相关论文: An atomistic description of alloys and core shells…
Gold nanoparticle assemblies show a strong plasmonic response due to the combined effects of the individual nanoparticles' plasmon modes. Increasing the number of nanoparticles in structured assemblies leads to significant shifts in the…
The paper reports on the optical detection and spectroscopy of ultracold atoms near a gold surface. A probe light field is used to excite surface plasmon polaritons. The refractive index of the atomic gas shifts the plasmon resonance and…
We have used density functional theory to study the structural stability of surface alloys. Our systems consist of a single pseudomorphic layer of $M_xN_{1-x}$ on the Ru(0001) surface, where $M$ = Fe or Co, and $N$ = Pt, Au, Ag, Cd, or Pb.…
We propose an explanation for the anomalous behaviour observed in the relaxation dynamics of the differential optical transmission of noble-metal nanoparticles. Using the temperature dependences of the position and the width of the surface…
Electron beam imaging is a common technique used for characterizing the morphology of plasmonic nanostructures. During the imaging process, the electron beam interacts with traces of organic material in the chamber and produces a well-know…
The sensitivity of the wavelength position of surface plasmon resonances in prolate and oblate fine metal particles to the refractive index of an embedding solution, a particle shape, and electron temperature is studied theoretically in the…
Liquid metals (LM) are emerging plasmonic nanomaterials with transformable surface plasmon resonances (SPR) due to their liquid-like deformability. This study delves into the plasmonic properties of LM nanoparticles, with a focus on EGaIn…
Contacts between particles in dense, sheared suspensions are believed to underpin much of their rheology. Roughness and adhesion are known to constrain the relative motion of particles, and thus globally affect the shear response, but an…
Except serving as an excellent gift on proper occasions, gold finds applications in life sciences, particularly in diagnostics and therapeutics. These applications were made possible by gold nanoparticles, which differ drastically from…
The flexibility and versatility of nanoassembled plasmonic structures provide platforms for mesoscale tunable optical modulation. Our recently developed model for these nanoassembled plasmonic structures is composed of a dielectric…
The peculiar linear temperature-dependent swelling of core-shell microgels has been conjectured to be linked to the core-shell architecture combining materials of different transition temperatures. Here the structure of pNIPMAM-core and…
Optical properties of metallic nanoparticles are most often considered in terms of plasmons, the coupled states of light and quasi-free electrons. Here we predict that confinement of electrons inside the nanostructure leads to another, very…
From a structural point of view, plasmonic nanoparticles are always at least two-layer structures with a dielectric layer of stabilizing, targeting, fluorescent, Raman, or other functional molecules. To optimize the optical properties of…
The random-phase-approximation semiclassical scheme for description of plasmon excitations in large metallic nanospheres, with radius range 10-60 nm, is formulated in an all-analytical version. The spectrum of plasmons is determined…
Inorganic nanoparticle cores are often coated with organic ligands to render them dispersible in apolar solvents. However, the effect of the ligand shell on the colloidal stability of the overall hybrid particle is not fully understood. In…
Particle plasmons in metal nanoparticles have primarily been investigated through the use of local optical response approximations. However, as nanoparticle size approaches the average distance of electrons to the metal surface, mesoscopic…
Alloyed metal nanoparticles are a promising platform for plasmonically enabled hot-carrier generation, which can be used to drive photochemical reactions. Although the non-plasmonic component in these systems has been investigated for its…
The behavior of colloidal particles with a hard core and a soft shell has attracted the attention for researchers in the physical-chemistry interface not only due the large number of applications, but due the unique properties of these…
We report the studies of ultrafast electron nanocrystallography on size-selected Au nanoparticles (2-20 nm) supported on a molecular interface. Reversible surface melting, melting, and recrystallization were investigated with dynamical…
We use molecular dynamics simulations to study the melting of gold icosahedral clusters of a few thousand atoms. We pay particular attention to the behavior of surface atoms, and to the equilibrium shape of the cluster. We find that…