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Ab initio modeling of electrochemical systems is becoming a key tool for understanding and predicting electrochemical behavior. Development and careful benchmarking of computational electrochemical methods are essential to ensure their…

化学物理 · 物理学 2017-03-01 Ravishankar Sundararaman , Kathleen Schwarz

Renewable energy is critical for combating climate change, whose first step is the storage of electricity generated from renewable energy sources. Li-ion batteries are a popular kind of storage units. Their continuous usage through…

统计方法学 · 统计学 2024-11-05 Youngjin Cho , Quyen Do , Pang Du , Yili Hong

Accurately predicting the future health of batteries is necessary to ensure reliable operation, minimise maintenance costs, and calculate the value of energy storage investments. The complex nature of degradation renders data-driven…

应用统计 · 统计学 2020-06-05 Robert R. Richardson , Michael A. Osborne , David A. Howey

We present a porous electrode model for lithium-ion batteries using Butler--Volmer reaction kinetics. We model lithium concentration in both the solid and fluid phase along with solid and liquid electric potential. Through asymptotic…

应用物理 · 物理学 2019-06-03 Iain R. Moyles , Matthew G. Hennessy , Timothy G. Myers , Brian R. Wetton

This manuscript presents an algorithm for individual Lithium-ion (Li-ion) battery cell state of charge (SOC) estimation in a large-scale battery pack under minimal sensing, where only pack-level voltage and current are measured. For battery…

系统与控制 · 电气工程与系统科学 2021-09-20 Dong Zhang , Luis D. Couto , Ross Drummond , Shashank Sripad , Venkatasubramanian Viswanathan

An appropriate description of the lithiation/delithiation dynamics in bi-phasic primary cathode particles of Li-ion batteries requires an accurate treatment of the conditions holding at the interface between the particle and the surrounding…

材料科学 · 物理学 2024-11-01 Ahmed Yousfi , Arnaud Demortière , Guillaume Boussinot

In this article the Butler-Volmer equation used in describing Lithium-ion (Li-ion) batteries is discussed. First, a complete mathematical model based on a macro-homogeneous approach developed by Neuman is presented. Two common mistakes…

化学物理 · 物理学 2015-03-20 A. M. Ramos , C. P. Please

Battery management is a critical component of ubiquitous battery-powered energy systems, in which battery state-of-charge (SOC) and state-of-health (SOH) estimations are of crucial importance. Conventional SOC and SOH estimation methods,…

系统与控制 · 电气工程与系统科学 2025-06-09 Shida Jiang , Junzhe Shi , Scott Moura

Modelling electrolytes accurately on both a nanoscale and cell level can contribute to improving battery chemistries.[Armand and Tarascon, Nature, 2008, 451, 652-657] We previously presented a thermodynamic continuum model for…

化学物理 · 物理学 2024-08-09 Constantin Schwetlick , Max Schammer , Arnulf Latz , Birger Horstmann

Lithium-ion batteries (LIBs) are the leading technology used in consumer electronics, electric vehicles, and grid-level electrochemical energy storage applications. The ever-increasing use of LIBs has highlighted a gap in understanding of…

The properties of rechargeable lithium-ion batteries are determined by the electrochemical and kinetic properties of their constituent materials as well as by their underlying microstructure. Microstructural design can be leveraged to…

材料科学 · 物理学 2022-03-11 Giovanna Bucci , Tushar Swamy , W. Craig Carter , Morad Behandish

The solid-state diffusion coefficient of the electrode active material is one of the key parameters in lithium-ion battery modelling. Conventionally, this diffusion coefficient is estimated through the galvanostatic intermittent titration…

化学物理 · 物理学 2021-10-18 Zeyang Geng , Yu-Chuan Chien , Matthew J. Lacey , Torbjörn Thiringer , Daniel Brandell

To study the electrochemical reaction on surfaces, phase interfaces, and crack surfaces in the lithium ion battery electrode particles, a phase-field model is developed, which describes fracture in large strains and anisotropic…

材料科学 · 物理学 2016-05-31 Ying Zhao , Bai-Xiang Xu , Peter Stein , Dietmar Gross

In this paper, a core-shell enhanced single particle model for iron-phosphate battery cells is formulated, implemented, and verified. Starting from the description of the positive and negative electrodes charge and mass transport dynamics,…

系统与控制 · 电气工程与系统科学 2022-09-26 Gabriele Pozzato , Aki Takahashi , Xueyan Li , Donghoon Lee , Johan Ko , Simona Onori

Hysteresis is a general phenomenon regularly observed in measurements of various materials properties such as magnetism, elasticity, capillary pressure, adsorption, battery voltage etc. Usually, the hysteretic behaviour is an intrinsic…

Lithium-ion batteries (LIBs) are utilized as a major energy source in various fields because of their high energy density and long lifespan. During repeated charging and discharging, the degradation of LIBs, which reduces their maximum…

机器人学 · 计算机科学 2024-10-23 Jayden Dongwoo Lee , Donghoon Seo , Jongho Shin , Hyochoong Bang

The projected rapid growth of battery cell production over the next decade demands advanced diagnostic tools for quality control, ageing prediction, and recycling. Most existing techniques lack the spatial and temporal resolution required…

Metal anodes provide the highest energy density in batteries. However, they still suffer from electrode/electrolyte interface side reactions and dendrite growth, especially under fast-charging conditions. In this paper, we consider a…

材料科学 · 物理学 2025-07-29 Hamed Taghavian , Viktor Vanoppen , Erik Berg , Peter Broqvist , Jens Sjölund

Obtaining a complete picture of local processes still poses a significant challenge in battery research. Here we demonstrate an in-situ combination of multimodal neutron imaging with neutron diffraction for spatially resolved operando…

Lithium metal cells are key towards achieving high specific energy and energy density for electrification of transportation and aviation. Anode-free cells are the limiting case of lithium metal cells involving no excess lithium and the…

材料科学 · 物理学 2019-12-04 Vikram Pande , Venkatasubramanian Viswanathan