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Dynamic Nuclear Polarization (DNP) presently stands as the preferred strategy to enhance the sensitivity of nuclear magnetic resonance measurements, but its application relies on the use of high-frequency microwave to manipulate electron…

介观与纳米尺度物理 · 物理学 2022-02-02 Carlos A. Meriles , Pablo R. Zangara

A portable NMR polarimeter system has been developed to measure the polarization of a polarized Hydrogen-Deuteride (HD) target for hadron photoproduction experiments at SPring-8. The polarized HD target is produced at the Research Center…

仪器与探测器 · 物理学 2015-05-27 T. Ohta , M. Fujiwara , K. Fukuda , H. Kohri , T. Kunimatsu , C. Morisaki , S. Ono , M. Tanaka , K. Ueda , M. Uraki , M. Utsuro , S. Y. Wang , M. Yosoi

The hyperpolarisation of nuclear spins within target molecules is a critical and complex challenge in magnetic resonance imaging (MRI) and nuclear magnetic resonance (NMR) spectroscopy. Hyperpolarisation offers enormous gains in signal and…

Dynamic nuclear polarization is widely used to enhance the sensitivity of nuclear magnetic resonance. It is presently the method of choice for enhancing the sensitivity of high-field solid state NMR experiments performed under cryogenic…

化学物理 · 物理学 2022-02-02 Maria Grazia Concilio , Ilya Kuprov , Lucio Frydman

We describe a method to hyperpolarize 3He nuclear spins at high magnetic fields (4.7 Tesla) solely by a magnetized plasma. The conditions for such a magnetized plasma are fulfilled when the mean free path of the free electrons is much…

原子物理 · 物理学 2018-12-12 A. Maul , P. Blümler , P. -J. Nacher , E. Otten , G. Tastevin , W. Heil

We demonstrate a novel method to ionize molecules or molecular clusters by proton transfer at temperatures below 1 K. The method yields nascent ions and largely eliminates secondary reactions, even for notoriously "delicate" molecules.…

化学物理 · 物理学 2022-11-16 Lukas Tiefenthaler , Siegfried Kollotzek , Andrew M. Ellis , Paul Scheier , Olof Echt

Direct dynamic nuclear polarization of 1H nuclei in frozen water and water-ethanol mixtures is demonstrated using silicon nanoparticles as the polarizing agent. Electron spins at dangling-bond sites near the silicon surface are identified…

介观与纳米尺度物理 · 物理学 2014-01-14 M. C. Cassidy , C. Ramanathan , D. G. Cory , J. W. Ager , C. M. Marcus

SABRE (Signal Amplification By Reversible Exchange) has become a widely used method for hyper-polarizing nuclear spins, thereby enhancing their Nuclear Magnetic Resonance (NMR) signals by orders of magnitude. In SABRE experiments,…

化学物理 · 物理学 2020-12-02 Stephan Knecht , Danila A. Barskiy , Gerd Buntkowsky , Konstantin L. Ivanov

Dynamic nuclear polarization (DNP) is an NMR sensitivity enhancement technique that mediates polarization transfer from unpaired electrons to NMR-active nuclei. Despite its success in elucidating important structural information on…

Hyperpolarization approaches in magnetic resonance overcome the sensitivity limitations imposed by thermal magnetization and play an important role in a very wide range of modern applications. One of the newer strategies, variants of what…

化学物理 · 物理学 2025-11-10 Loren L. Smith , Warren S. Warren

Nuclear Magnetic Resonance (NMR) is an intriguing quantum-mechanical effect that is used for daily life medical diagnostics and chemical analysis alike. Numerous advancements have contributed to the success of the technique, including…

化学物理 · 物理学 2020-04-28 Andrey N. Pravdivtsev , Frank D. Sönnichsen , Jan-Bernd Hövener

Recently, Pang et al reported a novel polarization transfer scheme applicable to three-spin systems, whereby a rotating-frame NMR analogue of the cross effect could transfer polarization between; e.g., two 13Cs and an 15N in a single…

量子物理 · 物理学 2026-04-21 Sundaresan Jayanthi , Adonis Lupulescu , Julia Grinshtein , Lucio Frydman

Dynamic nuclear polarisation (DNP) refers to a class of techniques used to increase the signal in nuclear magnetic resonance measurements by transferring spin polarisation from ensembles of highly polarised electrons to target nuclear…

量子物理 · 物理学 2020-12-24 L. T. Hall , D. A. Broadway , A. Stacey , D. A. Simpson , J-P. Tetienne , L. C. L. Hollenberg

In dissolution-dynamic nuclear polarization, nuclear spins are hyperpolarized at cryogenic temperatures using radicals and microwave irradiation. The hyperpolarized solid is dissolved with hot solvent and the solution is transferred to a…

仪器与探测器 · 物理学 2019-06-20 Karel Kouřil , Hana Kouřilová , Samuel Bartram , Malcolm H. Levitt , Benno Meier

We study the polarization of antihyperon in lepton induced reactions such as $e^+e^-\to\bar H+X$ and $l+p\to l'+\bar H+X$ with polarized beams using different models for spin transfer in high energy fragmentation processes. We compare the…

高能物理 - 唯象学 · 物理学 2009-11-11 Hui Dong , Jian Zhou , Zuo-tang Liang

Spin-polarized solid targets have underpinned many recent key advances in nuclear and particle physics, yet traditional methods to produce them face significant limitations due to the high cost and demanding cryogenic and magnetic field…

Polarization transfers are crucial building blocks in magnetic resonance experiments, i.e., they can be used to polarize insensitive nuclei and correlate nuclear spins in multidimensional NMR spectroscopy. The polarization can be…

化学物理 · 物理学 2022-08-24 Zhenfeng Pang , Sheetal Jain , Chen Yang , Xueqian Kong , Kong Ooi Tan

Polarized antiprotons can be produced in a storage ring by spin--dependent interaction in a purely electron--polarized hydrogen gas target. The polarizing process is based on spin transfer from the polarized electrons of the target atoms to…

Medicine is evolving beyond therapy largely predicated on anatomical information and towards incorporating patient-specific molecular biomarkers of disease for more accurate diagnosis and effective treatment. The complementary combination…

Highly sensitive nuclear spin detection is crucial in many scientific areas including nuclear magnetic resonance spectroscopy (NMR), imaging (MRI) and quantum computing. The tiny thermal nuclear spin polarization represents a major obstacle…