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The phenomenon of electrowetting, i.e., the dependence of the macroscopic contact angle of a fluid on the electrostatic potential of the substrate, is analyzed in terms of the density functional theory of wetting. It is shown that…

软凝聚态物质 · 物理学 2014-05-07 Markus Bier , Ingrid Ibagon

Within the framework of the mode-coupling theory of super-cooled liquids, we investigate new phenomena in colloidal systems on approach to their glass transitions. When the inter-particle potential contains an attractive part, besides the…

软凝聚态物质 · 物理学 2009-11-07 K. A. Dawson , G. Foffi , F. Sciortino , P. Tartaglia , E. Zaccarelli

The effective potential between charged colloids trapped at water interfaces is analyzed. It consists of a repulsive electrostatic and an attractive capillary part which asymptotically both show dipole--like behavior. For sufficiently large…

软凝聚态物质 · 物理学 2016-08-31 M. Oettel , A. Dominguez , S. Dietrich

Electrostatics plays a key role in biomolecular assembly. Oppositely charged biomolecules, for instance, can co-assembled into functional units, such as DNA and histone proteins into nucleosomes and actin-binding protein complexes into…

材料科学 · 物理学 2009-11-11 Y. S. Velichko , M. Olvera de la Cruz

We present a theory which allows us to calculate the interaction potential between charge-regulated metal nanoparticles inside an acid-electrolyte solution. The approach is based on the recently introduced model of charge regulation which…

软凝聚态物质 · 物理学 2020-12-11 Amin Bakhshandeh , Alexandre P. dos Santos , Yan Levin

The electrostatic double layer force is key to determining the stability and self-assembly of charged colloids and many other soft matter systems. Fully understanding the attractive force between two like-charged surfaces remains a great…

软凝聚态物质 · 物理学 2024-02-27 Nikhil R. Agrawal , Ravtej Kaur , Carlo Carraro , Rui Wang

A proper treatment of electrostatic interactions is crucial for the accurate calculation of forces in computer simulations. Electrostatic interactions are typically modeled using Ewald based methods, which have become one of the…

软凝聚态物质 · 物理学 2016-09-21 K. A. Terrón-Mejía , R. López-Rendón , A. Gama Goicochea

Despite decades of intensive studies, the effective interactions between strongly charged colloids still remain elusive. Here we show that a strongly charged surface with a layer of condensed counter- ions behaves effectively as a…

软凝聚态物质 · 物理学 2011-07-12 Xiangjun Xing , Zhenli Xu , Hongru Ma

We study the asymptotic long-range behavior of the time-dependent correlation function of the surface charge density induced on the interface between two media of distinct dielectric functions which are in thermal equilibrium with one…

统计力学 · 物理学 2016-10-26 Ladislav Samaj

We study the phase behavior of a system of charged colloidal particles that are electrostatically bound to an almost flat interface between two fluids. We show that, despite the fact that our experimental system consists of only $10^{3}$ -…

软凝聚态物质 · 物理学 2017-02-09 Colm P. Kelleher , Rodrigo E. Guerra , Andrew D. Hollingsworth , Paul M. Chaikin

We present a self-consistent kinetic theory for the electronic response of a plasma-facing dielectric solid. Based on the Poisson equation and two sets of spatially separated Boltzmann equations, one for electrons and ions in the plasma and…

等离子体物理 · 物理学 2017-08-02 Franz X. Bronold , Holger Fehske

The theory of elastic interaction of micron size axially symmetric colloidal particles immersed into confined nematic liquid crystal has been proposed. General formulas are obtained for the self energy of one colloidal particle and…

软凝聚态物质 · 物理学 2015-05-14 S. B. Chernyshuk , B. I. Lev

Several statistical mechanical theories predict that colloidal suspensions of highly charged macroions and monovalent microions can exhibit unusual thermodynamic phase behavior when strongly deionized. Density-functional, extended…

软凝聚态物质 · 物理学 2009-11-11 A. R. Denton

The bare Coulomb interaction between two like-charges is repulsive. When these charges are immersed in an electrolyte, the thermal fluctuations of the ions turn the bare Coulomb interaction into an effective interaction between the two…

统计力学 · 物理学 2023-03-15 Gabriel Tellez

We calculate the interaction potential between two colloids immersed in an aqueous mixture containing salt near or above the critical temperature. We find an attractive interaction far from the coexistence curve due to the combination of…

软凝聚态物质 · 物理学 2015-06-03 Sela Samin , Yoav Tsori

We study the interaction between two charge regulating spherical macroions with dielectric interior and dissociable surface groups immersed in a monovalent electrolyte solution. The charge dissociation is modelled via the…

软凝聚态物质 · 物理学 2023-12-11 Hu Ruixuan , Arghya Majee , Jure Dobnikar , Rudolf Podgornik

We study the ionic equilibria and interactions of neutral semi-permeable spherical shells immersed in electrolyte solutions, including polyions. Although the shells are uncharged, only one type of ions of the electrolyte can permeate them,…

软凝聚态物质 · 物理学 2012-07-24 Vladimir Lobaskin , Artem N. Bogdanov , Olga I. Vinogradova

Using a simple mean-field density functional theory theory (DFT), we investigate the structure and phase behaviour of a model colloidal fluid composed of particles interacting via a pair potential which has a hard core of diameter $\sigma$,…

软凝聚态物质 · 物理学 2007-05-23 A. J. Archer , D. Pini , R. Evans , L. Reatto

Electrostatic polarization is important in many nano-/micro-scale physical systems such as colloidal suspensions, biopolymers, and nanomaterials assembly. The calculation of polarization potential requires an efficient algorithm for solving…

软凝聚态物质 · 物理学 2015-06-11 Zhenli Xu

The classical problem of two uniformly charged infinite planes in electrochemical equilibrium with an infinite monovalent salt reservoir is solved exactly at the mean-field nonlinear Poisson-Boltzmann (PB) level, including an explicit…

软凝聚态物质 · 物理学 2009-11-07 M. N. Tamashiro , H. Schiessel