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Cation displacements, oxygen octahedral tilts, and magnetism of epitaxial, ferrimagnetic, insulating GdTiO3 films sandwiched between cubic SrTiO3 layers are studied using scanning transmission electron microscopy and magnetization…

强关联电子 · 物理学 2013-11-05 Jack Y. Zhang , Clayton A. Jackson , Santosh Raghavan , Jinwoo Hwang , Susanne Stemmer

We report high-resolution dilatometry on high-quality single crystals of NiTiO3 grown by means of the optical floating-zone technique. The anisotropic magnetic phase diagram is constructed from thermal expansion and magnetostriction studies…

High-quality single crystals of CoTiO$_3$ are grown and used to elucidate in detail structural and magnetostructural effects by means of high-resolution capacitance dilatometry studies in fields up to 15 T which are complemented by specific…

强关联电子 · 物理学 2021-07-19 M. Hoffmann , K. Dey , J. Werner , R. Bag , J. Kaiser , H. Wadepohl , Y. Skourski , M. Abdel-Hafiez , S. Singh , R. Klingeler

In the Mott-Hubbard insulators YTiO3 and SmTiO3 we study optical excitations from the lower to the upper Hubbard band, d^1d^1 -> d^0d^2. The multi-peak structure observed in the optical conductivity reflects the multiplet structure of the…

Neutron scattering was used to determine the spin structure and the magnon spectrum of the Mott--Hubbard insulator YTiO$_3$. The magnetic structure is complex, comprising substantial G-type and A-type antiferromagnetic components in…

强关联电子 · 物理学 2009-11-07 C. Ulrich , G. Khaliullin , S. Okamoto , M. Reehuis , A. Ivanov , H. He , Y. Taguchi , Y. Tokura , B. Keimer

We use first-principles methods to study doped strong ferroelectrics (taking BaTiO$_3$ as a prototype). Here we find a strong coupling between itinerant electrons and soft polar phonons in doped BaTiO$_3$, contrary to Anderson/Blount's…

材料科学 · 物理学 2021-04-21 Jiaji Ma , Ruihan Yang , Hanghui Chen

Nanometer-scale modulations can spontaneously emerge in complex materials when multiple degrees of freedom interact. Here we demonstrate that ferroelectric Sr$_{1-x}$Ca$_x$TiO$_3$ lies in close proximity to an incipient structurally…

Polarized neutron reflectometry measurements are presented exploring the evolution of ferrimagnetism in GdTiO$_3$ films as they are confined between SrTiO$_3$ layers of variable thicknesses. As GdTiO$_3$ films approach the thin layer limit…

介观与纳米尺度物理 · 物理学 2018-04-18 R. F. Need , B. J. Isaac , B. J. Kirby , J. A. Borchers , S. Stemmer , S. D. Wilson

Using a point-charge calculation of the electrostatic crystal field, we determine the non-degenerate orbital ground state of the ferromagnetic Mott insulator YTiO3, which is found to agree perfectly with experiment. Based on the orbital…

强关联电子 · 物理学 2009-11-11 Robert Schmitz , Ora Entin-Wohlman , Amnon Aharony , Erwin Mueller-Hartmann

Infrared reflectivity and time-domain terahertz transmission spectra of EuTiO3 ceramics revealed a polar optic phonon at 6 - 300K, whose softening is fully responsible for the recently observed quantum paraelectric behaviour. Even if our…

材料科学 · 物理学 2007-09-24 S. Kamba , D. Nuzhnyy , P. Vanek , M. Savinov , K. Knizek , Z. Shen , E. Santava , K. Maca , M. Sadowski , J. Petzelt

Epitaxial strain and chemical substitution have been the workhorses of functional materials design. These static techniques have shown immense success in controlling properties in complex oxides through the tuning of subtle structural…

强关联电子 · 物理学 2018-03-06 Guru Khalsa , Nicole A. Benedek

In quantum materials, degeneracies and frustrated interactions can have a profound impact on the emergence of long-range order, often driving strong fluctuations that suppress functionally relevant electronic or magnetic phases. Engineering…

Here we present polarized neutron reflectometry measurements exploring thin film heterostructures comprised of a strongly correlated Mott state, GdTiO$_3$, embedded with SrTiO$_3$ quantum wells. Our results reveal that the net…

强关联电子 · 物理学 2016-07-15 R. F. Need , B. J. Isaac , B. J. Kirby , J. A. Borchers , S. Stemmer , Stephen D. Wilson

Optical and magneto-optical properties of YVO$_3$ single crystal were studied in FIR, visible, and UV regions. Two structural phase transitions at 75 K and 200 K were observed and established to be of the first and second order,…

In order to establish the correlation between the magnetoelectric coupling and magnetic instability, we have studied the structural, magnetic, and ferroelectric properties of \textit{x}BaTiO${_3}$-(1-\textit{x})BiCoO${_3}$ as a function of…

材料科学 · 物理学 2019-02-14 Lokanath Patra , Zhao Pan , Jun Chen , Masaki Azuma , P. Ravindran

The ultrafast response of the prototype Mott-Hubbard system (V1-xCrx)2O3 was systematically studied with fs pump-probe reflectivity, allowing us to clearly identify the effects of the metal-insulator transition on the transient response.…

强关联电子 · 物理学 2011-08-29 B. Mansart , D. Boschetto , S. Sauvage , A. Rousse , M. Marsi

The 3d electronic structure and phase transition in pure and Cr doped V2O3 are theoretically investigated in relation to the 3d spin-orbit interaction and lattice distortion. A model consisting of the nearest-neighbor V ion pair with full…

强关联电子 · 物理学 2016-08-31 Arata Tanaka

Magnetic correlations in all four phases of pure and doped vanadium sesquioxide V_2O_3 have been examined by magnetic thermal neutron scattering. While the antiferromagnetic insulator can be accounted for by a Heisenberg localized spin…

强关联电子 · 物理学 2009-10-31 Wei Bao , C. Broholm , G. Aeppli , S. A. Carter , P. Dai , T. F. Rosenbaum , J. M. Honig , P. Metcalf , S. F. Trevino

Intrinsic magnetoelectric coupling describes the interaction between magnetic and electric polarization through an inherent microscopic mechanism in a single phase material. This phenomenon has the potential to control the magnetic state of…

The compressive strain effects on the magnetic ground state and electronic structure of strained GdTiO 3 have been studied by the first-principles method. Different from the congeneric YTiO3 and LaTiO3 cases both of which becomes the A-type…

材料科学 · 物理学 2014-11-04 Li-Juan Yang , Ya-Kui Weng , Hui-Min Zhang , Shuai Dong
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