相关论文: Achieving large zeta-potentials with charged porou…
In this paper we report a novel inertial instability that occurs in electro-osmotically driven channel flows. We assume that the charge motion under the influence of an externally applied electric field is confined to a small vicinity of…
While fluids near a solid surface are at the core of applications in energy storage/conversion, electrochemistry/electrowetting and adsorption/catalysis, their nanoscale behavior remains only partially deciphered. Beyond conventional…
We review recent dissipative particle dynamics (DPD) simulations of electrolyte flow in nanochannels. A method is presented by which the slip length $delta_B$ at the channel boundaries can be tuned systematically from negative to infinity…
Microchannel with porous wall has various microfluidic applications including iontophoresis, diagnostic devices, etc. In order to have an efficient and better design of such devices, exact quantification of velocity field in the…
It has been suggested that superhydrophobic surfaces, due to the presence of a no-shear zone, can greatly enhance transport of surface charges, leading to a considerable increase in the streaming potential. This could find potential use in…
We describe the general phenomenon of `induced-charge electro-osmosis' (ICEO) -- the nonlinear electro-osmotic slip that occurs when an applied field acts on the ionic charge it {\sl induces} around a polarizable surface. Motivated by a…
The paper deals with a theoretical study of electrokinetic flow of a rheological Herschel-Bulkley fluid through a cylindrical tube of variable cross-section. The concern of this study is to analyze combined pressure-driven and…
In computational models of microchannel flows, the Helmholtz-Smoluchowski slip velocity boundary condition is often used because it approximates the motion of the electric double layer without resolving the charge density profiles close to…
Osmotic transport in nanoconfined aqueous electrolytes provides new venues for water desalination and "blue energy" harvesting; the osmotic response of nanofluidic systems is controlled by the interfacial structure of water and electrolyte…
We discuss how the wettability of solid walls impacts electrokinetic properties, from large systems to a nanoscale. We show in particular how could the hydrophobic slippage, coupled to confinement effects, be exploited to induce novel…
Electrokinetic in-situ recovery is an alternative to conventional mining, relying on the application of an electric potential to enhance the subsurface flow of ions. Understanding the pore-scale flow and ion transport under electric…
We study the wetting properties of water on silica surfaces using molecular dynamics (MD) simulations. To describe the intermolecular interaction between water and silica atoms, two types of interaction potential models are used: the…
Nonlinear electrokinetic phenomena, where electrically driven fluid flows depend nonlinearly on the applied voltage, are commonly encountered in aqueous suspensions of colloidal particles. A prime example is the induced-charge…
The performances of lubricated systems widely used in natural, biological, and artificial settings are traditionally dictated by their load bearing capacities. Here we unveil that, by exploiting a unique coupling between interfacial…
We study the electrophoretic flow of suspensions of charged colloids with a mesoscopic method that allows to model generic experimental conditions. We show that for highly charged colloids their electrophoretic mobility increases…
The classical Poisson-Boltzmann (PB) theory of electrolytes assumes a dilute solution of point charges with mean-field electrostatic forces. Even for very dilute solutions, however, it predicts absurdly large ion concentrations (exceeding…
The present study deals with the effect of ionic advection on electroosmotic flow over charge modulated surfaces in a generalized paradigm when the classically restrictive "weak field" limit may be relaxed. Going beyond the commonly…
The venerable theory of electrokinetic phenomena rests on the hypothesis of a dilute solution of point-like ions near a weakly charged surface, whose potential relative to the bulk is of order the thermal voltage ($kT/e \approx 25$ mV at…
The zeta ($\zeta$) potential is a pivotal metric for characterizing the electric field topology within an electric double layer - an important phenomenon on phase interface. It underpins critical processes in diverse realms such as…
The Brinkman equation has found great popularity in modelling the interfacial flow between free fluid and a porous medium. However, it is still unclear how to determine an appropriate effective Brinkman viscosity without resolving the flow…