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The carbon dimer, the $^{12}$C$_2$ molecule, is ubiquitous in astronomical environments. Experimental-quality rovibronic energy levels are reported for $^{12}$C$_2$, based on rovibronic transitions measured for and among its singlet,…

An analysis of the measured rovibrational transitions is carried out for the 12C32S2 isotopologue of carbon disulfide. Data from 21 sources is extracted and validated using a consistent set of standard linear molecule quantum numbers. A…

原子物理 · 物理学 2025-02-28 Tanvi Sattiraju , Jonathan Tennyson

Rotation-vibration energy levels are determined for the electronic ground state of the acetylene molecule, $^{12}$C$_2$H$_2$, using the Measured Active Rotational-Vibrational Energy Levels (MARVEL) technique. 37,813 measured transitions…

Accurate, experimental rovibronic energy levels, with associated labels and uncertainties, are reported for 11 low-lying electronic states of the diatomic \TiO\ molecule, determined using the \Marvel\ (Measured Active Rotational-Vibrational…

Rovibronic energy levels are determined for four low-lying electronic states (\X, \A, \Sa, and \Sc) of the imidogen free radical ($^{14}$NH) using the \Marvel\ (Measured Active Rotational-Vibrational Energy Levels) technique. Compilation of…

An accurate line list, VOMYT, of spectroscopic transitions is presented for hot VO. The 13 lowest electronic states are considered. Curves and couplings are based on initial {\it ab initio} electronic structure calculations and then tuned…

太阳与恒星天体物理 · 物理学 2016-10-20 Laura K. McKemmish , Sergei N. Yurchenko , Jonathan Tennyson

Accurate line lists for the carbon dimer, C$_2$, are presented. These line lists cover rovibronic transitions between the eight lowest electronic states: $X\,{}^{1}\Sigma_{g}^{+}$, $a\,{}^{3}\Pi_{u}$, $A\,{}^{1}\Pi_{u}$,…

太阳与恒星天体物理 · 物理学 2018-12-19 Sergei N. Yurchenko , István Szabó , Elizaveta Pyatenko , Jonathan Tennyson

Comprehensive and accurate rovibronic line lists for the X $^{1}\Sigma^{+}$ and A $^{1}\Pi$ states of $^{12}$C$^{1}$H$^{+}$ and $^{13}$C$^{1}$H$^{+}$ which should be applicable up to temperatures of 5000 K are presented. Available empirical…

太阳与恒星天体物理 · 物理学 2023-08-09 Oliver Pearce , Sergei N. Yurchenko , Jonathan Tennyson

Carbon monoxide is thought to be the second most abundant molecule in the Universe. This makes observation of both its parent isotopologue ($^{12}$C$^{16}$O) and its stable isotopologues, $^{13}$C$^{16}$O, $^{12}$C$^{18}$O,…

星系天体物理 · 物理学 2026-01-21 Timur Grigorev , Yuhang Dai , Max Potter , Xiaoyu Xiang , Keyu Zhang , Jonathan Tennyson

Accurate line lists are important for the description of the spectroscopic nature of small molecules. While a line list for CN (an important molecule for chemistry and astrophysics) exists, no underlying energy spectroscopic model has been…

化学物理 · 物理学 2021-06-08 Anna-Maree Syme , Laura K. McKemmish

Zirconium oxide(ZrO) is an important astrophysical molecule that defines the S-star classification class for cool giant stars. Accurate, empirical rovibronic energy levels, with associated labels and uncertainties, are reported for 9…

Improved opacities are needed for modelling the atmospheres and evolution of cool carbon-rich stars and extra-solar planets; in particular, contributions made by the astrophysically important propadienediylidene (C$_3$) molecule need, at a…

太阳与恒星天体物理 · 物理学 2024-10-25 A. E. Lynas-Gray , O. L. Polyansky , J. Tennyson , S. N. Yurchenko , N. F. Zobov

44325 measured and assigned transitions of H$_2^{32}$S, the parent isotopologue of the hydrogen sulfide molecule, are collated from 33 publications into a single database and reviewed critically. Based on this information,…

An accurate line list for calcium oxide is presented covering transitions between all bound ro-vibronic levels from the five lowest electronic states \X, \Ap, \A, \astate, and \bstate. The ro-vibronic energies and corresponding…

星系天体物理 · 物理学 2016-07-05 Sergei N. Yurchenko , Audra Blissett , Usama Asari , Marcus Vasilios , Christian Hill , Jonathan Tennyson

An accurate line list, called XABC, is computed for nitric oxide which covers its pure rotational, vibrational and rovibronic spectra. A mixture of empirical and theoretical electronic transition dipole moments are used for the final…

地球与行星天体物理 · 物理学 2021-08-24 Qianwei Qu , Sergei N. Yurchenko , Jonathan Tennyson

A new hot line list for the main isotopologue of CO$_2$ is presented. The line list consists of almost 2.5 billion transitions between 3.5 million rotation-vibration states of CO$_2$ in its ground electronic state, covering the wavenumber…

地球与行星天体物理 · 物理学 2020-07-10 S. N. Yurchenko , Thomas M. Mellor , Richard S. Freedman , J. Tennyson

The rovibronic structure of A$^2\Sigma^+$, B$^2\Pi$ and C$^2\Pi$ states of nitric oxide (NO)is studied with the aim of producing comprehensive line lists for its near ultraviolet spectrum. Empirical energy levels for the three electronic…

化学物理 · 物理学 2021-08-24 Qianwei Qu , Bridgette Cooper , Sergei N. Yurchenko , Jonathan Tennyson

Indications of aluminium monoxide in atmospheres of exoplanets are being reported. Studies using high-resolution spectroscopy should allow a strong detection but require high accuracy laboratory data. A \textsc{marvel} (measured active…

地球与行星天体物理 · 物理学 2021-10-29 Charles A. Bowesman , Meiyin Shuai , Sergei N. Yurchenko , Jonathan Tennyson

The calcium monohydroxide radical (CaOH) is an important astrophysical molecule relevant to cool stars and rocky exoplanets, amongst other astronomical environments. Here, we present a consistent set of highly accurate rovibronic…

化学物理 · 物理学 2020-06-01 Y. Wang , A. Owens , J. Tennyson , S. N. Yurchenko

Published high-resolution rotation-vibration transitions of \spec{h212c16o}, the principal isotopologue of methanal, are analyzed using the MARVEL (Measured Active Rotation-Vibration Energy Levels) procedure. The literature results are…

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