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Zero and ultralow-field nuclear magnetic resonance (ZULF NMR) is an NMR modality where experiments are performed in fields at which spin-spin interactions within molecules and materials are stronger than Zeeman interactions. This typically…

As a complementary analysis tool to conventional high-field NMR, zero- to ultralow-field (ZULF) NMR detects nuclear magnetization signals in the sub-microtesla regime. Spin-exchange relaxation-free (SERF) atomic magnetometers provide a new…

量子物理 · 物理学 2020-12-01 Min Jiang , Ji Bian , Qing Li , Ze Wu , Haowen Su , Minxiang Xu , Yuanhong Wang , Xin Wang , Xinhua Peng

Zero- to ultralow-field nuclear magnetic resonance (ZULF NMR) is a powerful version of NMR that allows studying molecules and their transformations in the regime dominated by intrinsic spin-spin interactions. While spin dynamics at zero…

Zero- to ultralow-field nuclear magnetic resonance (ZULF NMR) is an alternative spectroscopic method to high-field NMR, in which samples are studied in the absence of a large magnetic field. Unfortunately, there is a large barrier to entry…

化学物理 · 物理学 2020-04-29 John W. Blanchard , Teng Wu , James Eills , Yinan Hu , Dmitry Budker

We present a method which allows for the extraction of physical quantities directly from zero- to ultralow-field nuclear magnetic resonance (ZULF NMR) data. A numerical density matrix evolution is used to simulate ZULF NMR spectra of…

化学物理 · 物理学 2018-03-14 Alexander Wilzewski , Samer Afach , John W. Blanchard , Dmitry Budker

One-dimensional chains of coupled spins are minimal models of strongly correlated quantum matter, and have been proposed as wires for transporting quantum information. In liquids, rapid molecular tumbling averages anisotropic dipolar…

Despite its versatility and high chemical specificity, conventional NMR spectroscopy is limited in measurement throughput due to the need for high-homogeneity magnetic fields, necessitating sequential sample analysis, and bulky devices.…

仪器与探测器 · 物理学 2024-07-02 Blake Andrews , Matthew Lai , Zhen Wang , Norihisa Kato , Michael Tayler , Emanuel Druga , Ashok Ajoy

Zero-field (ZF) nuclear magnetic resonance (NMR) spectroscopy probes scalar J-couplings between nuclei while dispensing with large homogeneous magnetic fields, enabling low-cost and geometrically flexible detection, including through…

Nuclear-magnetic-resonance experiments can interrogate a broad spectrum of molecular-tumbling regimes and can accurately measure interatomic distances in solution with sub-nanometer resolution. In the zero- to ultralow-field (ZULF) regime,…

Zero- to ultra-low-field nuclear magnetic resonance (ZULF NMR) provides a new regime for the measurement of nuclear spin-spin interactions free from effects of large magnetic fields, such as truncation of terms that do not commute with the…

We report measurements of zero- to ultra-low-field nuclear magnetic resonance (ZULF NMR) signals at frequencies of a few hertz with a diamond-based magnetic sensor. The sensing diamond is a truncated pyramid with 0.18 mm height and a 0.5 mm…

This study pioneers the two-field correlation spectroscopy (COSY) in zero to ultralow field (ZULF) liquid state NMR, employing hyperpolarized [1-$^{13}$C]pyruvate as a model system. We demonstrate the successful integration of signal…

Magnetic sensors are important for detecting nuclear magnetization signals in nuclear magnetic resonance (NMR). As a complementary analysis tool to conventional high-field NMR, zero- and ultralow-field (ZULF) NMR detects nuclear…

原子物理 · 物理学 2019-02-13 Min Jiang , Roman Picazo Frutos , Teng Wu , John W. Blanchard , Xinhua Peng , Dmitry Budker

We review instrumentation for nuclear magnetic resonance (NMR) in zero and ultra-low magnetic field (ZULF, below 0.1 $\mu$T) where detection is based on a low-cost, non-cryogenic, spin-exchange relaxation free (SERF) $^{87}$Rb atomic…

Ultralow-field nuclear magnetic resonance (NMR) provides a new regime for many applications ranging from materials science to fundamental physics. However, the experimentally observed spectra show asymmetric amplitudes, differing greatly…

量子物理 · 物理学 2019-02-22 Min Jiang , Wenjie Xu , Yunlan Ji , Ji Bian , Shiming Song , Xinhua Peng

We investigate nuclear magnetic resonance (NMR) in near-zero-field, where the Zeeman interaction can be treated as a perturbation to the electron mediated scalar interaction (J-coupling). This is in stark contrast to the high field case,…

Zero- and ultralow-field nuclear magnetic resonance (ZULF NMR) has experienced rapid development and provides an excellent tool for diverse research fields ranging from materials science, quantum information processing to fundamental…

量子物理 · 物理学 2024-03-05 Taizhou Hong , Yuanhong Wang , Zhenhan Shao , Qing Li , Min Jiang , Xinhua Peng

Two dimensional nuclear magnetic resonance (NMR) spectroscopy is one of the major tools for analysing the chemical structure of organic molecules and proteins. Despite its power, this technique requires long measurement times, which,…

Nuclear magnetic resonance (NMR), conventionally detected in multi-tesla magnetic fields, is a powerful analytical tool for the determination of molecular identity, structure, and function. With the advent of prepolarization methods and…

We present single- and multiple-quantum correlation $J$-spectroscopy detected in zero ($<\!\!1$~$\mu$G) magnetic field using a \Rb vapor-cell magnetometer. At zero field the spectrum of ethanol appears as a mixture of \carbon isotopomers,…

化学物理 · 物理学 2020-08-26 Tobias F. Sjolander , John W. Blanchard , Dmitry Budker , Alexander Pines
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