the most challenging subjects in modern physics. Recent experiments reported that lanthanum hydride LaH$_{10{\pm}x}$ ($x$$<$1) raises a superconducting transition temperature $T_{\rm c}$ up…

超导电性 · 物理学 2019-04-10 Liangliang Liu , Chongze Wang , Seho Yi , Kun Woo Kim , Jaeyong Kim , Jun-Hyung Cho

It has been a hot issue to search for hydrides at high pressure with high superconducting transition temperature (Tc). In this work, ternary hydrogen-rich compounds KYHn (n = 1-16) were studied and calculated using the density function…

超导电性 · 物理学 2021-10-27 LingYan Chen

Hydrogen-rich ternary hydrides are promising candidates for high-Tc superconductivity at megabar pressures, yet their chemical space is vast and largely unexplored. Combining evolutionary structure searches with first-principles…

The uniquely characteristic macrostructures of binary hydrogen-clathrate compounds $M$H$_\textrm{n}$ formed at high pressure, a cage of hydrogens surrounding a central-atom host, is theoretically predicted in various studies to include…

超导电性 · 物理学 2020-06-22 Dale R. Harshman , Anthony T. Fiory

The compressed hydrogen-rich compounds have received extensive attention as promising candidates for room temperature superconductivity, however, the high pressure required to stabilize such materials hinders their wide practical…

超导电性 · 物理学 2023-11-14 Wendi Zhao , Defang Duan , Decheng An , Qiwen Jiang , Zhengtao Liu , Tiancheng Ma , Zihao Huo , Jianhui Du , Tian Cui

Ternary hydrides are considered as the ideal candidates with high critical temperature (Tc) stabilized at submegabar pressure, evidenced by the recent discoveries in LaBeH8 (110 K at 80 GPa) and LaB2H8 (106 K at 90 GPa). Here, we…

超导电性 · 物理学 2024-12-02 Tingting Gu , Wenwen Cui , Jian Hao , Jingming Shi , Artur P. Durajski , Hanyu Liu , Yinwei Li

We review five years of experimental and theoretical attempts (2020-2025) to enhance the superconducting critical temperature ($\textit{T$_c$}$) of hydrogen-rich compounds by alloying binary superhydrides with additional elements. Despite…

Lanthanum (La) is the first member of the rare-earth series of elements that has recently raised considerable interest because of its unique high-Tc superhydride LaH10. Although several studies have found superconductivity and phase…

Room-temperature superconductor has been a century-long dream of humankind. Recent research on hydrogen-based superconductors (e.g., CaH6, LaH10, etc.) at high-pressure conditions lifts the record of superconducting critical temperature…

Zhou et al., in their recent publication (Nat. Commun. 16, 1135, 2025), reported the synthesis of lanthanum superhydride, LaHx (x = 10.2-11.1), by laser heating LaH3 with NH3BH3 at a pressure of 170 GPa and investigated the temporal…

We report the observation of conventional superconductivity at the highest temperature yet attained without mechanical compression, around 54 kelvin in palladium-hydride and 60 kelvin in palladium-deuteride. The remarkable increase in Tc…

超导电性 · 物理学 2016-08-08 H. M. Syed , T. J. Gould , C. J. Webb , E. MacA. Gray

Searching for superconductivity with Tc near room temperature is of great interest both for fundamental science & many potential applications. Here we report the experimental discovery of superconductivity with maximum critical temperature…

Recent theoretical and experimental studies of hydrogen-rich materials at megabar pressures (i.e., >100 GPa) have led to the discovery of very high-temperature superconductivity in these materials. Lanthanum superhydride LaH$_{10}$ has been…

超导电性 · 物理学 2022-01-05 Yanfeng Ge , Fan Zhang , Russell J. Hemley

High-temperature superconductivity has been observed in binary hydrides such as LaH10 at pressures above 150 GPa. Hydrogen cage structures have been identified as a common motif beneficial for high critical temperatures Tc. Efforts are now…

Lanthanum hydrides, containing hydrogen framework structures under compression, display a superconducting state with a high observed critical temperature. However, this phenomenon has so far only been observed at very high pressures. Here,…

超导电性 · 物理学 2023-06-16 Hao Song , Zihan Zhang , Tian Cui2 , Chris J. Pickard , Vladimir Z. Kresin , Defang Duan

The research on hydrogen-rich ternary compounds attract tremendous attention for it paves new route to room-temperature superconductivity at lower pressures. Here, we study the crystal structures, electronic structures, and superconducting…

超导电性 · 物理学 2023-12-19 Juefei Wu , Bangshuai Zhu , Chi Ding , Cuiying Pei , Qi Wang , Jian Sun , Yanpeng Qi